Coextruded, biaxially oriented multilayer film

• US 4,975,329 A
• Filed: 11/21/1988
• Issued: 12/04/1990
• Est. Priority Date: 11/28/1987
• Status: Expired due to Fees

• Current Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Original Assignee: Hoechst Aktiengesellschaft (Sanofi )
• Inventors: Wilheim, Thomas, Bothe, Lothar, Crass, Guenther, Schloegl, Gunter
• Primary Examiner(s): Buffalow, Edith
• Application Number:
  US07/274,334
• Time in Patent Office: 743 Days
• Field of Search: 428/910, 428/516, 428/461, 361/319, 361/313, 361/323
• US Class Current: 428/461
• CPC Class Codes: B32B 15/085 comprising polyolefins
• CPC Class Codes: B32B 2307/206 Insulating
• CPC Class Codes: B32B 2307/518 bi-axially
• CPC Class Codes: B32B 2307/538 Roughness
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/18 characterised by the use of special additives
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 7/027 Thermal properties
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 23/0815 Copolymers of ethene with aliphatic 1-olefins
• CPC Class Codes: C08L 23/10 Homopolymers or copolymers of propene
• CPC Class Codes: C08L 23/12 Polypropene
• CPC Class Codes: C08L 23/20 having four to nine carbon atoms
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: H01G 4/18 of synthetic material, e.g. derivatives of cellulose H01G4/16 takes precedence
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

A coextruded, biaxailly oriented multilayer film comprises a base layer comprising an extremely pure raw material and outer layer. It is suitable for use as an electrically insulating film, as a dielectric in an electrical capacitor, and has improved dielectrical properties for this purpose. The base layer and the outer layer or layers contain propylene polymer on one or both sides and stabilizers for propylene polymers. The raw material for the base layer has an idealized thermal oxidation temperature in the range of 260° to 300° C., preferably in the range 260° to 280° C., and the raw material for the outer layer or layers has an idealized thermal oxidation temperature in the region of 240° to 300° C., preferably in the range 240° to 270° C. The multilayer film as a whole has an idealized thermal oxidation temperature in the range 250° to 290° C., in paticular in the range 250° to 275° C. The content of organic neutralizing agents, in particular calcium stearate, in the raw materials is less than or equal to 100 ppm.

Claims

1. A coextruded, biaxially oriented multilayer film comprising:

(a) a base layer comprising an extremely pure raw material which comprises at least one propylene polymer and at least one stabilizer for propylene polymers, and

(b) an outer layer on at least one side of said base layer, comprising a raw material which comprises at least one propylene polymer and at least one stabilizer for propylene polymers,

wherein said base layer raw material has an idealized thermal oxidation temperature of between about 260 and 300°

C., said outer layer raw material has an idealized thermal oxidation temperature of between about 240 and 300°

C., and said multilayer film as a whole has an idealized thermal oxidation temperature of between about 250 and 290°

C., and wherein said raw materials further comprise from 0 to about 100 ppm of at least one organic neutralizing agent.

2. A multilayer film as claimed in claim 1, wherein said base layer raw material has an idealized thermal oxidation temperature of between about 260 and 280°

C.

3. A multilayer film as claimed in claim 1, wherein said outer layer raw material has an idealized thermal oxidation temperature of between about 240 and 270°

C.

4. A multilayer film as claimed in claim 1, wherein said film as a whole has an idealized thermal oxidation temperature of between about 250 and 275°

C.

5. A multilayer film as claimed in claim 1, wherein said film has an outer layer on each side of the base layer.

6. A multilayer film as claimed in claim 1, wherein said neutralizing agent comprises calcium stearate.

7. A multilayer film as claimed in claim 1, wherein the stabilizer content of said outer layer material is equal to the stabilizer content of said base layer material.

8. A multilayer film as claimed in claim 1, wherein the stabilizer content of said outer layer material is less than the stabilizer content of said base layer material.

9. A multilayer film as claimed in claim 8, wherein the stabilizer content of said outer layer material is less than about 50% by weight of the stabilizer content of said base layer material.

10. A multilayer film as claimed in claim 1, wherein said base and outer layer materials comprise extremely pure polypropylene.

11. A multilayer film as claimed in claim 1, wherein said base and outer layer materials comprise a polymer mixture of polypropylene with at least one polyolefin.

12. A multilayer film as claimed in claim 11, wherein said polyolefin comprises HDPE, LDPE, LLDPE or poly-4-methyl-1-pentene and the proportion of said polyolefin does not exceed about 15% by weight based on the total weight of the polymer mixture.

13. A multilayer film as claimed in claim 1, wherein said base and outer layer materials comprise a block copolymer comprising polypropylene and a comonomer.

14. A multilayer film as claimed in claim 13, wherein said comonomer comprises ethylene and the proportion of said comonomer does not exceed about 10% by weight based on the total weight of the copolymer.

15. A multilayer film as claimed in claim 1, wherein said base and outer layer materials comprise a random copolymer comprising polypropylene and a comonomer.

16. A multilayer film as claimed in claim 15, wherein said comonomer comprises ethylene and the proportion of said comonomer does not exceed about 10% by weight based on the total weight of the copolymer.

17. A multilayer film as claimed in claim 1, wherein said stabilizer comprises a thioether, a phosphonite, a phosphite, or a sterically hindered phenol.

18. A multilayer film as claimed in claim 17, wherein said sterically hindered phenol has a molecular weight greater than about 300 g/mol.

19. A multilayer film as claimed in claim 18, wherein said sterically hindered phenol has a molecular weight greater than about 700 g/mol.

20. A multilayer film as claimed in claim 1, wherein the residual ash content is less than about 50 ppm and the chlorine content is less than about 10 ppm.

21. A multilayer film as claimed in claim 1, wherein the total thickness of the multilayer film is between about 3 and 30 μ

m.

22. A multilayer film as claimed in claim 21, wherein each outer layer has a thickness of from 0.3 to 2.0 μ

m.

23. A multilayer film as claimed in claim 22, wherein each layer is of the same thickness.

24. A multilayer film as claimed in claim 22, wherein each outer layer surface has a roughness R_z less than or equal to about 1.5 μ

m.

25. A multilayer film as claimed in claim 1, which further comprises an outer metal layer.

26. An electrical film capacitor, comprising two metallic electrode layers separated by an electrically insulating film as claimed in claim 1.