Compact reinforced composite

• US 4,979,992 A
• Filed: 02/09/1988
• Issued: 12/25/1990
• Est. Priority Date: 06/09/1986
• Status: Expired due to Term

• Current Assignee: Aalborg Portland A/S
• Original Assignee: Aktieselskabetarlborg Portland-Cement-Fabrik
• Inventors: Bache, Hans H.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Brunsman, David M.
• Application Number:
  US07/159,589
• Time in Patent Office: 1,050 Days
• Field of Search: 106/99, 109/80, 109/82-84
• US Class Current: 106/644
• CPC Class Codes: B29C 70/023 with reinforcing inserts
• CPC Class Codes: C03C 14/002 the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
• CPC Class Codes: C03C 2214/02 Fibres; Filaments; Yarns; Felts; Woven material
• CPC Class Codes: C03C 2214/08 Metals
• CPC Class Codes: C04B 14/06 Quartz; Sand
• CPC Class Codes: C04B 14/303 Alumina
• CPC Class Codes: C04B 14/34 Metals , e.g. ferro-silicon
• CPC Class Codes: C04B 18/14 from metallurgical processes treatment of molten slag C04B5/00
• CPC Class Codes: C04B 20/0048 Fibrous materials
• CPC Class Codes: C04B 20/0076 characterised by the grain distribution
• CPC Class Codes: C04B 2111/00301 Non-porous materials, e.g. macro-defect free [MDF] products
• CPC Class Codes: C04B 2235/5224 Alumina or aluminates
• CPC Class Codes: C04B 2235/524 Non-oxidic, e.g. borides, carbides, silicides or nitrides
• CPC Class Codes: C04B 2235/5244 Silicon carbide
• CPC Class Codes: C04B 2235/5248 Carbon, e.g. graphite
• CPC Class Codes: C04B 2235/5264 characterised by the diameter of the fibers
• CPC Class Codes: C04B 2235/5276 Whiskers, spindles, needles or pins
• CPC Class Codes: C04B 2235/5445 submicron sized, i.e. from 0,1 to 1 micron
• CPC Class Codes: C04B 24/22 Condensation or polymerisation products thereof
• CPC Class Codes: C04B 24/24 Macromolecular compounds C04B24/14 takes precedence; macromolecular compounds comprising sulfonate or sulfate groups C04B24/16
• CPC Class Codes: C04B 26/02 : Macromolecular compounds
• CPC Class Codes: C04B 28/00 : Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
• CPC Class Codes: C04B 28/02 : containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 32/00 : Artificial stone not provided for in other groups of this subclass
• CPC Class Codes: C04B 32/02 : with reinforcements contains no documents; reinforcing elements E04C5/00
• CPC Class Codes: C04B 35/10 : based on aluminium oxide
• CPC Class Codes: C04B 35/117 : Composites
• CPC Class Codes: C04B 35/14 : based on silica
• CPC Class Codes: C04B 35/488 : Composites
• CPC Class Codes: C04B 35/505 : based on yttrium oxide
• CPC Class Codes: C04B 35/76 : Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: C04B 35/80 : Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: E04C 5/073 : Discrete reinforcing elements, e.g. fibres
• CPC Class Codes: Y02W 30/91 : Use of waste materials as fillers for mortars or concrete

Abstract

A compact reinforced composite comprising a matrix (A) with a reinforcement (B) embedded therein, the matrix (A) being a composite structure comprising a base matrix (C) which is reinforced with reinforcing bodies (D) in the form of fibers. The transverse dimension of (B) being at least 5 times as large as the transverse dimension of (D).

Claims

1. A shaped article comprising a matrix (A) with a reinforcement (B) being a composite structure comprising a a cement-based matrix selected from a cement paste, mortar and concrete made from a cement selected from portland cement and refractory cement (C) which is reinforced with reinforcing bodies (D) in the form of fibers, the transverse dimension of the reinforcement B being at least 5 times as large as the transverse dimension of the fibers D, at least one of the group consisting of the article, the matrix A and the base matrix C having high stiffness in any direction as defined by at least one of the following criteria:

(1) the modulus of elasticity in any direction being at least 30,000 MPa, or

(2) the resistance to compression in any direction being at least 80 MPa,

the fibers D being present in a volume concentration of at least 4%, based on the volume of the matrix A, the volume concentration of the reinforcement B in the tensile zone or tensile zones of the article being at least 5%.

2. A shpaed article according to claim 1 which has a yield strain of at least 10 mm/m with retention of a load capacity of at least 50% of the maximum load applied during the course of loading up to the yield.

3. A shaped article according to claim 1, wherein the transverse dimension of the reinforcement B is at least 10 times as large as the transverse dimension of the fibers D.

