Process for crystallizing adduct of bisphenol A with phenol

• US 4,950,806 A
• Filed: 02/17/1989
• Issued: 08/21/1990
• Est. Priority Date: 02/22/1988
• Status: Expired due to Term

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals)
• Original Assignee: Mitsui Toatsu Chemicals Incorporated (Mitsui Chemicals)
• Inventors: Kitamura, Takashi, Morimoto, Yoshio, Iimuro, Shigeru
• Primary Examiner(s): LONE, WERREN
• Application Number:
  US07/311,844
• Time in Patent Office: 550 Days
• Field of Search: 568/724, 568/722, 568/727
• US Class Current: 568/724
• CPC Class Codes: C07C 37/84 by crystallisation
• CPC Class Codes: C07C 39/16 Bis-(hydroxyphenyl) alkanes; Tris-(hydroxyphenyl)alkanes

Abstract

A process for crystallizing the adduct of bisphenol A with phenol from a phenol solution in the presence of water comprises controlling the concentration of bisphenol A in said solution by removing portion of the phenol from said solution or adding phenol to said solution according to feedback control based on the measurement of solution density to obtain an adjusted solution, and feeding the adjusted solution to the crystallizer in which its inside wall is kept at a temperature higher than that of the adjusted solution, provided the temperature difference being smaller than 5° C. The crystallized adduct has a uniform particle size and a high purity.

Claims

1. A process for crystallizing an adduct of bisphenol A with phenol from a phenol solution of bisphenol A in the presence of water, said process comprising the steps of controlling the concentration of bisphenol A in said solution by removing a portion of the phenol from said solution or adding phenol to said solution according to feedback control based on the measurement of solution density to obtain an adjusted solution containing from 20 to 50 wt. % of bisphenol A, and feeding the adjusted solution to the crystallizer to form a content solution having a temperature of 35 to 70°

C. and maintaining the inside wall of the crystallizer at a temperature higher than that of the content solution, provided the temperature difference is smaller than 5°

C.

2. A process as claimed in claim 1, wherein the adjusted solution contains 30 to 45 wt. % of bisphenol A.

3. A process as claimed in claim 1, wherein the crystallizer is of Draft-tube type and wall surfaces of the Draft-tube are also kept at a temperature higher than the temperature of the content solution, with the temperature difference being smaller than 5°

C.