Multi-function additive for lubricating oils

• US 4,978,464 A
• Filed: 09/07/1989
• Issued: 12/18/1990
• Est. Priority Date: 09/07/1989
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Halbert, Thomas R., Stiefel, Edward I., Coyle, Catherine L.
• Primary Examiner(s): Chaudhuri, Olik
• Assistant Examiner(s): MCAVOY, ELLEN M
• Application Number:
  US07/404,143
• Time in Patent Office: 467 Days
• Field of Search: 252/49.7, 252/49.8, 252/400.54, 252/400.21, 252/46.6, 252/42.7, 252/46.4
• US Class Current: 508/363
• CPC Class Codes: C10M 135/14 having a carbon-to-sulfur double bond
• CPC Class Codes: C10M 135/18 thiocarbamic type, e.g. containing the groups
• CPC Class Codes: C10M 137/10 Thio derivatives
• CPC Class Codes: C10M 137/14 containing sulfur
• CPC Class Codes: C10M 159/18 Complexes with metals
• CPC Class Codes: C10M 2219/062 having carbon-to-sulfur double bonds
• CPC Class Codes: C10M 2219/068 Thiocarbamate metal salts
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10M 2223/06 having phosphorus-to-carbon bonds
• CPC Class Codes: C10M 2223/061 Metal salts
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2070/02 Concentrating of additives

Abstract

A lubricating oil composition is provided which comprises a major amount of an oil of lubricating viscosity and a minor amount of an additive having the formula Mo₄ S₄ L₆ in which L is a ligand selected from dithiocarbamates, dithiophosphates, dithiophosphinates, thioxanthates, and mixtures thereof and in which the ligands, L, have organo groups having a sufficient number of carbon atoms to render the additive soluble in the oil. In general, the organo groups of the ligands, L, will be the same, although they may be different and they preferably are selected from alkyl, aryl, substituted aryl and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.

Claims

1. A lubricating composition comprising:

a major amount of an oil of lubricating viscosity; and

, a minor amount of an additive having the formula Mo₄ S₄ L₆ wherein L is an organo group selected from dithiocarbamates, dithiophosphates, dithiophosphinates, thioxanthates, and mixtures thereof and wherein the organo group has a sufficient number of carbon atoms to render the additive soluble in the oil.

2. The composition of claim 1 wherein the amount of the additive is in the range of from about 0.01 to about 10 weight percent based on the weight of oil.

3. The composition of claim 2 wherein the organo groups are selected from alkyl, aryl, substituted aryl and ether groups.

4. The composition of claim 3 wherein the organo groups are alkyl groups and the number of carbon atoms in the alkyl groups are in the range of from about 1 to 30, provided that when L is a dithiocarbamate, the number of carbon atoms in the alkyl group is greater than 4.

5. The composition of claim 4 wherein the number of carbon atoms is in the range of about 4 to about 20.

6. The composition of claim 2 wherein L is a dithiophosphate.

7. The composition of claim 2 wherein L is a thioxanthate.

8. The composition of claim 2 wherein L is a dithiophosphinate.

9. A lubricating composition comprising:

a major amount of an oil selected from natural and synthetic oils having viscosities in the range of from about 5 to about 26 centistokes at 100°

C., and from about 0.01 to about 10 weight percent of an additive having the formula Mo₄ S₄ L₆, wherein L is an organo group selected from dithiocarbamates, dithiophosphates, dithiophosphinates, thioxanthates, and mixtures thereof and wherein the organo group has from about 1 to about 30 carbon atoms and when the ligand, L, is a dithiocarbamate having alkyl organo groups, the alkyl groups have greater than about 4 carbon atoms.

10. The composition of claim 9 wherein the additive is present in an amount ranging from about 0.1 to about 1.0 weight percent.

11. The composition of claim 10 wherein L is a dithiocarbamate.

12. The composition of claim 10 wherein L is dithiophosphate.

13. The composition of claim 10 wherein L is a thioxanthate.

14. The composition of claim 10 wherein L is a dithiophosphate.

15. An additive concentrate for blending with lubricating oils to provide a lubricating composition having antiwear, antioxidant and friction reducing properties comprising:

a hydrocarbon diluent and from about 1 to about 90 weight percent of an additive, based on the weight of diluent, the additive having the formula Mo₄ S₄ L₆ wherein L is an organo group selected from dithiocarbamates, dithiophosphates, dithiophosphinates, thioxanthates, and mixtures thereof and wherein the organo group has from about 1 to about 30 carbon atoms and when the organo group is a dithiocarbamate having alkyl organo groups, the alkyl groups have greater than about 4 carbon atoms.

16. The concentrate of claim 15 wherein the diluent is an aromatic hydrocarbon and the additive ranges between about 20 to about 70 weight percent, based on the weight of diluent.