Metal-air battery with easily removable anodes

• US 4,950,561 A
• Filed: 06/29/1989
• Issued: 08/21/1990
• Est. Priority Date: 06/29/1989
• Status: Expired due to Fees

• Current Assignee: Eltech Systems Corporation Town Executive Center
• Original Assignee: Eltech Systems Corporation (Industrie De Nora S.p.A)
• Inventors: Sovich, Thomas J., Noscal, Jay M, Nikasa, Marilyn J., Niksa, Andrew J.
• Primary Examiner(s): Walton, Donald L.
• Application Number:
  US07/373,362
• Time in Patent Office: 418 Days
• Field of Search: 429/27, 429/28
• US Class Current: 429/404
• CPC Class Codes: H01M 12/065 with plate-like electrodes or stacks of plate-like electrodes
• CPC Class Codes: H01M 2004/024 Insertable electrodes
• CPC Class Codes: H01M 4/8626 characterised by the form
• CPC Class Codes: H01M 50/184 characterised by their shape or structure
• CPC Class Codes: H01M 50/193 Organic material
• CPC Class Codes: H01M 50/463 Separators, membranes or diaphragms characterised by their shape
• CPC Class Codes: H01M 50/50 Current conducting connections for cells or batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

The present inveniton resides in a metal-air battery consisting of one or more cells. Each cell comprises a cell frame. An air cathode is attached to each face of the frame. An anode blank is inserted through an access opening in the frame into the space between the cathodes. The anode blank comprises an elastomeric rubber labyrinth seal molded to the blank and sealing the access opening. Means may be provided for circulating electrolyte into an out of the spaces between the anode and air cathodes. A preferred electrolyte is an aqueous solution of an alkali hydroxide.

Claims

1. A metal-air battery comprising:

one or more cells;

each cell comprising;

a frame having opposed faces;

an air cathode sealed to each face of said frame;

an access opening in said frame;

an anode blank comprising a consumable end inserted through said access opening into the space between said air cathodes and an exposed end protruding from said opening for replacement of the anode blank through said opening; and

a labyrinth seal molded directly onto the anode blank between said consumable end and said exposed end sealing said access opening.

2. The metal-air battery of claim 1, wherein said seal is an elastomeric rubber material which is vulcanized directly onto the anode blank.

3. The metal-air battery of claim 2, wherein said seal has a cross-section comprising a main body portion extending circumferentially around the anode blank pressing against the anode blank and a plurality of circumferentially extending tapered lobes emanating from the exposed surface of said body portion, said lobes having an apex pressing against said frame opening, said lobes being tapered in a direction which reduces the amount of force required to press the anode blank into the frame opening.

4. The metal-air battery of claim 3, in which said taper resists withdrawal of the anode blank through said frame opening.

5. The metal-air battery of claim 1, wherein said anode blank is selected from the group consisting of zinc, iron, beryllium, cadmium, magnesium, lithium, lead and aluminum, and said battery contains an electrolyte which is a saline electrolyte or an aqueous solution of an alkali hydroxide.

6. The metal-air battery of claim 1, comprising means for circulating said electrolyte through said cells.

7. The metal-air battery of claim 1 comprising:

a plurality of cells;

each cell anode blank exposed end defining an anode contact edge;

a cathode bus having at least a section disposed to one side of said anode contact edge; and

means connecting said air cathodes to said cathode bus;

the anode contact edges and cathode bus sections of said cells all lying at least substantially in the same plane.

8. The metal-air battery of claim 7 comprising an elongated inter-electrode buswork removably attached to said battery;

a plurality of spaced-apart contact plates positioned longitudinally along said buswork;

each contact plate being positioned so that it bridges the gap between the anode contact edge of one cell and the cathode bus section of an adjacent cell electrically connecting the anode contact edge of one cell with the cathode bus section of an adjacent cell thus connecting the cells in series.

9. A metal-air battery of claim 1 comprising:

a plurality of cells;

means affixing said cell frames together;

means defining inter-cell spaces for access of air to said air cathodes;

a cathode frame for each air cathode positioned on the air side of each air cathode; and

reinforcing ribs in said cathode frame extending across the face of each air cathode.

