Method of making an open pore structure

• US 4,975,230 A
• Filed: 06/17/1988
• Issued: 12/04/1990
• Est. Priority Date: 06/17/1988
• Status: Expired due to Fees

• Current Assignee: Masco VT Incorporated (Masco Corporation)
• Original Assignee: Vapor Technologies, Inc. (Masco Corporation)
• Inventors: Pinkhasov, Eduard
• Primary Examiner(s): Lowe, James
• Assistant Examiner(s): Fiorilla, Christopher A.
• Application Number:
  US07/208,886
• Time in Patent Office: 900 Days
• Field of Search: 264/59, 264/81, 427/37, 427/227, 164/46, 428/613, 204/192.38, 429/94
• US Class Current: 264/414
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/1121 by using decomposable, meltable or sublimatable fillers
• CPC Class Codes: C23C 14/0005 Separation of the coating from the substrate
• CPC Class Codes: C23C 14/32 by explosion; by evaporation and subsequent ionisation of the vapours , e.g. ion-platingC23C14/34 - C23C14/48 take precedence
• CPC Class Codes: C25B 11/031 Porous electrodes
• CPC Class Codes: H01M 4/80 Porous plates, e.g. sintered carriers
• CPC Class Codes: H01M 4/808 Foamed, spongy materials
• CPC Class Codes: H01M 4/8621 containing only metallic or ceramic material, e.g. made by sintering or sputtering
• CPC Class Codes: H01M 4/8885 Sintering or firing
• CPC Class Codes: H01M 4/9016 Oxides, hydroxides or oxygenated metallic salts
• CPC Class Codes: H01M 4/9041 Metals or alloys H01M4/92 takes precedence
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

An openwork nickel structure having a high surface area to volume ratio and a porosity which is largely independent of the degree to which the metal structure may be compressed, is formed by depositing on a pyrolyzable support, preferably a reticulated open-pore polyurethane support, a coating of metal by arc-striking utilizing at least one electrode of that metal and by bringing the electrodes out of contact with one another. The metal-covered support is then subjected to pyrolysis to form the metal skeleton which is then sintered. The resulting metal structure has been found to be suitable for use as an electrode in a Ni-Cd cell.

Claims

1. A method of fabricating an open-pore structure, comprising:

(a) depositing on and in an openwork synthetic-resin pyrolyzable support a coating of at least one material selected from the group which consists of metals, semiconductors and ceramics by juxtaposing said support with a pair of electrodes at least one of which is composed of at least one element of said material, advancing said electrodes into contact to strike an electric arc between said electrodes and evaporate said element from said one of said electrodes and effect deposition of said material on said support, and evacuating a space in which said support is juxtaposed with such electrodes prior to depositing said material on said support; and

(b) sintering the deposited material into a coherent body constituting said open-pore structure.

2. A method of fabricating an open-pore structure, comprising:

(a) depositing on and in an openwork reticulated polyurethane foam pyrolyzable support a coating of at least one material selected from the group which consists of metals, semiconductors and ceramics by juxtaposing said support with a pair of electrodes at least one of which is composed of at least one element of said material, advancing said electrodes into contact to strike an electric arc between said electrodes and evaporate said element from said one of said electrodes and effect deposition of said material on said support, and evacuating a space in which said support is juxtaposed with such electrodes prior to depositing said material on said support;

(b) thereafter pyrolyzing said support to form an openwork skeleton consisting essentially of said material deposited on said support in step (a); and

(c) sintering said skeleton into a coherent body constituting said open-pore structure.

3. The method defined in claim 2, further comprising the step of compressing said open-pore structure to a reduced thickness while retaining porosity thereof.

4. The method defined in claim 2 wherein step (a) is carried out by applying a vacuum at a pressure no greater than 10^-3 torr to said steps, applying a voltage of 20 to 150 volts across said electrodes and supplying an arc current of 40 to 150 amperes.

5. The method defined in claim 2 wherein said element is a metal capable of forming an electrode for an electrochemical cell.

6. The method defined in claim 5 wherein said metal is nickel.

7. The method defined in claim 2 wherein said pyrolysis is carried out in the presence of air at a temperature of about 350°

C. for a period sufficient to substantially completely eliminate said support.

8. The method defined in claim 7 wherein said sintering is carried out in a vacuum oven in the absence of air or in an inert gas or reducing atmosphere at a temperature between substantially 950°

C. to 1250°

C. for a period sufficient to sinter said body into a structurally self-supporting state.

9. The method defined in claim 2 wherein 20 to 70 grams per square foot of metal is deposited on said support in step (a).

10. The method defined in claim 2 wherein the vacuum deposition, pyrolysis and sintering are carried out continuously on a continuously advancing web of said support to continuously produce a web of said open-pore structure.

11. A method of making a battery electrode which comprises the steps of:

(a) juxtaposing an open-pore reticulated polyurethane foam support having substantially 10 to 100 pores per linear inch with a pair of electrodes in a space evacuated to a pressure of at most 10^-3 torr with at least one of the electrodes being composed of nickel, applying a voltage of substantially 20 to 150 volts across said electrodes with a current of 40 to 150 amperes and striking an arc between said electrodes, to evaporate nickel and deposit evaporated nickel on and in said support to form a nickel-coated support;

(b) pyrolyzing the support following the nickel coating thereof in step (a) in an electric furnace at a temperature of about 350°

C. to form an openwork nickel body; and

(c) sintering said openwork nickel body at a temperature of 950°

C. to 1250°

C. into a coherent openwork nickel structure.