Process for preparing microporous membranes

• US 4,963,304 A
• Filed: 09/26/1988
• Issued: 10/16/1990
• Est. Priority Date: 09/26/1988
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Chau, C. C., Im, Jang-hi
• Primary Examiner(s): Lorin, Hubert C.
• Application Number:
  US07/249,034
• Time in Patent Office: 750 Days
• Field of Search: 264/49, 264/41, 264/171, 264/344, 264/211.19
• US Class Current: 264/49
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B29C 48/335 Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
• CPC Class Codes: B29C 48/362 using static mixing devices
• CPC Class Codes: B29C 48/71 for layer multiplication extrusion of multi-component articles B29C48/16
• CPC Class Codes: B29C 67/202 comprising elimination of a solid or a liquid ingredient
• CPC Class Codes: B29K 2105/0088 Blends of polymers
• CPC Class Codes: C08J 9/26 by elimination of a solid phase from a macromolecular composition or article, e.g. leaching out

Abstract

A process for preparing microporous membranes by coextruding a melt of a plurality of interdigitated layers of at least two polymers, one having preferential solubility over the other, dividing and reorienting the layers of said melt into discrete domains of random orientation, forming a thin membrane or like article and leaching the preferentially soluble polymer out of the resulting article.

Claims

1. A process for preparing a microporous membrane having a narrow pore size distribution and sharp size cutoff comprising:

forming a lamellar polymeric composition by dividing and reorienting a plurality of adjacent layers of polymeric materials, each layer comprising at least two different polymeric materials and having a thickness of from 0.03 to 5 microns to form discrete domains of said polymeric materials of random orientation, at least one of said different polymeric materials having a preferential solubility in a selected solvent with respect to at least one other of said different polymeric materials;

forming a melt composition of said lamellar polymeric composition into a thin solid structure;

contacting said solid unitary structure with an extraction medium which has a preferential solubility for at least one of said at least two different polymeric materials, whereby said preferentially soluble polymeric material is removed from said solid unitary structure to form a porous unitary structure; and

separating said extraction medium from said porous unitary structure.

2. A process according to claim 1 which includes forming each of said layers from a mixture of said at least two different polymeric materials.

3. A process according to claim 2 which includes forming each of said layers from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.

4. A process according to claim 3 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.

5. A process according to claim 4 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.

6. A process according to claim 5 wherein said first polymeric material comprises polyethylene and said second polymeric material comprises polystyrene.

7. A process according to claim 2 wherein said mixture of at least two polymeric materials comprises a mixture of polyethylene and polystyrene.

8. A process according to claim 1 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.

9. A process according to claim 8 wherein the amount of said preferentially soluble polymeric material is in the range from 30 to 85 volume percent.

10. A process according to claim 8 wherein the amount of said preferentially soluble polymeric material is in the range from 50 to 80 volume percent.

11. A process according to claim 8 which includes forming each of said layers from a mixture of said at least two different polymeric materials.

12. A process according to claim 11 which includes forming each of said layers from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.

13. A process according to claim 12 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.

14. A process according to claim 13 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.

15. A process according to claim 14 wherein said first polymeric material comprises polyethylene and said second polymeric material comprises polystyrene.

16. A process according to claim 11 wherein said mixture of at least two polymeric materials comprises a mixture of polyethylene and polystyrene

17. A process for preparing a microporous membrane comprising:

forming a melt blend comprising an admixture of at least two different polymeric materials, at least one of said different polymeric materials having a differential solubility in a selected solvent with respect to at least one other of said different polymeric materials;

forming said melt blend into a melt stream comprising a layered stream of a plurality of thin, substantially parallel layers, each layer comprising a blend of said different polymeric material and being from about 0.03 to about 5 microns in thickness;

passing said melt stream through a mixing means;

forming said mixed melt stream into a solid unitary structure;

contacting said solid unitary structure with an extraction medium which has a differential solubility for at least one of said at least two different polymeric materials whereby said preferentially soluble polymeric material is removed from said solid uniform structure to form a solid unitary microporous structure; and

separating said extraction medium from said unitary porous structure.

18. A process in accordance with claim 17 wherein said mixing means comprises a motionless mixer.

19. A process in accordance with claim 17 wherein said polymeric material comprises a mixture of polyethylene and polystyrene.

20. A process according to claim 17 wherein said melt blend comprising a admixture of at least two different polymeric materials is formed from a melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material.

21. A process according to claim 20 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.

22. A process according to claim 21 wherein said compatibilizing polymeric material comprises styrene-butadiene-styrene triblock copolymer.

23. A process according to claim 22 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.

24. A process according to claim 17 wherein the amount of said preferentially soluble polymeric material is in the range from 10 to 90 volume percent, based on the total volume of said differentially soluble polymeric materials.

25. A process according to claim 24 wherein the amount of said preferentially soluble polymeric material is in the range from 30 to 85 volume percent.

26. A process according to claim 25 wherein the amount of said preferentially soluble polymeric material is in the range from 50 to 80 volume percent.

27. The process of claim 17 wherein said melt blend is formed from another melt of at least one lamellar composition comprising a plurality of thin layers of a first polymeric material interdigitated with thin layers of a second and different polymeric material, where said another melt has been passed through said motionless mixer prior to recoextruding.

28. A process according to claim 27 which includes providing a compatibilizing polymeric material interdigitated between each layer of said first and second polymeric materials of said one lamellar composition.