10. A metal-air battery comprising:

a plurality of adjacent aligned cells;

a cathode bus for each cell, each cathode bus having at least a section which is aligned in the same plane with all such bus sections for each cell;

an anode blank; and

means replaceably positioning said anode blanks within said cell electrolyte chambers so that the anode blanks comprise ends protruding from said chambers an equal amount, the anode ends comprising contact edges in the same plane with said cathode bus sections.

11. The battery of claim 10 further comprising an inter-electrode buswork comprising an elongated terminal block assembly and a plurality of contact plates positioned on said assembly to electrically connect the anode contact edge of one cell with the cathode bus section of an adjacent cell.

12. The battery of claim 11, wherein said cathode buses have a handlebar configuration comprising a center section in the same plane with the anode contact edges and leg sections extending from said center section, the leg sections embracing opposite sides of cell frames having opposed faces with air cathodes sealed to said faces, said air cathodes comprising tab portions electrically connecting the air cathodes with said leg sections.

13. The battery of claim 12, wherein said air cathodes comprise a current collector surface, said tab portions being metallic current-carrying extensions of said air cathode current collector surfaces.

14. In a metal-air battery comprising a plurality of adjacent cells, each cell comprising a frame having opposed faces, air cathodes sealed to said faces, said frame and air cathodes defining an electrolyte chamber, and an anode blank replaceably positioned within said electrolyte chamber, the improvement comprising:

an opening in said frame to receive said anode blank;

a labyrinth seal of elastomeric rubber material vulcanized to said anode blank, said seal comprising a plurality of tapered lobes pressing against the frame opening sealing said opening;

means for circulating electrolyte into and out of said chamber.

15. The metal-air battery of claim 14, wherein said labyrinth seal has a cross-section defining a body portion engaging the anode surface, said plurality of lobes protruding from said body portion and being tapered with the apex of each lobe pressing against said frame opening.

16. The metal-air battery of claim 15, wherein the taper of each lobe is more pronounced in the direction of insertion of an anode into an electrolyte chamber than in the direction of withdrawal to reduce the amount of force required to press the anode blank into the frame opening.

17. In a cell adapted for use in a metal-air battery, said cell containing a frame and an air cathode with said frame and air cathode defining an electrolyte chamber for an anode blank to be positioned within said electrolyte chamber, the improvement comprising:

an elastomeric rubber gasket positioned within said electrolyte chamber for contact with an edge of said anode blank, said gasket comprising a plurality of lobes pressing against said anode edge for providing secure seating of said anode blank with said electrolyte chamber.

18. In a metal-air battery comprising a plurality of adjacent cells, each cell containing a frame and an air cathode, with said frame and air cathode defining an electrolyte chamber, and an anode blank positioned within said electrolyte chamber, the improvement comprising:

an anode blank exposed end protruding from said electrolyte chamber and terminating in an anode contact edge;

a cathode bus for each cell, said cathode bus having an at least generally U-shaped configuration with a center section and legs at opposite ends of said center section; and

an inter-electrode buswork, said buswork comprising an elongated terminal block assembly and a plurality of contact plates spaced longitudinally along said terminal block assembly, said contact plates being positioned on said assembly to electrically connect the anode contact edge of one cell with the cathode bus center section of an adjacent cell.

19. A metal-air battery comprising:

one or more cells, each cell comprising;

a rectangular frame having opposed faces;

a rectangular air cathode sealed to each face of said frame;

said frame and air cathodes defining an electrolyte chamber;

an access opening in said frame;

a rectangular anode blank comprising a consumable end inserted through said access opening into the space between said air cathodes and an exposed end protruding from said opening for replacement of the anode blank through said opening;

a seal sealing said opening;

said anode blank exposed end defining an anode contact edge;

a cathode bus having a U-shaped configuration comprising a center section and spaced apart bus legs in a plane at right angles to said center section, said legs embracing opposite sides of said frame, the cathode bus comprising bends between said legs and center section whereby said center section is displaced from the plane of said legs; and

means electrically connecting said air cathodes to said cathode bus legs.

20. The battery of claim 19, wherein said seal is an elastomeric rubber labyrinth seal molded onto said anode blank sealing said frame opening.