4. A shaped article according to claim 3, wherein the transverse dimension of the reinforcement B is at least 100 times as large as the transverse dimension of the fibers D.

5. A shaped article according to claim 1, wherein at least one of the group consisting of the article, the matrix A, and the base matrix C has a high stiffness in any direction as defined by at least one of the following criteria:

(1) the modulus of elasticity in any direction being at least 50,000 MPa, or

(2) the resistance to compression in any direction being at least 130 MPa.

6. A shaped article according to claim 1, wherein the fibers D are present in a volume concentration of at least 5%, based on the volume of the matrix A.

7. A shaped article according to claim 6, wherein the fibers D are present in a volume concentration of at least 7%, based on the volume of the matrix A.

8. A shaped article according to claim 7, wherein the fibers D are present in a volume concentration of at least 10%, based on the volume of the matrix A.

9. A shaped article according to claim 1, wherein the volume concentration of the reinforcement B in the tensile zone or tensile zones of the article is at least 7%.

10. A shaped article according to claim 9, wherein the volume concentration of the reinforcement B in the tensile zone or tensile zones of the article is at least 10%.

11. A shaped article according to claim 10, wherein the volume concentration of the reinforcement B in the tensile zone or tensile zones of the article is at least 15%.

12. A shaped article according to claim 1, comprising a matrix (A) with a reinforcement (B) embedded therein, the matrix (A) being a composite structure comprising a base matrix (C) which is reinforced with reinforcing bodies (D) in the form of fibers. whereby the strain capacity of the matrix (A) is increased over that of the base matrix (C) so that the ratio between the strain capacity of the matrix (A) and the strain capacity of the base matrix (C) is at least 1.2.

13. A shaped article according to claim 12, wherein the ratio between the strain capacity of the matrix (A) and the strain capacity of the base matrix (C) is at least 5.

14. A shaped article according to claim 12, wherein the amount, shape, arrangement, and performance of the reinforcement (B) are adapted to the matrix (A) so that the strain capacity of the matrix (A) with the reinforcement embedded therein is increased relative to the strain capacity of the matrix (A) in bulk so that the ratio between the strain capacity of the matrix (A) with the reinforcement embedded therein and the matrix (A) in bulk is at least 1.2.

15. A shaped article according to claim 14, wherein the ratio between the strain capacity of the matrix (A) with the reinforcement embedded therein and the matrix (A) in bulk is at least 5.

16. A shaped article according to claim 1, wherein the base matrix (C) is a cement-based matrix selected from a cement paste, mortar and concrete made from a cement selected from Portland Cement and refractory cement, the matrix material being in a dense packing corresponding to a water/powder ratio of at the most 0.30 by weight.

17. A shaped article according to claim 16 wherein the water/powder ratio in the base matrix (C) is at the most 0.20 by weight.

18. A shaped article according to claim 16 wherein the base matrix (C) further comprises additional particles which are at least one power of 10 smaller than the cement particles.

19. A shaped article according to claim 18, wherein the additional particles are microsilica particles.

20. A shaped article according to claim 16, wherein some or all of the water in the base matrix (C) is replaced by a water-soluble polymer.

21. A shaped article according to claim 16, wherein the paste, mortar or concrete contains additional bodies of strong materials selected form the group consisting of quartz, Al₂ O₃, steel and glass.

22. A shaped article according to claim 21, wherein the base matrix (C) further comprises wollastonit.

23. A shaped article according to claim 1, wherein the bodies (D) are fibers selected from the group consisting of glass fibers, polypropylene fibers, Kevlar fibers, carbon fibers, ceramic fibers, including aluminum oxide fibers, silicon nitride fibers and silicon carbide fibers, and steel fibers, with a fiber diameter of less than 400 μ

m, the fibers being present in a volume concentration of at least 5%, based on the volume of the matrix (A).

24. A shaped article according to claim 23, wherein the fibers have a diameter of less than 200 μ

m.

25. A shaped article according to claim 23, wherein the bodies (D) are fibers having a strength larger than 300 MPa.

26. A shaped article according to claim 25, wherein the fibers have a strength larger than 800 MPa.

27. A shaped article according to claim 1, wherein the bodies (D) comprise fibers with a fiber diameter in at least one of the ranges 4-1 mm, 1-0.3 mm, 300-100 μ

m, 100-30 μ

m, 30-10 μ

m and less than 10 μ

m.

28. A shaped article according to claim 27, wherein the bodies (D) are fibers having a strength larger than 300 MPa.

29. A shaped article according to claim 28, wherein the fibers have a strength larger than 800 MPa.

30. A shaped article according to claim 1, wherein the modulus of elasticity of fibers incorporated in the matrix, E_f, is at least 2×

10¹⁰ N/m², and the modulus of elasticity of the material material, E_m, is at least 10¹⁰ N/m².

