Multistage process for producing polycarbonate from oligomer

• US 4,959,456 A
• Filed: 04/28/1989
• Issued: 09/25/1990
• Est. Priority Date: 04/29/1988
• Status: Expired due to Term

• Current Assignee: Idemitsu Kosan Company Limited
• Original Assignee: Idemitsu Petrochemical Co., Ltd. (Idemitsu Kosan Company Limited)
• Inventors: Yamamoto, Koji, Ashida, Takashi, Kunishi, Noriyuki
• Primary Examiner(s): ANDERSON, HAROLD
• Application Number:
  US07/344,602
• Time in Patent Office: 515 Days
• Field of Search: 528/371, 528/370, 528/198, 526/65
• US Class Current: 528/371
• CPC Class Codes: C08G 64/20 General preparatory processes

Abstract

A process for producing polycarbonate from a polycarbonate oligomer and a phenol compound, comprising introducing the oligomer, caustic alkali and the phenol compound in the first reaction zone where polymerization is carried out to produce polycarbonate having a viscosity average molecular weight of 3,000 to 15,000, and then introducing the reaction mixture containing the above polycarbonate into the second reaction zone where polymerization is carried out while controlling the alkali concentration to the range of 0.05 to 0.7N by regulating caustic alkali supplied.

Claims

1. A process for producing polycarbonate by reacting a polycarbonate oligomer and a phenol compound in the presence of caustic alkali, which process comprises introducing the polycarbonate oligomer, caustic alkali and the phenol compound, the equivalent ratio of alkali to hydroxyl group in the phenol compound (alkali/hydroxyl group) being 0.9:

1 to 1.8;

1, in a first reaction zone where polymerization is carried out to produce polycarbonate having a viscosity average molecular weight of 3,000 to 15,000, and then introducing a reaction mixture containing the polycarbonate as produced in the first reaction zone into a second reaction zone where polymerization is carried out while adjusting the alkali concentration in the second reaction zone to 0.05 to 0.7N by regulating caustic alkali supplied.

2. The process as claimed in claim 1, wherein after polymerization in the first reaction zone, caustic alkali is supplied to the first reaction zone to adjust the caustic alkali concentration to 0.05 to 0.7N.

3. The process as claimed in claim 1, wherein polymerizations in the first reaction zone and the second reaction zone are carried out in different reactors.

4. The process as claimed in claim 1, wherein polymerizations in the first reaction zone and the second reaction zone are carried out in the presence of a solvent.

5. The process as claimed in claim 1, wherein polymerization in the first reaction zone or the second reaction zone is carried out in a reactor selected from line mixer, orifice mixer, static mixer or stirring vessel.

6. The process as claimed in claim 1, wherein polymerization in the first reaction zone is carried out at a temperature of 10°

to 50°

C.

7. The process as claimed in claim 1, wherein polymerization in the second reaction zone is carried out at a temperature of 10°

to 50°

C.

8. The process as claimed in claim 1, wherein the polycarbonate oligomer has a number average molecular weight of 300 to 2,500.