Method of treating the surface of a molded article comprising liquid crystal polyester resin

• US 4,950,360 A
• Filed: 09/27/1988
• Issued: 08/21/1990
• Est. Priority Date: 10/09/1987
• Status: Expired due to Term

• Current Assignee: Polyplastics Co., Ltd. (Daicel Corporation)
• Original Assignee: Polyplastics Co., Ltd. (Daicel Corporation)
• Inventors: Wada, Mitsuo, Suzuki, Yoshiharu, Murao, Toshiro, Konuma, Hiroaki
• Primary Examiner(s): Lacey, David L.
• Assistant Examiner(s): BURNS, TODD
• Application Number:
  US07/249,691
• Time in Patent Office: 693 Days
• Field of Search: 156/668, 156/625, 204/29, 204/30, 204/32.1, 204/44, 204/52.1, 427/307, 427/444
• US Class Current: 216/23
• CPC Class Codes: C08J 2367/03 the dicarboxylic acids and dihydroxy compounds having the hydroxy and the carboxyl groups directly linked to aromatic rings
• CPC Class Codes: C08J 7/14 with acids, their salts or anhydrides
• CPC Class Codes: C08K 3/013 Fillers, pigments or reinforcing additives
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: H05K 1/0313 Organic insulating material
• CPC Class Codes: H05K 1/0373 containing additives, e.g. fillers H05K1/036 takes precedence
• CPC Class Codes: H05K 3/381 by special treatment of the substrate

Abstract

Three dimensional molded articles comprising liquid crystalline polyesters are recognized to be extremely difficult to finish such as by printing, painting, metallizing, plating, etc. An effective answer to this difficulty is provided by initially blending within the liquid crystalline polyester at least one particulate inorganic filler selected from the group consisting of Group II elements of the periodic table and oxides, sulfates, phosphates, silicates, and carbonates thereof, and elements of aluminum, silicon, tin, lead, antimony, and bismuth and oxides thereof, in an amount of 5 to 80 percent by weight; forming a molded article from the same; and contacting the resulting molded article with an acidic solution containing at least 80 percent by weight of sulfuric acid. The requisite surface modification for finishing to form a quality product is made possible.

Claims

1. A method of treating the surface of a molded article comprising a liquid crystal polyester resin composition, said composition being composed of a melt-processable polyester capable of forming an anisotropic melt phase and at least one inorganic filler selected from the group consisting of the Group II elements of the periodic table and oxides, sulfates, phosphates, silicates, and carbonates thereof, and elements of aluminum, silicon, tin, lead, antimony, and bismuth and oxides thereof incorporated therein in an amount of 5 to 80% by weight based on the total amount of said molded article composition the method comprising bringing into contact said molded article with an acidic solution containing at least 80% by weight of sulfuric acid for treatment of said molded article.

2. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said at least one inorganic filler is a finely divided powder having an average particle diameter of 0.01 to 100 μ

m.

3. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said molded article composition further comprises a fibrous inorganic material having a diameter of 1 to 30 μ

m and a length of 5 μ

m to 1 mm incorporated therein in an amount of 1 to 60% by weight based on the total weight of said molded article composition.

4. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 2, wherein said molded article composition further comprises a fibrous inorganic material having a diameter of 1 to 30 μ

m and a length of 5 μ

m to 1 mm incorporated therein in an amount of 1 to 60% by weight based on the total weight of said molded article composition.

5. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said melt-processable polyester capable of forming an anisotropic melt phase contains at least 10 mole percent of naphthalene units.

6. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 5, wherein said naphthalene units of said melt-processable polyester capable of forming an anisotropic melt phase are selected from the group consisting of 6-hydroxy-2-naphthoyl, 2,6-dioxynaphthalene, and 2,6-dicarboxynaphthalene.

7. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said at least one inorganic filler is incorporated in said melt-processable polyester capable of forming an anisotropic melt phase in an amount of 20 to 70% by weight based on the total amount of said molded article composition.

8. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said at least one inorganic filler is a phosphate.

9. A method of treating the surface of a molded article comprising a liquid crystal polyester resin according to claim 1, wherein said at least one inorganic filler has an average diameter of 0.1 to 30 μ

m.