Use of salt hydrates as reversible absorbents of acid gases

• US 4,973,456 A
• Filed: 10/24/1988
• Issued: 11/27/1990
• Est. Priority Date: 10/24/1988
• Status: Expired due to Term

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Quinn, Robert, Pez, Guido P.
• Primary Examiner(s): Heller, Gregory A.
• Application Number:
  US07/261,653
• Time in Patent Office: 764 Days
• Field of Search: 423/244 A, 423/244 R, 423/210.5, 423/245.1, 423/245.2, 423/224, 423/225, 423/230, 423/576.8, 423/236, 423/226, 423/243
• US Class Current: 423/210.5
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: C10K 1/10 with aqueous liquids alkaline reacting aqueous liquids C10K1/12
• CPC Class Codes: C10K 1/12 alkaline-reacting including the revival of the used wash liquors
• CPC Class Codes: C10K 1/14 organic

Abstract

The present invention is a process for reversibly absorbing acid gases, such as CO₂, H₂ S, SO₂, HCN and the like from gas mixtures. The gas mixture containing one or more of these acid gases is contacted with a hydrated salt of the composition

A.sub.x.sup.m+ B.sub.y.sup.n-.rH.sub.2 O

wherein A^m+ is a cation, B^n- is the conjugate base of a weak acid having a pKa corresponding to an ionization constant of the acid greater than 3 as measured in dilute aqueous solution, m and n are independently integers from 1-4, x and y are integers such that the ratio of x to y provides a neutral salt and r is any number greater than zero up to the maximum number of moles of water which can be bound to the salt. The salt hydrate reversibly absorbs the acid gas from the gas mixture.

Claims

1. A process for removing acid gases selected from the group consisting of CO₂, H₂ S, SO₂, HCN, and COS from a gas mixture containing one or more of said acid gases and at least one other component, said process comprising:

bringing said gas mixture into contact with a hydrated salt of the composition

space="preserve" listing-type="equation">A.sub.x.sup.m+ B.sub.y.sup.n- •

rH.sub.2 O

wherein A^m+ is a cation, B^n- is the conjugate base of a weak acid having a pKa corresponding to an ionization constant of the acid greater than 3 as measured in dilute aqueous solution, m and n are independently integers from 1-4, x and y are integers such that the ratio of x to y provides a neutral salt and r is any number greater than zero up to the maximum number of moles of water which can be bound to the salt; and

carrying out said process at a temperature from 0°

to 200°

C. whereby said salt hydrate reversibly absorbs said acid gases thereby removing them from the gas mixture.

2. A process in accordance with claim 1 wherein m=1.

3. A process in accordance with claim 2 wherein A^m+ is an alkali metal cation.

4. A process in accordance with claim 2 wherein A^m+ is a quaternary ammonium ion of the formula R₄ N⁺, wherein R is a substituted or unsubstituted alkyl or aromatic group.

5. A process in accordance with claim 1 wherein B^n- is a fluoride ion.

6. A process in accordance with claim 1 wherein B^n- is an anion of a carboxylic acid.

7. A process in accordance with claim 5 wherein B^n- is an anion of a carboxylic acid selected from the group consisting of acetate, malonate, citrate, ethylenediaminetetraacetate and nitrilotriacetate.

8. A process in accordance with claim 7 wherein said process is carried out at a temperature from 20°

to 80°

C.

9. A process in accordance with claim 1 wherein said salt hydrate is a molten salt hydrate.

10. A process in accordance with claim 2 wherein r is from 0.5 to 24.

11. A process in accordance with claim 10 wherein r is from 0.5 to 12.

12. A process in accordance with claim 10 wherein said salt hydrate is tetraethylammonium acetate tetrahydrate.

13. A process in accordance with claim 10 wherein said salt hydrate is tetramethylammonium malonate monohydrate.

14. A process in accordance with claim 10 wherein said salt hydrate is tetramethylammonium fluoride tetrahydrate.

15. A process in accordance with claim 1 wherein said salt hydrate is in the presence of up to 6 moles of water per mole of cation, and independently up to 6 moles of water per mole of anion present in the salt.

16. A process in accordance with claim 1 wherein said acid gas reversibly absorbed by said salt hydrate is CO₂.