Magnetic recording medium

• US 4,950,555 A
• Filed: 01/09/1989
• Issued: 08/21/1990
• Est. Priority Date: 05/27/1986
• Status: Expired due to Fees

• Current Assignee: Denki Kagaku Kogyo Kabushiki Kaisha (TDK Corporation)
• Original Assignee: Denki Kagaku Kogyo Kabushiki Kaisha (TDK Corporation)
• Inventors: Nagasaka, Hideaki, Nakamura, Toshikazu, Michimori, Tooru
• Primary Examiner(s): Thibodeau, Paul J.
• Application Number:
  US07/294,998
• Time in Patent Office: 589 Days
• Field of Search: 428/694, 428/500, 428/900
• US Class Current: 428/836.3
• CPC Class Codes: G11B 5/64 comprising only the magnetic material without bonding agent
• CPC Class Codes: G11B 5/657 containing inorganic, non-oxide compound of Si, N, P, B, H or C, e.g. in metal alloy or compound containing oxygen G11B5/658
• CPC Class Codes: Y10S 428/90 Magnetic feature

Abstract

A magnetic recording medium is disclosed, which comprises a substrate having provided thereon a magnetic substance which is composed of an alloy comprising cobalt, phosphorus and at least one member selected from the group consisting of thallium and elements of group Vb of the periodic table, and optionally at least one member selected from the group consisting of nickel and zinc. The magnetic recording medium exhibits a high coercive force, squareness ratio and a high output with a small noise.

Claims

1. A magnetic recording medium, having a coercive force squareness ratio of not less than 0.90, comprising a substrate having provided thereon by electroless plating a magnetic substance which is composed of an alloy comprising cobalt, phosphorus and at least one element selected from the group consisting of thallium, bismuth, arsenic and antimony in an amount of at least 0.05 to about 5 atomic percent.

2. The magnetic recording medium as claimed in claim 1, wherein said alloy further comprises at least one member selected from the group consisting of nickel and zinc.

3. The magnetic recording medium as claimed in claim 1, wherein said alloy is composed of cobalt, phosphorus and thallium.

4. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, nickel and thallium.

5. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, thallium and zinc.

6. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, nickel, thallium and zinc.

7. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, 0 to 20 atomic % nickel and 0.5 to 5 atomic% thallium.

8. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, up to 20 atomic% nickel, 0.5 to 5 atomic% thallium, and zinc, wherein the content of said zinc results from the use of about 2×

10^-6 to 2×

10^-2 mol/l of zinc ion in an electroless plating bath.

9. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, nickel, and at least one element selected from the group consisting of thallium, bismuth, arsenic and antimony.

10. The magnetic recording medium as claimed in claim 1, wherein said at least one element is arsenic.

11. The magnetic recording medium as claimed in claim 9, wherein said at least one element is arsenic.

12. The magnetic recording medium as claimed in claim 1, wherein said at least one element is bismuth.

13. The magnetic recording medium as claimed in claim 9, wherein said at least one element is bismuth.

14. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, zinc and at least one element selected from the group consisting of thallium, bismuth, arsenic, and antimony.

15. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of cobalt, phosphorus, nickel, zinc and at least one element selected from the group consisting of thallium, bismuth, arsenic, and antimony.

16. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, up to 20 atomic% nickel and 0.5 to 5 atomic% arsenic.

17. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, up to 20 atomic% nickel and 0.5 to 5 atomic% bismuth.

18. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, up to nickel, 0.5 to 5 atomic% arsenic and zinc, wherein the content of said zinc results from the use of about 2×

10^-6 to 2×

10^-2 mol/l of zinc ion in an electroless plating bath.

19. The magnetic recording medium as claimed in claim 2, wherein said alloy is composed of 70 to 95 atomic% cobalt, 5 to 20 atomic% phosphorus, up to 20 atomic% of nickel, 0.5 to 5 atomic% bismuth and zinc, wherein the content of said zinc results from the use of about 2×

10^-6 to 2×

10^-2 mol/l of zinc ion in an electroless plating bath.

20. The magnetic recording medium as claimed in claim 1, wherein said magnetic substance on said substrate is composed of an alloy comprising cobalt, phosphorus and at least one element selected from the group consisting of thallium, bismuth and arsenic.

21. The magnetic recording medium as claimed in claim 1, wherein said coercive force squareness ratio is in the range of about 0.90 to 0.93 .