31. A shaped article according to claim 30, wherein the modulus of elasticity of fibers incorporated in the matrix, E_f, is at least 2×

10¹¹ N/m².

32. A shaped article according to claim 30, wherein the modulus of elasticity of the matrix material, E_f, is at least 50×

10¹⁰ N/m².

33. A shaped article according to claim 1, wherein the reinforcement (B) is selected from the group consisting of bars, rods and threads.

34. A shaped article according to claim 33, wherein the reinforcement (B) is selected from the group consisting of deformed steel bars a pre-stressing wires and cables, and fiber-polymer composite reinforcement.

35. A shaped article according to claim 33, wherein some of or all of the reinforcing bodies (B) are in the form of short components selected from discrete small rods and fibers.

36. A shaped article according to claim 1, which comprises a reinforcement transverse to the reinforcement (B), the transverse reinforcement being substantially straight and arranged substantially perpendicular to the reinforcement B.

37. A shaped article according to claim 36, wherein the transverse reinforcement has a deformed and/or rough surface texture substantially perpendicular to the longitudinal direction of the transverse reinforcement.

38. A shaped article according to claim 37, wherein the transverse reinforcement has a structure selected from a deformed bar structure and a thread structure.

39. A shaped article according to claim 1, wherein the strength of the reinforcement (B) is at least 400 MPa.

40. A shaped article according to claim 1, wherein the reinforcement (B) has a modulus of elasticity of at least 5×

10¹⁰ N/m².

41. A shaped article according to claim 40, wherein the reinforcement (B) has a modulus of elasticity of at least 5×

10¹¹ N/m².

42. A shaped article according to claim 1, in which the number of reinforcing bodies B in the tensile zone, as judged from a plane perpendicular to the reinforcement, is at least 2.

43. A shaped article according to claim 1, in which the reinforcement B is arranged in such a manner that the article has a high stiffness in at least two directions perpendicular to each other as defined by at least one of the following criteria:

(1) the modulus of elasticity in at least two direction perpendicular to each other being at least 30,000 MPA, or

(2) the resistance to compression in at least two directions perpendicular to each other being at least 80 MPA.

44. A shaped article comprising a matrix (A) with a reinforcement (B) being a composite structure comprising a a cement-based matrix selected from a cement paste, mortar and concrete made from a cement selected from portland cement and refractory cement (C) which is reinforced with reinforcing bodies (D) in the form of fibers, the transverse dimension of the reinforcement B being at least 5 times as large as the transverse dimension of the fibers D, at least one of the group consisting of the article, the matrix A and the base matrix C having high stiffness in any direction as defined by at least one of the following criteria:

(1) the modulus of elasticity in any direction being at least 30,000 MPa, or

(2) the resistance to compression in any direction being at least 80 MPa, the fibers D being present in a volume concentration of at least 2%, based on the volume of the matrix A, the volume concentration of the reinforcement B in the tensile zone or tensile zones of the article being at least 5%, the article showing at least one of the following qualities I, II, III;

(I) a large tensile strain capacity with retention of substantial coherence of the article as defined by the tensile zone of the article having a tensile strain capacity of at least 0.5 mm/m, the article retaining substantial coherence during the straining as defined by the absence of any cracks passing the reinforcement B, or by any damage in the tensile zone in the form of fine cracks passing the reinforcement B having a width of at the most 0.2 mm, with the proviso that the ratio between the crack width and the smallest transverse diameter of the reinforcement B is at the most 0.02,

(II) a large tensile load capacity (referring to stresses in the tensile zone of the article) defined by the tensile load capacity fulfilling at least one of the following conditions (a), (b), and (c);

(a) under conditions of substantially elastic behavior, the tensile load capacity of the article corresponds to a tensile stress of at least 50 MPa, with retention of coherence during the straining as defined by the tensile zone of the article having a tensile strain capacity of at least 0.5 mm/m, the article retaining substantial coherence during the straining as defined by the absence of any cracks passing the reinforcement B, or by any damage in the tensile zone in the form of fine cracks passing the reinforcement B having a width of at the most 0.2 mm, with the proviso that the ratio between the crack width and the smallest transverse diameter of the reinforcement B is at the most 0.02,

(b) under yielding, the tensile load capacity of the article corresponds to a tensile stress of at least 70 MPa, with the retention of coherence as defined by the absence of any cracks passing the reinforcement B, or by any damage in the tensile zone in the form of fine cracks passing the reinforcement B having a width of at the most 1 mm, with the proviso that the ratio between the crack width and the smallest transverse diameter of the reinforcement B is at the most 0.10,

(c) under ultimate loading, the article shows a tensile load capacity corresponding to at least 120 MPa,

(III) an increase in tensile strain capacity of the matrix defined as the amount, shape, arrangement, and performance of the reinforcement (B) being adapted to the matrix (A) so that the strain capacity of the matrix (A) with the reinforcement embedded therein is increased relative to the strain capacity of the matrix (A) in bulk so that the ratio between the strain capacity of the matrix (A) with the reinforcement embedded therein and the matrix (A) in bulk is at least 1.2.