21. The battery of claim 19, wherein said cathode bus legs are in essentially the same plane with the anode contact edge, said cathode bus center section being parallel with but displaced to one side of the anode contact edge.

22. The battery of claim 19, wherein said air cathodes comprise current collector surfaces and said means connecting said air cathodes to said cathode bus legs comprise tab portions which are metallic current collecting extensions of said air cathode current collector surfaces.

23. A metal-air battery comprising:

a plurality of adjacent aligned cells;

each cell comprising a frame having opposed faces;

air cathodes sealed to said faces;

said frame and air cathodes defining an electrolyte chamber;

a cathode bus for each cell, said cathode bus having a U-shaped configuration with a center section and legs at opposite ends of said center section embracing sides of said frame;

said center sections lying in the same plane;

each air cathode comprising a current collecting screen;

means electrically connecting said current collecting screens with said cathode bus legs;

an anode blank; and

means removably positioning said anode blanks within said cell electrolyte chambers so that the anode blanks comprise ends protruding from said chambers an equal amount, the anode ends comprising contact edges in the same plane with said cathode bus center sections;

the cathode bus center sections being offset to one side of the anode contact edges.

24. The battery of claim 23 comprising an inter-electrode buswork, said buswork comprising an elongated terminal block assembly and a plurality of contact plates spaced longitudinally along said terminal block assembly, said contact plates being positioned on said assembly to electrically connect the anode contact edge of one cell with the cathode bus center section of an adjacent cell.

25. In a cell adapted for use in a metal-air battery, said cell containing a frame and an air cathode, with said frame and air cathode defining an electrolyte chamber for an anode blank to be positioned within said electrolyte chamber, the improvement comprising:

means attaching said air cathode to said frame, said attachment means comprising a first surface attached to said frame around the periphery thereof, a second surface attached to said air cathode around the periphery thereof, and an annular expandable section intermediate said first and second surfaces in the shape of a bellows, said attachment means allowing the movement of said air cathode in the direction of said anode.

26. The battery of claim 25, wherein said cell contains a separator between the anode and air cathode.

27. The battery of claim 26, wherein said separator comprises an open mesh screen resistant to electrolyte having nodules at the intersections of the mesh strands which have a diameter greater than the diameter of the mesh strands.

28. The battery of claim 25, further comprising a cathode bus, wherein said attachment means is a metal foil, said second surface being electrically connected with an air cathode current collector screen, said first surface being electrically connected to said cathode bus.

29. The battery of claim 28, wherein said first surface is attached to said frame in sealing relationship therewith and said second surface is attached to said air cathode in sealing relationship therewith.

30. An anode blank for a metal-air battery, said anode blank comprising a consumable end and an exposed end, said exposed end being adapted for protruding from an opening in a cell of said battery upon insertion of said anode blank in said cell, said anode blank having a seal molded directly onto said blank intermediate said consumable end and said exposed end, with said seal comprising a main body portion extending circumferentially around the anode blank pressing against said anode blank.

31. The anode blank of claim 30, wherein said anode seal is a labyrinth seal and said main body portion has a plurality of circumferentially extending tapered lobes emanating from said main body portion, with said lobes being tapered toward said consumable end.

32. The anode blank of claim 30, wherein said exposed end comprises about 5 to 30 percent of the length of said anode blank.

33. The anode blank of claim 30, wherein said labyrinth seal is an elastomeric rubber seal vulcanized directly onto said anode blank.

34. In a metal-air battery comprising a plurality of adjacent cells each having an electrolyte chamber with an anode blank having an exposed end protruding from said electrolyte chamber and terminating in an anode contact edge, with each cell containing a cathode bus having a post section at least substantially adjacent said anode contact edge, and with there being an intercell bus connector between a cathode bus post section for at least one cell and an anode contact edge of an adjacent cell, the improvement comprising:

an elongated intercell spring clip bus connector having in cross-section, an at least substantially U-shaped center section of a curved portion with two extending side legs, with one side leg of said U-shaped center section forming a side leg from an adjacent, at least substantially hairpin shaped side section of said bus connector, and with the other side leg of said U-shaped center section extending curvilinearly to provide a curved side section of non-hairpin shape for said spring clip.