Coating composition and cast-coated paper coated with the same

• US 4,975,473 A
• Filed: 03/01/1989
• Issued: 12/04/1990
• Est. Priority Date: 03/02/1988
• Status: Expired due to Fees

• Current Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals), New Oji Paper Co., Ltd.
• Original Assignee: Mitsui Chemicals Incorporated (Mitsui Chemicals), OJI Paper Company Limited (Oji Holdings Corporation)
• Inventors: Matsuda, Noriaki, Hyugaji, Teruo, Yamamoto, Itsuro, Kuroda, Nobuo, Kaneda, Katsumi, Tanaka, Akio
• Primary Examiner(s): Schoffer, Joseph L.
• Assistant Examiner(s): DELMENDO, ROMULO H
• Application Number:
  US07/317,366
• Time in Patent Office: 643 Days
• Field of Search: 523/221, 523/335, 524/426, 524/433, 524/501
• US Class Current: 523/221
• CPC Class Codes: D21H 19/58 Polymers or oligomers of diolefins, aromatic vinyl monomers or unsaturated acids or derivatives thereof

Abstract

A coating composition for a cast-coated paper which principally comprises a pigment and an adhesive and in which the adhesive is composed of (A) a rubber latex having an average particle size of 0.1 to 0.3 micron and (B) a rubber latex or an acrylic emulsion having an average particle size of 0.5 to 1.5 micron and the sum of the solid content of the components (A) and (B) is in the range of 9 to 30 parts by weight per 100 parts by weight of the pigment is herein provided. The coating composition may further contain casein as a binder. In addition, inorganic compounds selected from NaCl, Na₂ SO₄, ZnO and MgO and organic acid salts selected from formates or acetates of Ca, Zn, Mg may be added to the coating composition as coagulants. The use of the aforesaid coating composition makes it possible to produce cast-coated paper having excellent permeability, gloss and surface strength at a high speed.

Claims

1. A coating composition for a cast-coated paper which comprises mainly a pigment and an adhesive, characterized in that the adhesive comprises per 100 parts by weight of the pigment, (A) 2 to 15 parts by weight of casein;

(B) 6 to 18 parts by weight, expressed in solids content, of a rubber latex having an average particle size ranging from 0.1 to 0.3 microns;

(C) 3 to 12 parts by weight, expressed in solids content, of an acrylic emulsion or a secondary particle-forming rubber latex having an average particle size ranging from 0.1 to 0.3 microns; and

(D) at least one inorganic compound selected from the group consisting of NaCl, Na₂ SO₄, ZnO and MgO and at least one organic acid salt selected from the group consisting of formates and acetates of calcium, zinc and magnesium, the total solids content of the components (A), (B) and (C) being in the range of 18 to 40 parts by weight.

2. The coating composition according to claim 1 wherein the latexes as the components (B) and (C) are a rubber emulsion of polymer having repeating units derived from diene type monomers as essential units.

3. The coating composition according to claim 1 wherein the acrylic emulsion as the component (C) is an emulsion of a polymer having repeating units derived from at least one monomer selected from the group consisting of aromatic alkenyl compounds and non-aromatic mono-olefinic unsaturated compounds as principal repeating units.

4. The coating composition according to claim 1 wherein the amount of the component (D) composed of the inorganic and organic compounds to be added to the composition is determined so that the component (C) used as the synthetic binder having a particle size of 0.1 to 0.3 microns is selectively aggregated to form secondary particles and to increase the particle size of the resulting aggregates to 0.5 to 1.5 microns.

5. The coating composition according to claim 4 wherein the amount of the inorganic compound ranges from 0.1 to 7 parts by weight and the amount of the organic acid salt ranges from 0.1 to 3 parts by weight, per 100 parts by weight of the pigment.