Composite fiberboard and process of manufacture

• US 4,963,603 A
• Filed: 11/15/1989
• Issued: 10/16/1990
• Est. Priority Date: 05/24/1989
• Status: Expired due to Term

• Current Assignee: AWI Licensing Company
• Original Assignee: Armstrong World Industries Incorporated
• Inventors: Felegi, John Jr., Kehrer, Kenneth P.
• Primary Examiner(s): Nutter, Nathan M.
• Application Number:
  US07/434,041
• Time in Patent Office: 335 Days
• Field of Search: 524/13, 524/35, 524/443, 524/445, 524/494, 162/145, 162/146, 162/147, 162/152
• US Class Current: 524/13
• CPC Class Codes: C04B 26/04 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: D21H 13/40 vitreous, e.g. mineral wool, glass fibres
• CPC Class Codes: D21H 19/58 Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof
• CPC Class Codes: D21H 23/765 Addition of all compounds to the pulp

Abstract

A novel composite board of mineral wool, perlite, and cellulosic newsprint fibers for use primarily as a ceiling tile is disclosed. The board displays virtually no sag (less than 200 mils) when exposed to high temperature and high humidity while displaying quite acceptable strength. The board, or product without mineral wool or perlite, is manufactured by selective deposition of a latex composition on the cellulosic newsprint fibers.

Claims

1. A composite board which comprises up to 87% by weight mineral wool, 5-65% by weight perlite, up to 25% by weight clay, 4-35% by weight cellulosic newsprint composed primarily of cellulosic fibers, and 2-15% by weight of a thermoplastic polymeric binder having a glass transition temperature of from 80°

C. to 115°

C., the ratio of said binder to said cellulosic newsprint being no greater than about 1.25 when said cellulosic newsprint content is less than 6% by weight and said ratio being no greater than 0.7 when said cellulosic newsprint content is at Ieast 6% by weight, wherein the cellulose fibers in said board are substantially completely coated with said thermoplastic binder, said board displaying a sag of less than 200 mils when a 0.6 inch thick sample, 9 inches wide and 24 inches long is supported at both ends and exposed to a temperature of 85°

F. and a relative humidity of 95% for 24 hours.

2. A composite board which comprises up to 75% by weight mineral wool, 5-65% by weight perlite, up to 25% by weight clay, 4-35% by weight cellulosic newsprint composed primarily of cellulosic fibers, and 4-15% by weight of a thermoplastic polymeric binder having a glass transition temperature of from 80°

C. to 115°

C., the ratio of said binder to said cellulosic newsprint being no greater than about 1 when said cellulosic newsprint content is less than 6% by weight and said ratio being no greater than 0.4 when said cellulosic newsprint content is at least 6% by weight, wherein the cellulose fibers in said board are substantially completely coated with said thermoplastic binder, said board displaying a sag of less than 200 mils when a 0.6 inch thick sample, 9 inches wide and 24 inches long is supported at both ends and exposed to a temperature of 85°

F. and a relative humidity of 95% for 24 hours.

3. A composite board which comprises about 20-50% by weight mineral wool, about 20-50% by weight perlite, up to 25% by weight clay, 10-30% by weight cellulosic newsprint composed primarily of cellulosic fibers, and 4-15% by weight of a thermoplastic polymeric binder having a glass transition temperature of from 80°

C. to 115°

C., the ratio of said binder to said cellulosic newsprint being no greater than about 0.7, wherein the cellulosic fibers in said board are substantially completely coated with said thermoplastic binder, said board displaying a sag of less than 200 mils when a 0.6 inch thick sample, 9 inches wide and 24 inches long is supported at both ends and exposed to a temperature of 85°

F. and a relative humidity of 95% for 24 hours.

4. A composite board which comprises about 20-50% by weight mineral wool, about 20-50% by weight perlite, up to 25% by weight clay. 10-30% by weight cellulosic newsprint composed primarily of cellulosic fibers, and 4-15% by weight of a thermoplastic polymeric binder having a glass transition temperature of from 80°

