Composite solar/safety film and laminated window assembly made therefrom

• US 4,973,511 A
• Filed: 12/01/1988
• Issued: 11/27/1990
• Est. Priority Date: 12/01/1988
• Status: Expired due to Term

• Current Assignee: Solutia Incorporated (Eastman Chemical Company)
• Original Assignee: Monsanto Company (Bayer AG)
• Inventors: Riek, Raymond F., Ho, Stanley S., Farmer, Peter H., Woodard, Floyd E.
• Primary Examiner(s): Herbert, Thomas J.
• Application Number:
  US07/278,576
• Time in Patent Office: 726 Days
• Field of Search: 428/457, 428/412, 428/423.1, 428/426, 428/216, 428/332, 428/337, 428/522, 428/523, 428/500, 428/343, 428/334
• US Class Current: 428/216
• CPC Class Codes: B32B 17/10005 laminated safety glass or glazing
• CPC Class Codes: B32B 17/10018 comprising only one glass sheet
• CPC Class Codes: B32B 17/10036 comprising two outer glass sheets
• CPC Class Codes: B32B 17/10174 Coatings of a metallic or dielectric material on a constituent layer of glass or polymer
• CPC Class Codes: B32B 17/10339 Specific parts of the laminated safety glass or glazing being colored or tinted tinted glass sheet B32B17/1011; tinted interlayer B32B17/10651
• CPC Class Codes: B32B 17/10651 comprising colorants, e.g. dyes or pigments
• CPC Class Codes: B32B 17/10761 containing vinyl acetal
• CPC Class Codes: B32B 17/10981 Pre-treatment of the layers
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 2310/0445 using gas or flames B32B2310/0427 takes precedence
• CPC Class Codes: B32B 2310/0887 using electron radiation, e.g. beta-rays
• CPC Class Codes: B32B 2310/14 Corona, ionisation, electrical discharge, plasma treatment
• CPC Class Codes: B32B 2311/08 Silver
• CPC Class Codes: B32B 2329/00 Polyvinylalcohols, polyvinylethers, polyvinylaldehydes, polyvinylketones or polyvinylketals
• CPC Class Codes: B32B 2329/06 PVB, i.e. polyinylbutyral
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2605/006 Transparent parts other than made from inorganic glass, e.g. polycarbonate glazings
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: B32B 37/04 characterised by the partial melting of at least one layer
• CPC Class Codes: F24S 50/80 : for controlling collection or absorption of solar radiation
• CPC Class Codes: Y02B 10/20 : Solar thermal
• CPC Class Codes: Y02E 10/40 : Solar thermal energy, e.g. solar towers
• CPC Class Codes: Y10T 428/24975 : No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/26 : Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/263 : Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/266 : of base or substrate
• CPC Class Codes: Y10T 428/28 : Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/31507 : Of polycarbonate
• CPC Class Codes: Y10T 428/31551 : Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31678 : Of metal
• CPC Class Codes: Y10T 428/31855 : Of addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31935 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31938 : Polymer of monoethylenically unsaturated hydrocarbon

Abstract

A laminated window construction includes a solar control film formed by a flexible plastic substrate such as a PET sheet having on one surface a multilayer solar coating. This multilayer solor coating includes at least one thin layer of metal and at least one adjacent adherent layer of a dielectric material. An energy absorbing safety film of the type normally used in shatterproof glass laminates (e.g., plasticized PVB) is bonded to at least one side, and preferably both sides, of the solar control film to form a composite solar/safety film. This composite solar/safety film is specially designed to contribute, after incorporation into a glass laminate, no more than about two percent of visible reflection (based on total incident visible radiation) which has the effect of substantially masking the visible effects of wrinkles in the solar control film substrate (i.e., the wrinkles are made less visible). This low level of visible reflection contribution is achieved by careful control of the optical properties of the solar control film, the safety film or both. Outer layer transparent glass panes are laminated to one or both sides of the composite solar/safety film to provide a safety window which in one preferred embodiment is a windshield having at least seventy percent normal visible light transmissibility, and a total reflection of visible light of generally less than ten percent.

Claims

1. A composite solar/safety film for use in a laminated window assembly comprising:

a flexible, transparent plastic substrate layer having a carrier surface and an opposing back surface;

a multilayer solar control coating on said carrier surface, said coated substrate defining a solar control film; and

at least one flexible, transparent, energy absorbing plastic safety layer bonded to a surface of said solar control film;

wherein said solar control film contributes no more than about 2% visible reflectance, based on total visible incident radiation, in a laminated window assembly containing said composite solar/safety film laminated to at least one rigid transparent member.

2. The composite solar/safety film of claim 1 wherein said solar control film contribution to visible reflection is no more than about 1%.

3. The composite solar/safety film of claim 1 wherein said solar control film contribution to visible reflection is no more than about 0.7%.

4. The composite solar/safety film of claim 1 wherein said substrate layer has a thickness of from about 10 to about 200 microns.

5. The composite solar/safety film of claim 1 wherein said substrate layer has a visible light absorbing coating.

6. The composite solar/safety film of claim 1 wherein said solar control coating has a visible light absorbing coating.

7. The composite solar/safety film of claim 1 wherein said multilayer solar control coating comprises at least one electrically conductive, near infrared reflecting metal layer and at least one adjacent adherent layer of a dielectric material.

8. The composite solar/safety film of claim 7 wherein said layer of dielectric material has a thickness of from about 200 to about 600 angstroms.

