Thermo-shrinkable polyester type film and tube and processing method for preparing the tube

• US 4,963,418 A
• Filed: 01/26/1989
• Issued: 10/16/1990
• Est. Priority Date: 07/31/1985
• Status: Expired due to Term

• Current Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Isaka, Tsutomu, Yamashita, Toshihiro
• Primary Examiner(s): SEIDLECK, JAMES J
• Application Number:
  US07/301,827
• Time in Patent Office: 628 Days
• Field of Search: 528/304, 528/308, 528/308.1, 528/308.2, 528/308.3, 528/271, 428/34.9, 428/480, 428/410, 264/289.6, 264/290.2, 156/218
• US Class Current: 428/34.9
• CPC Class Codes: B29C 61/003 characterised by the choice of material
• CPC Class Codes: B29C 65/4895 Solvent bonding, i.e. the surfaces of the parts to be joined being treated with solvents, swelling or softening agents, without adhesives
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2995/0026 Transparent
• CPC Class Codes: C08J 2367/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds; C08J2367/06 takes precedence
• CPC Class Codes: C08J 5/122 using low molecular chemically inert solvents, swelling or softening agents
• CPC Class Codes: C08J 5/18 Manufacture of films or sheets
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 156/1038 Hollow cylinder article
• CPC Class Codes: Y10T 428/1328 Shrinkable or shrunk [e.g., due to heat, solvent, volatile agent, restraint removal, etc.]

Abstract

A thermo-shrinkable polyester type film having the following shrinking properties:

a shrinking ratio in one axis is not less than 30% at 80° C. and not less than 50% at 100° C., and

a shrinking ratio in a perpendicular axis to the former axis shows the minimum value at a temperature range of 80°±25° C., and the process therefor.

This film shows an excellent shrinking properties for packaging.

Claims

1. A thermo-shrinkable polyester type film which is obtained from a material selected from the group consisting of a polyester having a glass transition temperature of no less than 35°

C., a polyester copolymer having a glass transition temperature of no less than 35°

C., and a mixture of both of said polyester and polyester copolymer with at least one other polymer, wherein said film has the following shrinking properties;

a shrinking ratio in the one axis is not less than 30% of 80°

C. and not less than 50% at 100°

C., and

a shrinking ratio in perpendicular axis to the former axis is not more than 15% in the range of 55°

-105°

C., and the minimum value of the shrinking ratio occurs at a temperature in the range of 55°

-105°

C.; and

having an orientation factor of not more than 100×

10^-3.

2. A thermo-shrinkable polyester type film according to claim 1, which is made of a polyester copolymer or the mixture thereof, wherein the polyester copolymer mainly contains an ester group of a dicarboxylic residue and a glycol residue, and contains one kind of an aromatic dicarboxylic residue in an amount of 30-90 mole % based on the total dicarboxylic residue.

3. A thermo-shrinkable polyester type film according to claim 1, which has the maximum thermo-shrink stress at 80°

C. of 0.95-5 kg/mm², and the maximum thermo-shrink stress at 100°

C. of 1.0-5 kg/mm².

4. A tube of a thermo-shrinkable polyester type film which has a jointed surface being jointed by at least one solvent or swelling agent having a solubility or swelling ability to a polyester and a solubility index of 8.0-13.8, and the following shrinking properties:

a peripheral shrinking ratio is not less than 30% at 80°

C. and not less than 50% at 100°

C., and

a longitudinal shrinking ratio is not more than 15% in the range of 55°

-105°

C., and the minimum value of the shrinking ratio occurs at a temperature in the range of 55°

to 105°

C.

5. A tube of a thermo-shrinkable polyester type film according to claim 4, which is obtained from a material selected from the group consisting of a polyester having a glass transition temperature of not less than 35°

C., a polyester copolymer having a glass transition temperature of not less than 35°

C., and the mixture of both of said polyester and polyester copolymer with at least one other polymer, and has an orientation factor of not more than 100×

10^-3.

6. A tube of thermo-shrinkable polyester type film according to claim 4, which is made of a polyester copolymer or the mixture thereof, wherein the polyester copolymer mainly contains an ester group composed of a dicarboxylic residue and a glycol reside, and contains one kind of an aromatic dicarboxylic residue in an amount of 30-90 mole % based on the total dicarboxylic residue, and

has an orientation factor of not more than 100×

10^-3.

7. A tube of thermo-shrinkable polyester type film according to claim 4, wherein the jointed surface is jointed by means of simply superposing one side of the film onto the another surface, applying a tape onto at least one surface of the film to joint the film, or butt-seam wherein resulting sealed portion is bent and adhered onto either surface of the tube.

8. A tube of thermo-shrinkable polyester type film according to claim 4, wherein the tube is jointed by at least one solvent or swelling agent having solubility Parameter of 8.0-13.8 selected from the group consisting of aromatic hydrocarbon, halogenated hydrocarbon, halogenated aromatic hydrocarbon, phenols, alcohols, nitrogen compound, ketones, ethers, esters, organic acids, inorganic acids, sulfur derivative and N'"'"',N'"'"'-dimethyl formamide.

9. A process for production of a tube from polyester type film which comprises:

disposing a polyester type film having shrinking properties wherein a shrinking ratio in one axis is not less than 30% at 80°

C. and not less than 50% at 100°

C., and a shrinking ratio in a perpendicular axis to the former axis is not more than 15% in the range of 55°

-105°

C., and the minimum value of the shrinking ratio in the perpendicular axis occurs at a temperature in the range of 55°

-105°

C.,

spreading at least one jointed surface of the film with a solvent or a swelling agent having a solubility or swelling ability to a polyester and a solubility parameter or 8.0-13.8, and

jointing the surfaces to be jointed to give a tubular film before the solvent or swelling agent is dried.

10. A process according to claim 9, wherein the polyester type film is obtained from a material selected from the group consisting of a polyester having a glass transition temperature of not less than 35°

C., a polyester copolymer having a glass transition temperature of not less than 35°

C., and the mixture of both of said polyester and polyester copolymer with at least one other polymer, and has an orientation factor of not more than 100×

10^-3.

11. A process according to claim 9, wherein the film is jointed by using a solvent or a swelling agent selected from the group consisting of halogenated hydrocarbon and ethers.

12. A process according to claim 9, wherein the film is jointed at a temperature of not higher than 70°

C.

13. A process for production of a tube from polyester type film which comprises:

disposing a polyester type film having shrinking properties wherein a shrinking ratio in one axis is not less than 30% at 80°

C. and not less than 50% at 100°

C., and a shrinking ratio in a perpendicular axis to the former axis is not more than 15% in the range of 55°

-105°

C., and the minimum value of the shrinking ratio in the perpendicular axis occurs at a temperature in the range of 55°

-105°

C.,

disposing an adhesive layer on entire or part of at least one surface to be jointed,

spreading at least one surface with a solvent or a swelling agent having a solubility or swelling ability to a polyester and a solubility parameter of 8.0-13.8, and

jointing the surfaces to be jointed to give a tubular film before the solvent or swelling agent is dried.

14. A process according to claim 13, wherein the polyester type film is obtained from a material selected from the group consisting of a polyester having a glass transition temperature of not less than 35°

C., a polyester copolymer having a glass transition temperature of not less than 35°

C., and the mixture of both of said polyester and polyester copolymer with at least one other polymer, and has an orientation factor coefficient of surface orientation of not more than 100×

10^-1.