Absorbent composition containing a severely-hindered amine mixture with amine salts and/or aminoacid additives for the absorption of H.sub.2 S

• US 4,961,873 A
• Filed: 08/24/1989
• Issued: 10/09/1990
• Est. Priority Date: 10/13/1987
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Sartori, Guido, Ho, W. S. Winston, Stogryn, Eugene L.
• Primary Examiner(s): Miller, Edward A.
• Application Number:
  US07/398,346
• Time in Patent Office: 411 Days
• Field of Search: 252/182.14, 252/182.17, 252/189, 252/190
• US Class Current: 252/189
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents

Abstract

The present invention relates to a new alkaline absorbent solution that reduces the H₂ S content in a treated gas to below 10 vppm. The absorbent solution contains two severely-hindered amines, such as bis(tertiarybutylaminoethoxy)-ethane (BTEE) and ethoxyethoxyethanol-tertiarybutylamine (EEETB), a severely hindered amine salt, and/or a severely hindered aminoacid. This invention also describes a process for the removal of H₂ S from fluid mixtures using this absorbent solution to produce a very low level of H₂ S in the treated fluid. The process is also suitable for the selective removal of H₂ S from fluid mixtures comprising H₂ S and CO₂.

Claims

1. An absorbent composition comprising:

(1) a first severely hindered amine with the formula;

##STR7## (2) a second severely hindered amine with the formula;

##STR8## with x being an integer ranging from 2 to 6 and the weight ratio, in the mixture, of the first amine to the second amine ranging from 0.43;

1 to 2.3;

1,

(3) and an additive including;

(a) an amine salt, said amine salt being the reaction product of a severely hindered amino compound having a cumulative -E_s value greater than 1.75, and a component selected from the group consisting of an acid having at least one pKa of not more than about 7, a decomposable salt of an acid having at least one pKa of not more than 7, a compound capable of forming an acid having a pKa of not more than about 7 and mixtures thereof, said amine salt and said severely hindered amine mixture of (1) and (2) being present in said absorbent composition in a mole ratio of said amine salt to said severely hindered amine mixture of (1) and (2) of at least about 0.2;

1, when said amine salt is present and/or

(b) an aminoacid, said aminoacid being a severely hindered aminoacid having a cumulative -E_s value greater than 1.75, said aminoacid and said severely hindered amine mixture being present in said absorbent composition in a mole ratio of said aminoacid to said severely hindered amine mixture of at least about 0.01;

1 when said aminoacid is present.

2. The absorbent composition of claim 1 wherein said absorbent composition additionally comprises a liquid selected from the group consisting of water, an organic solvent and mixtures thereof.

3. The absorbent composition of claim 1 wherein said severely hindered amino compound of said amine salt is selected from the group consisting of a secondary amino ether alcohol, a di-secondary amino ether, and mixtures thereof.

4. The absorbent composition of claim 1 wherein said component reacted with said severely hindered amino compound is selected from the group consisting of sulfuric acid, phosphoric acid, phosphorous acid, pyrophosphoric acid, sulfurous acid, and mixtures thereof.

5. The absorbent composition of claim 1 wherein said component reacted with said severely hindered amino compound is selected from the group consisting of ammonium sulfate, ammonium sulfite, sulfur dioxide, ammonium phosphate and mixtures thereof.

6. The absorbent composition of claim 1 wherein said severely hindered aminoacid is selected from N-tertiarybutylalanine, N-tertiarybutylglycine, and their mixture.

7. The absorbent composition of claim 1 wherein said mole ratio of said amine salt or said aminoacid to said severely hindered amine mixture ranges from about 0.2:

1 to 4;

1.

8. The absorbent composition of claim 1 wherein said mole ratio of said amine salt or said aminoacid to said severely hindered amine mixture ranges from about 0.2:

1 to 1;

1.

9. The absorbent composition of claim 1 wherein said mole ratio of said amine salt or said aminoacid to said severely hindered amine mixture ranges from about 0.3:

1 to 1;

1.

10. The absorbent composition of claim 1 wherein said absorbent composition comprises water and wherein said amine salt is a non-volatile water soluble amine salt.

11. The composition of claim 1 wherein said first amine is:

##STR9##

12. The composition of claim 1 wherein said second amine is:

##STR10##