9. The composite solar/system film of claim 7 wherein said dielectric material has a refractive index of at least about 1.8.

10. The composite solar/safety film of claim 7 wherein said multilayer solar control coating comprises, in order outward from said carrier surface, a first layer of dielectric material, a layer of metal, and a second layer of dielectric material.

11. The composite solar/safety film of claim 10 wherein said first and second layers of dielectric material each have a thickness of from about 200 to about 600 angstroms, said dielectric materials has a refractive index of at least about 1.8, said layer of metal has a thickness of from about 60 to about 120 angstroms, and said metal is silver.

12. The composite solar/safety film of claim 10 wherein said first layer of dielectric material is about 400 angstrom thick and comprises WO₃, said metal layer is about 90 angstroms thick and comprises silver, and said second layer of dielectric material is about 400 angstroms thick and comprises WO₃.

13. The composite solar/safety film of claim 7 wherein said metal is selected from the group consisting of silver, palladium, aluminum, chromium, nickel, copper, gold, brass, stainless steel and alloys thereof.

14. The composite solar/safety film of claim 13 wherein said metal is silver.

15. The composite solar/safety film of claim 13 wherein said metal layer has a thickness of from about 60 to about 120 angstroms.

16. The composite solar/safety film of claim 7 wherein said dielectric material is selected from the group consisting of ZrO₂, Ta₂ O₅, WO₃, In₂ O₃, SnO₂, In/SnOx, Al₂ O₃, ZnS, ZnO and TiO₂.

17. The composite solar/safety film of claim 16 wherein said dielectric material is WO₃, In₂ O₃ or SnO₂.

18. The composite solar/safety film of claim 7 wherein said multilayer solar coating comprises, in order outward from said carrier surface, a first layer of dielectric material and a series of at least two alternating metal layer/dielectric layer sets.

19. The composite solar/safety film of claim 18 wherein said first layer of dielectric material is 400 angstroms thick and comprises WO₃, said first metal layer is 90 angstroms thick and comprises silver, said second layer of dielectric material is 800 angstroms thick and comprises WO₃, said second metal layer is 90 angstroms thick and comprises silver, and said third layer of dielectric material is 400 angstroms thick and comprises WO₃.

20. The composite solar/safety film of claim 18 wherein said multilayer solar coating is a five-layer coating comprising, in order outward from said carrier surface, a first layer of dielectric material, a first layer of metal, a second layer of dielectric material, a second layer of metal and a third layer of dielectric material.

21. The composite solar/safety film of claim 20 wherein said dielectric material of said first layer of dielectric material has a refractive index greater than 1.8, said first layer of dielectric material has a thickness of from about 200 to about 600 angstroms, said first layer of metal has a thickness of from about 80 to about 120 angstroms, said dielectric material of said second layer of dielectric material has a refractive index greater than 1.5, said second layer of dielectric material has a thickness of from about 400 to about 1200 angstroms, said second layer of metal has a thickness of from about 80 to about 120 angstroms, said dielectric material of said third layer of dielectric material has a refractive index greater than 1.8, and said third layer of dielectric material has a thickness of from about 200 to about 600 angstroms.

22. The composite solar/safety film of claim 1 wherein said substrate layer is selected from the group consisting of biaxially oriented polyesters, nylons, polyurethanes, acrylics, polycarbonates, polyolefins, cellulose acetates and triacetates, and vinyl chloride polymers and copolymers.

23. The composite solar/safety film of claim 22 wherein said substrate layer is biaxially oriented polyethylene terephthalate.

24. The composite solar/safety film of claim 1 wherein said substrate layer back surface has an adhesion promoting configuration.

25. The composite solar/safety film of claim 24 wherein said adhesion promoting configuration comprises said substrate layer back surface having been subjected to a prior treatment selected from the group consisting of flame treatment, plasma energy treatment in a reactive atmosphere, and electron beam energy treatment in a reactive atmosphere.

26. The composite solar/safety film of claim 24 wherein said adhesion promoting configuration comprises a further coating layer of a material selected from the group consisting of dielectrics, adhesives and chemical primers.

27. The composite solar/safety film of claim 26 wherein said further coating layer is optically functional as an antireflecting layer.

28. The composite solar/safety film of claim 1 wherein said safety layer is selected from the group consisting of plasticized polyvinyl butyral, polyurethanes, polyvinyl chloride, polyvinyl acetal, polyethylene, and ethylene vinyl acetates.

29. The composite solar/safety film of claim 28 wherein said safety layer is plasticized polyvinyl butyral.

30. The composite solar/safety film of claim 28 wherein said safety layer has a thickness of from about 0.005" to 0.060".

31. The composite solar/safety film of claim 28 wherein said solar control film is encapsulated between and bonded in face-to-face relationship with two safety layers.

32. The composite solar/safety film of claim 28 wherein said solar control film has bonded to the surface containing said solar control coatings, one safety layer.

33. The composite solar/safety film of claim 32 wherein said substrate layer back surface has bonded thereto an adhesion promoting layer.

34. The composite solar/safety film of claim 1 wherein said safety layer has enhanced visible light absorption characteristics.

35. The composite solar/system film of claim 34 wherein said safety layer is tinted or pigmented.

36. The composite solar/safety film of claim 34 wherein said safety layer additionally contains a visible light absorbing coating.

37. The composite solar/safety film of claim 1 wherein said rigid transparent member is selected from the group consisting of glass, polycarbonates and acrylics.

38. The composite solar/safety film of claim 37 wherein said rigid transparent member is glass.