Thermochromic color masterbatch

• US 4,957,949 A
• Filed: 10/28/1988
• Issued: 09/18/1990
• Est. Priority Date: 10/29/1987
• Status: Expired due to Term

• Current Assignee: Matsui Shikiso Chemical Company Limited 29 Nishinorikyucho Yamashina-Ku Kyoto-Shi Kyoto-Fu Japan
• Original Assignee: Matsui Shikiso Chemical Co., Ltd.
• Inventors: Kobayashi, Tadashi, Shimizu, Goro, Maeda, Toshihisa, Kamada, Masayasu
• Primary Examiner(s): Lieberman, Allan M.
• Application Number:
  US07/263,755
• Time in Patent Office: 690 Days
• Field of Search: 523/351, 523/201, 523/206, 523/205, 523/207, 428/407, 524/487, 524/488, 524/277
• US Class Current: 523/201
• CPC Class Codes: C08J 2425/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
• CPC Class Codes: C08J 2491/00 Characterised by the use of oils, fats or waxes; Derivatives thereof
• CPC Class Codes: C08J 3/226 using a polymer as a carrier

Abstract

Disclosed is a thermochromic color masterbatch for use in a thermoplastic resin comprising a wax having substantially homogeneously dispersed therein a thermochromic granular material which is coated with a hydrophilic high-molecular weight substance, said thermochromic granular material being a mixture of a thermochromic composition comprising an electron-donating chromogen, an electron acceptor and a solvent with a thermosetting resin.

Claims

1. A thermochromic color masterbatch for use in a thermoplastic resin comprising a wax having substantially homogeneously dispersed therein a thermochromic granular material, said thermochromic granular material being a mixture of a thermochromic composition comprising 2 to 20% by weight of an electron donating chromogen, 4 to 40% by weight of an electron acceptor, and an alcohol, ester, azomethine or amide solvent having a boiling point 150°

C. or higher, with 10 to 40 parts by weight of a thermosetting resin per 100 parts by weight of said thermochromic composition, said thermochromic graular material being coated with about 5-30 parts by weight per 100 parts by weight of said thermochromic composition with a hydrophilic high-molecular weight substance coagulable by means of an acid, an alkaline electrolyte, a heavy metal, an aldehyde or a zwitterion;

said masterbatch containing 100-500 parts by weight of said wax per 100 parts by weight of said thermochromic granular material.

2. The color masterbatch according to claim 1 wherein the wax has a melting point of 50°

-180°

C., and a melt viscosity of 100-50,000 cps.

3. The color masterbatch according to claim 2, wherein the wax has a melting point of 70°

-150°

C., and a melt viscosity of 500-20,000 cps.

4. The color masterbatch according to claim 1 wherein the wax is at least one species selected from the group consisting of paraffin wax, microcrystalline wax, montan wax, carnauba wax, polystyrene wax, polyethylene wax, polypropylene wax, beeswax and anhydrous lanolin.

5. The color masterbatch according to claim 1, which contains 200-400 parts by weight of the wax per 100 parts of the coated thermochromic granular material.

6. The color masterbatch according to claim 1, in which said coated thermochromic granular material is substantially homogeneously dispersed in a mixture of the wax and up to 800 parts by weight per 100 parts by weight of the coated thermochromic granular material of a thermoplastic resin.

7. The color masterbatch according to claim 6, wherein the thermoplastic resin has a melt flow rate of at least 10 g/10 minutes.

8. The color masterbatch according to claim 7, wherein the thermoplastic resin is a polystyrene resin or polyolefin resin.

9. The color masterbatch according to claim 8 wherein the polystyrene resin is at least one polymer selected from the group consisting of polystyrene and copolymers of styrene and at least one monomer copolymerizable therewith.

10. The color masterbatch according to claim 7 wherein the polyolefin resin is at least one polymer selected from the group consisting of homopolymers of olefins and copolymers of olefins and at least one monomer copolymerizable therewith.

11. The color masterbatch according to claim 6 wherein a wax combined with a polystyrene resin is at least one species selected from the group consisting of paraffin wax, microcrystalline wax, polystyrene wax, montan wax and carnauba wax.

12. The color masterbatch according to claim 6 wherein a wax combined with a polyolefin resin is at least one species selected from the group consisting of paraffin wax, microcrystalline wax, polyethylene wax, polypropylene wax, montan wax, carnauba wax, beewax and anhydrous lanolin.

13. A shaped thermoplastic resin produced by admixing a thermoplastic resin with a color masterbatch of claim 1 and shaping the mixture into a desired shape.