Aromatic polyetherketone fiber product

• US 4,954,605 A
• Filed: 03/31/1989
• Issued: 09/04/1990
• Est. Priority Date: 05/10/1985
• Status: Expired due to Term

• Current Assignee: Invista North America Sarl (Invista)
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Deeg, Martin H. G.
• Primary Examiner(s): Foelak, Morton
• Assistant Examiner(s): HAMPTON HIGHTOWER, PATRICIA
• Application Number:
  US07/332,532
• Time in Patent Office: 522 Days
• Field of Search: 528/125, 528/126, 528/128, 528/219, 264/176.1, 264/211.22, 264/205, 428/364
• US Class Current: 528/125
• CPC Class Codes: D01D 1/106 Filtering
• CPC Class Codes: D01F 6/665 from polyetherketones, e.g. PEEK
• CPC Class Codes: Y10T 428/2913 Rod, strand, filament or fiber

Abstract

Filaments are produced from polymers having an inherent viscosity of at least 0.7 measured in concentrated sulfuric acid and containing in the polymer chain at least 50 percent of the repeating units. ##STR1## by melting the polymer and heating the melt to a temperature of from about 20° C. to about 80° C. above the melting point of the polymer, passing the melt through a filter pack having a filtering area of at least about 8 in² and a total volume of at least about 1.2 in³ per pound of polymer extruded per hour, and containing inert, irregularly shaped particles having a mesh size of about 25 to 140 to provide a pressure drop at least about 800 psig., and extruding the melt through spinning openings of desired shape to form filaments. The process is capable of producing fibers and yarns having a dpf of about 15 to 100, a tenacity of about 1 to 2 grams per denier, an elongation at break of about 50 to 160 percent and a modulus of about 20 to 30 grams per denier.

Claims

1. Multifilament and yarns of a polymer having an inherent viscosity of at least 0.7 measured in concentrated sulfuric acid, said polymer containing in the polymer chain at lease 50 percent of the repeating units:

##STR10## said fibers and yarns having at least ten filaments and a dpf of about 15 to 100, a tenacity of about 1 to 2 grams per denier, an elongation at break of about 50 to 160 percent, and a modulus of about 20 to 30 grams per denier.

2. The yarns of claim 1 wherein said polymer consists solely of said repeating units in the polymer chain.

3. The fibers and yarns of claim 2 wherein the individual fibers having a birefringence of about 25 to 150.