45. A shaped article according to claim 44, which has a yield strain of at least 10 mm/m with retention of a load capacity of at least 50% of the maximum load applied during the course of loading up to the yield.

46. A shaped article comprising a matrix (A) with a reinforcement (B) embedded therein, the matrix (A) being a composite structure comprising a base matrix (C) which is reinforced with reinforcing bodies (D) in the form of fibers, the article containing 5-40% by volume of reinforcement in the form of bars with a transverse dimension, of 5-25 mm, embedded in a fiber-reinforced matrix made with 20-60% by volume of large compact-shaped bodies with a maximum particle size of 10 mm, 4-20% by volume of fibers with a length of at least 2 mm, and a diameter of 5-400 μ

m, and 20-56% by volume of a binder-forming material made from

20-50% volume of water, 25-75% by volume of cement, 5-40% by volume of ultrafine powder of a size in the range between 50 and 0.5 μ

m, the ultrafine powder having a reactivity which is less than the reactivity of the cement, and a dispersing agent.

47. A shaped article according to claim 46, wherein the reinforcement with a transverse dimension of 5-25 mm is in the form of steel bars.

48. A shaped article according to claim 46, wherein the large compact-shaped bodies with a maximum particle size of 10 mm are selected from the group consisting of sand, stone and metal powder.

49. A shaped article according to claim 48, wherein the compact-shaped bodies comprise sand selected from the group consisting of quartz sand and Al₂ O₃ sand.

50. A shaped article according to claim 46, wherein the binder-forming material is further made from a water-soluble polymer.

51. A shaped article according to claim 46, wherein the ultrafine powder in the binder-forming material is selected from ultrafine silica having a BET surface area in the range of about 200,000-250,000 cm² /g and ultra fine Al₂ O₃.

52. A shaped article according to claim 46, wherein the dispersing agent in the binder-forming material is a concrete superplasticizer in an amount of 0.5-4% by volume, on a powder basis, based on the volume of the binder-forming material.

53. A shaped article according to claim 46, wherein the binder-forming material further comprises up to 30% by volume of a powder having a particle size of 2-10 μ

m.

54. A shaped article comprising a matrix (A) with a reinforcement (B) embedded therein, the matrix (A) being a composite structure comprising a base matrix (C) which is reinforced with reinforcing bodies (D) in the form of fibers, the article containing 5-40% by volume of reinforcement with a transverse dimension of 0.2-5 mm, embedded in a fine fiber-reinforced matrix made with 0-50% by volume of particles having a maximum particle size of 1 mm, the particles being selected from fine sand and metal particles, 4-20% by volume of fibers with a length from 20 μ

m to 5 mm and a diameter of 0.5-200 μ

m together with 30-96% by volume of a binder-forming material made from 20-50% by volume of water, 10-75% by volume of cement, 5-40% by volume of ultrafine powder of a size in the range between 50 Å and

0.5 μ

m, the ultrafine powder having a reactivity which is less than the reactivity of the cement, and a a dispersing agent.

55. A shaped article according to claim 54, wherein the reinforcement with a transverse dimension of 0.2-5 mm is selected from the group consisting of continuous wires and chopped wired.

56. A shaped article according to claim 55, wherein the wires are steel wires.

57. A shaped article according to claim 56, wherein the particles in the fiber-reinforced matrix having a maximum particle size of 1 mm comprise Al₂ O₃ sand.

58. A shaped article according to claim 54 wherein the binder-forming material is further made from a water-soluble polymer.

59. A shaped article according to claim 54, wherein the ultrafine powder in the binder-forming material is selected from ultrafine silica having a BET surface area in the range of about 200,000-250,000 cm² /g and ultrafine Al₂ O₃.

60. A shaped article according to claim 54, wherein the dispersing agent in the binder-forming material is a concrete superplasticizer in an amount of 0.5-4% by volume on a powder basis, based on the volume of the binder-forming material.

61. A shaped article according to claim 54, wherein the binder-forming material further comprises up to 30% by volume of a powder having a particle size of 2-10 μ

m.