Multifunctional molybdenum and sulfur containing lube additives

• US 4,966,719 A
• Filed: 03/12/1990
• Issued: 10/30/1990
• Est. Priority Date: 03/12/1990
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Greaney, Mark A., Stiefel, Edward I., Coyle, Catherine L., Beltzer, Morton
• Primary Examiner(s): Chaudhuri, Olik
• Assistant Examiner(s): McAvoy, Ellen
• Application Number:
  US07/493,042
• Time in Patent Office: 232 Days
• Field of Search: 252/42.7, 252/400.54
• US Class Current: 508/445
• CPC Class Codes: C10M 135/14 having a carbon-to-sulfur double bond
• CPC Class Codes: C10M 2203/10 Petroleum or coal fractions, e.g. tars, solvents, bitumen
• CPC Class Codes: C10M 2219/062 having carbon-to-sulfur double bonds
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2070/02 Concentrating of additives

Abstract

In accordance with this invention, there is provided a lubricating composition comprising a major amount of an oil of lubricating viscosity and a minor amount of an additive having the formula MoL₄ wherein L is a ligand selected from thioxanthates and mixtures thereof and, in particular, thioxanthates having a sufficient number of carbon atoms to render the additive soluble in the oil. In general, the thioxanthate ligand, L, will have from about 2 to about 30 carbon atoms.

Claims

1. A lubricating composition comprising:

a major amount of an oil of lubricating viscosity; and

, a minor amount of an additive having the formula MoL₄ wherein L is a ligand selected from thioxanthates and mixtures thereof.

2. The composition of claim 1 wherein the ligand, L, has organo groups having a sufficient number of carbon atoms to render the additive soluble in the oil.

3. The composition of claim 2 wherein the amount of the additive is in the range of from about 0.01 to about 10 weight percent based on the weight of oil.

4. The composition of claim 3 wherein the organo groups are selected from alkyl, aryl, aralkyl and alkoxylalkyl groups.

5. The composition of claim 4 wherein the organo groups are alkyl groups and the number of carbon atoms in the alkyl groups of the ligand, L, are in the range of from about 1 to about 30.

6. A lubricating composition comprising:

a major amount of an oil selected from natural and synthetic oils having viscosities in the range of from about 5 to about 26 centistokes at 100°

C., and from about 0.01 to about 10 weight percent of an additive having the formula MoL₄, wherein L is a thioxanthate and mixtures thereof and wherein the ligand, L, has organo groups having from about 2 to about 30 carbon atoms.

7. The composition of claim 6 wherein the additive is present in an amount ranging from about 0.1 to about 1.0 weight percent.

8. The composition of claim 7 wherein the organo group is an alkyl group having from about 8 to about 20 carbon atoms.

9. The composition of claim 8 wherein the alkyl group has 12 carbon atoms.

10. An additive concentrate for blending with lubricating oils to provide a lubricating composition having improved properties comprising:

a hydrocarbon diluent and from about 1 to about 90 weight percent of an additive, based on the weight of diluent, the additive having the formula MoL₄ wherein L is a ligand selected from thioxanthate and mixtures thereof and wherein the ligand, L, has organo groups having from about 2 to about 30 carbon atoms.

11. The concentrate of claim 10 wherein the diluent is an aromatic hydrocarbon and the additive ranges between about 20 to about 70 weight percent, based on the weight of diluent.