C. to 115°

C., the ratio of said binder to said cellulosic newsprint being no greater than about 0.7, wherein the cellulosic fibers in said board are substantially completely coated with said thermoplastic binder, said board displaying a sag of less than 200 mils when a 0.6 inch thick sample, 9 inches wide and 24 inches long is supported at both ends and exposed to a temperature of 85°

F. and a relative humidity of 95% for 24 hours, and a modulus of rupture, as measured by the procedure in ASTM D-1087, of greater than 150 psi.

5. A composite board as in claim 4 comprising 20-40% mineral wool, 20-35% perlite, 10-30% cellulosic newsprint and 6-10% latex having a glass transition temperature of from 80°

C. to 115°

C.

6. A composite board as in claim 4 comprising 20-40% mineral wool, 20-35% perlite, 10-30% cellulosic newsprint and 6-10% latex having a glass transition temperature of from 100°

C. to 115°

C.

7. A composite board as in claim 4 comprising about 20-50% mineral wool, about 20.50% perlite, about 13-23% cellulosic newsprint, and about 4-0.6% latex having a glass transition temperature of from 100°

C. to 115°

C.

8. A composite board as in claim 4 comprising about 35% mineral wool, about 30% perlite, about 25% cellulosic newsprint, about 8.5-10% latex having a glass transition temperature of 100°

C. and where the ratio of said latex to said cellulosic newsprint is no greater than 0.4.

9. In the process for making a product containing at least the components of 4-35% by weight cellulosic newsprint composed primarily of cellulose fibers, and 2-15% by weight of a thermoplastic polymeric binder wherein the components are mixed with water to form an aqueous slurry, and said slurry is flocculated While being fed to a mold and shaped, the shaped material drained of liquid and pressed into the shape and thickness of said product and then heated to solidify said product, the improvement wherein said polymeric binder is coated on the cellulose fibers of the newsprint substantially completely before the slurry is fed to the mold and the ratio of binder-to-cellulosic newsprint used is no greater than about 1.25.

10. In the process for making a composite board containing at least the components of mineral wool perlite. 10-30% by weight cellulosic newsprint composed primarily of cellulose fibers, and 4-15% by weight of a thermoplastic polymeric binder wherein the components are mixed with water to form an aqueous slurry, and said slurry is flocculated while being fed to a mold and shaped, the shaped material drained of liquid and pressed into the shape and thickness of said board and then heated to solidify said board, the improvement wherein said polymeric binder is coated on the cellulose fibers of the newsprint substantially completely before the slurry is fed to the mold and the ratio of binder-to-cellulosic newsprint used is no greater than 0.7.

11. A process as in claim 10 wherein said thermoplastic binder is an anionic latex dispersion in which the latex particle diameter is no greater than 0.12 micron.

12. A process as in claim 10 wherein said thermoplastic binder is an anionic latex dispersion and a coagulant is added to the mixture of components before said slurry is flocculated.

13. A process as in claim 12 wherein said mixture is formed in two steps, the first step in which only water, newsprint composed primarily of cellulose fibers, coagulant and a portion of the anionic latex dispersion are used to form the mixture and the second step in which the remaining components and the remainder of said latex dispersion and, optionally, additional coagulant are added to form the mixture.

14. In the process for making a product containing at least the components of 4-35% by weight cellulosic newsprint composed primarily of cellulose fibers, and 2-15% by weight of a thermoplastic polymeric binder wherein the components are mixed with water to form an aqueous slurry, and said slurry is flocculated while being fed to a mold and shaped, the shaped material drained of liquid and pressed into the shape and thickness of said product and then heated to solidify said product, the improvement wherein said polymeric binder is coated on the cellulose fibers of the newsprint substantially completely before the slurry is fed to the mold.