Apparatus for the production of heavier hydrocarbons from gaseous light hydrocarbons

• US 4,973,453 A
• Filed: 02/27/1989
• Issued: 11/27/1990
• Est. Priority Date: 02/05/1988
• Status: Expired due to Term

• Current Assignee: REG Synthetic Fuels, LLC (Chevron Corp.)
• Original Assignee: G.T.G., Inc.
• Inventors: Agee, Kenneth L.
• Primary Examiner(s): Warden, Robert J.
• Assistant Examiner(s): Johnston, Jill
• Application Number:
  US07/316,015
• Time in Patent Office: 638 Days
• Field of Search: 48/127.9, 48/198.7, 422/189, 422/198, 422/190, 422/187, 518/703, 518/704, 252/373, 252/374
• US Class Current: 422/614
• CPC Class Codes: C07C 1/0485 Set-up of reactors or accessories; Multi-step processes
• CPC Class Codes: C07C 2521/04 Alumina
• CPC Class Codes: C07C 2521/08 Silica
• CPC Class Codes: C07C 2521/12 Silica and alumina
• CPC Class Codes: C07C 2523/75 Cobalt

Abstract

An apparatus for the production of heavier hydrocarbons from one or more gaseous light hydrocarbons is provided. The process of using the apparatus comprises reacting the gaseous light hydrocarbons by autothermal reforming with air in the presence of recycled carbon dioxide and steam to produce a synthesis gas stream containing hydrogen and carbon monoxide. The synthesis gas stream is reacted in the presence of a hydrocarbon synthesis catalyst containing cobalt to form heavier hydrocarbons and water from the hydrogen and carbon monoxide. The heavier hydrocarbons and water are separated, and the resulting residue gas stream is subjected to catalytic combustion with additional air to form a product stream comprising carbon dioxide and nitrogen. The carbon dioxide is separated from the nitrogen to produce a nitrogen product stream, and at least a portion of the separated carbon dioxide is recycled to the autothermal reforming step.

Claims

1. Apparatus for producing heavier hydrocarbons from one or more gaseous light hydrocarbons comprising:

(a) a partial oxidation burner means having a gaseous light hydrocarbon inlet, an air inlet and a combusting hydrocarbon gas-air mixture outlet;

(b) a synthesis gas generation vessel containing a steam reforming catalyst bed having a combusting hydrocarbon gas-air mixture inlet attached to the outlet of said burner means, a carbon dioxide inlet, a water inlet and a synthesis gas stream outlet;

(c) a hydrocarbon synthesis reactor containing a bed of hydrocarbon synthesis catalyst having a synthesis gas stream inlet and a heavier hydrocarbon product gas stream outlet;

(d) first conduit means connected between the synthesis gas stream outlet of said synthesis gas generation vessel and the synthesis gas stream inlet of said hydrocarbon synthesis reactor;

(e) separating means for separating heavier hydrocarbons from a hydrocarbon synthesis product gas stream having a hydrocarbon synthesis product gas stream inlet, a residue gas stream outlet and a separated heavier hydrocarbons outlet;

(f) second conduit means connected between the heavier hydrocarbon synthesis product gas stream outlet of said hydrocarbon synthesis reactor and the synthesis product gas stream inlet of said separating means;

(g) catalytic combustion means for catalytically combusting the residue gas stream produced when heavier hydrocarbons are separated from a heavier hydrocarbon synthesis product gas stream to form a stream containing carbon dioxide therefrom having a residue gas stream inlet and a product gas stream outlet;

(h) third conduit means connected between the residue gas stream outlet of said separating means and the residue gas stream inlet of said catalytic combustion means;

(i) carbon dioxide separating means for separating carbon dioxide from the product gas stream having a product gas stream inlet and a carbon dioxide outlet;

(j) fourth conduit means connected between the product gas stream outlet of said catalytic combustion means and the product gas stream inlet of said carbon dioxide separating means; and

(k) fifth conduit means connected between the carbon dioxide outlet of said carbon dioxide separating means and the carbon dioxide inlet of said synthesis gas generation vessel.

2. The apparatus of claim 1 wherein said separating means for separating heavier hydrocarbons from a heavier hydrocarbon synthesis product gas stream comprises:

cooling means for cooling said heavier hydrocarbon synthesis product gas stream and condensing heavier hydrocarbons and water contained therein; and

means for accumulating and withdrawing condensed heavier hydrocarbons and water from the resulting residue gas stream connected to said cooling means.

3. The apparatus of claim 1 which is further characterized to include:

fractionator means for subjecting separated heavier hydrocarbons to fractionation whereby a product stream containing selected hydrocarbon components and a residue hydrocarbon stream is produced, said fractionator means including a heavier hydrocarbons inlet, a product stream outlet and a residue hydrocarbons stream outlet;

sixth conduit means connected between the separated heavier hydrocarbons outlet of said separating means and the heavier hydrocarbons inlet of said fractionator means; and

seventh conduit means connected between said residue hydrocarbons stream outlet of said fractionator means and said gaseous light hydrocarbon inlet of said partial oxidation burner means.

4. The apparatus of claim 1 which is further characterized to include:

heat exchanger means disposed and connected in and to said first conduit means having a gaseous light hydrocarbon inlet and a gaseous light hydrocarbon outlet; and

eighth conduit means connected between said gaseous light hydrocarbon outlet of said heat exchanger means and the gaseous light hydrocarbon inlet of said partial oxidation burner means.

5. The apparatus of claim 1 which is further characterized to include:

a second heavier hydrocarbon synthesis reactor containing a bed of hydrocarbon synthesis catalyst disposed and connected in and to said third conduit means; and

downstream of said second heavier hydrocarbon synthesis reactor, a second separating means for separating heavier hydrocarbons from a heavier hydrocarbon synthesis product gas stream disposed and connected in and to said third conduit means.