Process for electroplating stainless steel strips with zinc or zinc-nickel alloy

• US 4,969,980 A
• Filed: 05/03/1988
• Issued: 11/13/1990
• Est. Priority Date: 10/01/1986
• Status: Expired due to Fees

• Current Assignee: Kawasaki Steel Corporation (JFE Holdings Incorporated)
• Original Assignee: Kawasaki Steel Corporation (JFE Holdings Incorporated)
• Inventors: Kato, Yasushi, Watanabe, Kenji, Yoshioka, Keiichi
• Primary Examiner(s): Niebling, John F.
• Assistant Examiner(s): Leader, William T.
• Application Number:
  US07/189,641
• Time in Patent Office: 924 Days
• Field of Search: 204/27, 204/28, 204/34
• US Class Current: 205/130
• CPC Class Codes: C25D 5/028 one side electroplating, e.g. substrate conveyed in a bath with inhibited background plating
• CPC Class Codes: C25D 5/36 of iron or steel
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12799 Next to Fe-base component [e.g., galvanized]

Abstract

An exterior stainless steel sheet is provided comprising a stainless steel substrate and a coating layer formed on one surface of the steel substrate from Al, Al alloy, Zn or Zn alloy to a thickness of 0.1 to 70 μm, preferably 1 to 70 μm. A Zn or Zn-Ni alloy plated stainless steel strip is prepared by degreasing a stainless steel strip, substantially activating the surface of the strip, and electroplating the strip by immersing the strip in a hydrochloric acid solution having a concentration of 0.5 to 40 wt % in a zinc or zinc-nickel alloy plating bath at pH 3.5 or lower. Alternatively, activation may be carried out by cathodic electrolytic treatment in a hydrochloric acid solution having a concentration of 0.5 to 40 wt % at a current density of 0.1 to 100 A/dm. During electroplating of one side, the other side of the strip not to be plated is covered with a protective film. A stainless steel sheet comprising a stainless steel substrate and a coating layer formed on one surface of the steel substrate from Zn or Zn alloy to a thickness of 0.1 to 50 μm, preferably 1 to 50 μm is useful in preparing welded pipes.

Claims

1. A process for preparing a zinc or zinc-nickel alloy plated stainless steel strip, comprising the steps of:

degreasing a stainless steel strip,

subjecting the surface of the strip to activation carried out by immersing the strip in an aqueous solution consisting essentially of water and hydrochloric acid at a concentration of 0.5 to 40 wt % at a temperature of 25°

to 90°

C. to improve the adherence of the zinc or zinc-nickel alloy and

electroplating the strip in a zinc or zinc-nickel alloy plating bath at pH 3.5 or lower.

2. A process according to claim 1 wherien the stainless steel strip is electroplated on one side while another side of the strip not to be plated is covered with a protective film to provide a one-side electroplated stainless steel strip.

3. A process for preparing a zinc or zinc-nickel alloy plated stainless steel strip, comprising the steps of:

degreasing a stainless steel strip,

subjecting the surface of the strip to activation, said activation being cathodic electrolysis treatment conducted on the strip surface in an aqueous solution consisting essentially of water and hydrochloric acid at a concentration of 0.5 to 40 wt % at a temperature of up to 90°

C. and a current density of 0.1 to 100 A/dm² to improve the adherence of the zinc or zinc-nickel alloy, and

electroplating the strip in a zinc or zinc-nickel alloy plating bath at pH 3.5 or lower.

4. A process according to claim 3 wherein the stainless steel strip is electroplated on one side while another side of the strip not to be plated is covered with a protective film to provide a one-side electroplated stainless steel strip.