Electroconductive copolymers
First Claim
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1. A copolymer of an aniline monomer of the general formula:
- ##STR4## where R is in the ortho- or meta- position and is selected from the group consisting of hydrogen, C1-18 alkyl, C1-6 alkoxy, amino, chloro, bromo, sulpho, carboxy, hydroxy and the group ##STR5## where R" is selected from the group consisting of alkyl and aryl; and
R'"'"' is selected from the group consisting of hydrogen, C1-6 alkyl and aryl;
with at least one other aniline monomer of formula I as defined above, the copolymer including counterions X where X is selected from the group consisting of C1-, Br-, SO4=, BF4=, PF6=, H2 PO3-, H2 PO4-, arylsulphonate, arenedicarboxylate, arenecarboxylate, polystyrene sulphonate, polyacrylate, alkylsulphonate, vinylsulphonate, vinylbenzene sulphonate, cellulose sulphonate, cellulose sulphate and a perfluorinated polyanion.
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Abstract
A copolymer of an aniline monomer of the general formula: ##STR1## where R and R'"'"' are certain specified substituents with another aniline monomer of formula I, the copolymer including counterions X therein. These copolymers are electroconductive.
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6 Claims
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1. A copolymer of an aniline monomer of the general formula:
- ##STR4## where R is in the ortho- or meta- position and is selected from the group consisting of hydrogen, C1-18 alkyl, C1-6 alkoxy, amino, chloro, bromo, sulpho, carboxy, hydroxy and the group ##STR5## where R" is selected from the group consisting of alkyl and aryl; and
R'"'"' is selected from the group consisting of hydrogen, C1-6 alkyl and aryl;
with at least one other aniline monomer of formula I as defined above, the copolymer including counterions X where X is selected from the group consisting of C1-, Br-, SO4=, BF4=, PF6=, H2 PO3-, H2 PO4-, arylsulphonate, arenedicarboxylate, arenecarboxylate, polystyrene sulphonate, polyacrylate, alkylsulphonate, vinylsulphonate, vinylbenzene sulphonate, cellulose sulphonate, cellulose sulphate and a perfluorinated polyanion. - View Dependent Claims (2, 3, 4, 5)
- ##STR4## where R is in the ortho- or meta- position and is selected from the group consisting of hydrogen, C1-18 alkyl, C1-6 alkoxy, amino, chloro, bromo, sulpho, carboxy, hydroxy and the group ##STR5## where R" is selected from the group consisting of alkyl and aryl; and
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6. A copolymer of an aniline monomer of the general formula:
- ##STR6## where R is in the ortho- or meta- position and is selected from the group consisting of hydrogen, C1-18 alkyl, C1-6 alkoxy, amino, chloro, bromo, sulpho, carboxy, hydroxy and the group ##STR7## where R" is selected from the group consisting of alkyl and aryl; and
R'"'"' is selected from the group consisting of hydrogen, C1-6 alkyl and aryl;
with at least one other aniline monomer of formula I as defined above, the copolymer including organosulphonate counterions.
- ##STR6## where R is in the ortho- or meta- position and is selected from the group consisting of hydrogen, C1-18 alkyl, C1-6 alkoxy, amino, chloro, bromo, sulpho, carboxy, hydroxy and the group ##STR7## where R" is selected from the group consisting of alkyl and aryl; and
Specification