Magneto-optical recording element and method for fabrication thereof

• US 4,954,232 A
• Filed: 05/26/1989
• Issued: 09/04/1990
• Est. Priority Date: 07/09/1984
• Status: Expired due to Term

• Current Assignee: Kyocera Corporation
• Original Assignee: Kyocera Corporation
• Inventors: Yamada, Takashi, Maeda, Takashi, Arimune, Hisao
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): MARQUIS, STEVEN
• Application Number:
  US07/358,554
• Time in Patent Office: 466 Days
• Field of Search: 204/192.15, 204/192.2, 204/192.22, 204/192.23, 204/298 TC, 437/241
• US Class Current: 204/192.23
• CPC Class Codes: G03G 5/16 Layers for recording by changing the magnetic properties, e.g. for Curie-point-writing
• CPC Class Codes: G11B 11/10586 characterised by the selection of the material
• CPC Class Codes: G11B 11/10591 for improving write-in properties, e.g. Curie-point temperature
• CPC Class Codes: G11B 5/7262 Inorganic protective coating
• CPC Class Codes: G11B 5/7368 Non-polymeric layer under the lowermost magnetic recording layer base layers having a non-magnetic layer under a soft magnetic layer G11B5/736; magnetic recording media substrates G11B5/739
• CPC Class Codes: G11B 5/73923 Organic polymer substrates

Abstract

In a magneto-optical recording element comprising a substrate, a magnetic layer and a dielectric layer, the dielectric layer is formed by deposition of a composition comprising Si₃ N₄ and a refractive index-improving agent such as Al₂ O₃ or Y₂ O₃. This dielectric layer has a high refractive index and the enhancement effect is improved. Moreover, this dielectric layer is excellent in the adhesion and resistance characteristics.

Claims

1. A method for the fabrication of a magneto-optical recording element, which comprises maintaining a substrate on which a film is to be formed, a first target composed of a sintered composition comprising (a) silicon nitride and (b) at least one additive selected from the group consisting of single elements, oxides, nitrides, sulfides and silicides of elements of the groups IIIa, IVa, IIb, IIIb, IVb and VIb of the Periodic Table and a second target composed of a magnetic layer-forming metal in an inert gas atmosphere maintained at 1×

10^-3 to 50×

10^-3 Torr and forming a magnetic layer and a dielectric layer alternately on the substrate by sputtering, wherein said additive (b) is contained in the first target in an amount of 4 to 20 mole %.

2. The method of claim 1 wherein at least the substrate and first target are exposed to a vacuum of less than 1×

10^-5 Torr, prior to maintaining said substrate, first target and second target in an inert gas atmosphere.

3. A method for fabrication of a magneto-optical recording element, the sequential steps of the method comprising:

(a) providing a substrate on which a film is to be formed, a first target composed of a sintered composition comprising (i) silicon nitride and (ii) at least one additive selected from the group consisting of single elements, oxides, nitrides, sulfides, and silicides of elements of the groups IIIa, IVa, VIa, IIb, IIIb, IVb and VIb of the Periodic Table and a second target composed of a magnetic layer-forming metal, said additive (b) being contained in the first target in an amount of 4 to 20 mole %;

(b) maintaining the substrate, the first target and the second target in an inert gas atmosphere maintained at 1×

10^-3 to 50×

10^-3 Torr;

(c) applying a high-frequency electric power or direct current between the first target and the substrate to form a first dielectric layer; and

(d) applying a high-frequency or direct current electric power between the second target and the substrate to form a magnetic layer.

4. The method of claim 3 wherein at least the substrate and first target are exposed to a vacuum of less than 1×

10^-5 Torr, prior to maintaining said substrate, first target and second target is an inert gas atmosphere.

5. The method of claim 3, further comprising the step of (b) applying a high frequency or direct current electric power between the first target and the substrate to form a second dielectric layer.

6. The method of claim 3 wherein the inert gas atmosphere is maintained at 3×

10^-3 to 20×

10^-3 Torr.

7. The method of claim 3 wherein the additive is present in the first target in an amount of 0.5 to 8.0 mole percent based on the first target.

8. The method of claim 3 wherein the sputtering is high-frequency sputtering.

9. The method of claim 3 wherein the first target comprises 0.1 to 5.0 mole % of alumina or aluminum nitride and 0.1 to 3.0 mole % of an oxide or nitride of a rare earth element.

10. The method of claim 3 wherein the substrate is composed of transparent plastic material.

11. The method of claim 3 wherein the magnetic layer is composed of an amorphous alloy magnetic material.

12. The method of claim 3 wherein the additive is at least one member selected from the group consisting of Al, Ti, Si, Ge, Al₂ O₃, Y₂ O₃, La₂ O₃, CeO₂, Bi₂ O₃, GeO₂, ZrO₂, CdO, Cr₂ O₃, SnO₂, PbO, AlN, TiN, YN, ZnS, Sb₂ S₃, TiSi₂ and YSi₂.