Process for washing and obtaining solids of slurry

• US 4,950,805 A
• Filed: 02/14/1989
• Issued: 08/21/1990
• Est. Priority Date: 02/19/1988
• Status: Expired due to Term

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Kitamura, Takashi, Morimoto, Yoshio, Iimuro, Shigeru
• Primary Examiner(s): LONE, WERREN
• Application Number:
  US07/310,345
• Time in Patent Office: 553 Days
• Field of Search: 568/722, 568/724, 568/727, 568/728
• US Class Current: 568/724
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

A process for washing and obtaining solids of a slurry comprises feeding a slurry containing the adduct of bisphenol A with phenol crystallized from a phenol solution of bisphenol A to a first solid-liquid separator to separate solids from the slurry, transferring the solids separated by the first solid-liquid separator to an agitation tank in which the solids are reslurried, feeding the slurry obtained in the agitation tank to a second solid-liquid separator, said second solid-liquid separator being intended to obtain the solids from the slurry discharged from the agitation tank, and permitting the admission of a washing solvent to wash the solids, and permitting the filtrate and washings to be recovered independently, feeding the washing solvent to the second solid-liquid separator, feeding all of the washings from the second solid-liquid separator to the agitation tank, feeding a part of the filtrate from the second solid-liquid separator to the agitation tank, and discharging the remainder of the filtrate from the system. The process makes it possible to produce a high-purity adduct of bisphenol A with phenol and hence high-purity bisphenol A.

Claims

1. A process for washing and obtaining solids of a slurry which comprises feeidng a slurry containing the adduct of bisphenol A with phenol crystallized from a phenol solution fo bisphenol A to a first solid-liquid separator to separate solids from the slurry, transferring the solids separated by the first solid-liquid separator to an agitation tank in which the solids are reslurried, feeding the slurry obtained in the agitation tank to a second solid-liquid separator, said second solid-liquid separator being intended to obtian the solids from the slurry discharged from the agitation tank, and permitting the admission of a washing solvent consisting of phenol or water-containing phenol at a temperature of 35°

to 45°

C. to wash the solids, and permitting the filtrate and washings to be recovered independently, feeding the washing solvent to the second solid-liquid separator, feeidng all of the washings from the second solid-liquid separator, feeding all of the washings from the second solid-liquid separator to the agitation tank, feeding a part of the filtrate from the second solid-liquid separator to the agitation tank, and discharging the remainder of the filtrate from the system.

2. A process as claimed in claim 1, wherein the washing solvent is phenol at a temperature of 40°

to 45°

C.

3. A process as claimed in claim 1, wherein the washing solvent is water-containing phenol at a temperature of 35°

to 45°

C.

4. A process as claimed in claim 1, wherein the slurry formed in the agitation tank contains 30 to 50 wt% of solids.

5. A process as claimed in claim 1, wherein the washing solvent is used in a total amount which is less than 60 wt% of the total amount of the adduct crystals to be washed.