Process for the decaffeination of tea

• US 4,976,979 A
• Filed: 03/20/1989
• Issued: 12/11/1990
• Est. Priority Date: 05/02/1985
• Status: Expired due to Term

• Current Assignee: Degussa AG (Rag-Stiftung)
• Original Assignee: SKW Trostberg Aktiengesellschaft (Rag-Stiftung)
• Inventors: Schutz, Erwin, Vollbrecht, Heinz-Rudiger, Klima, Hubertus
• Primary Examiner(s): Golian, Joseph
• Application Number:
  US07/326,510
• Time in Patent Office: 631 Days
• Field of Search: 426/427, 426/481
• US Class Current: 426/427
• CPC Class Codes: A23F 3/366 by extraction of the leaves with selective solvents
• CPC Class Codes: A23F 3/385 using flocculating, precipitating, adsorbing or complex-forming agents, or ion-exchangers
• CPC Class Codes: B01D 11/0219 Fixed bed of solid material
• CPC Class Codes: B01D 11/0284 Multistage extraction

Abstract

The present invention provides a process for the decaffeination of tea containing 15 to 50% by weight of water with moist carbon dioxide at 255 to 350 bar at 50° to 80° C. in a pressure vessel, subsequent separation of the caffeine from the carbon dioxide with the help of an adsorbent and recycling the caffeine-free carbon dioxide over the already extracted tea, wherein the adsorbent is distributed in the material to be extracted in an amount of from 5 to 40% by weight, referred to the dry weight of the tea.

Claims

1. A process for the selective decaffeination of tea, comprising distributing in the tea, a charcoal adsorbing means operable to remove caffeine from solution in carbon dioxide;

adjusting the moisture content of the tea to 15 to 50% by weight of water;

extracting the tea containing 15 to 50% by weight of water in a single step with moist carbon dioxide at 255 to 350 bar and at 50°

to 80°

C. in a pressure vessel thereby to extract the caffeine into the carbon dioxide and remove the caffeine from the carbon dioxide into the adsorbent; and

recycling the caffeine-free carbon dioxide over the already extracted tea and separating the carbon dioxide from the tea essentially without removing flavor, color or aroma from the tea.

2. The process of claim 1, wherein the adsorbing means is active carbon used in an amount of 5 to 40% by weight referred to the dry weight of the tea.

3. The process of claim 1, wherein the adsorbing means is homogeneously mixed with the tea before being placed into the pressure vessel.

4. The process of claim 1, wherein the adsorbing means is distributed by filling the pressure vessel with alternating layers of the tea and adsorbing means.

5. The process of claim 1 further comprising passing the stream of carbon dioxide through a pure adsorbent packing and thereafter removing the carbon dioxide from the pressure vessel for further use.

6. The process of claim 1 wherein said adsorbing means is an adsorbent with a grain size of from 0.1 to 10 mm.

8. The process of claim 6 wherein the adsorbent is enveloped with gas-permeable material.

9. The process of claim 8, wherein the adsorbent is used filled into bags, sacks or tubes of textile material.

10. The process of claim 8, wherein the adsorbent is enveloped in porous clay or porous graphite.

11. The process of claim 1 wherein the carbon dioxide flows through the pressure vessel in the axial or radial direction.

12. The process of claim 1 wherein extraction is carried out for from 1 to 4 hours.

13. The process of claim 1 wherein 0.1 to 3 kg of carbon dioxide are used per gram of caffeine to be removed from the tea.

7. The process of claim 7 further comprising separating the adsorbent from the tea after the extraction by means of cyclone separation, air sifting, sieve classification or electrofiltration.