Stabilized propellant composition for the generation of nontoxic propellant gases

• US 4,981,536 A
• Filed: 12/19/1989
• Issued: 01/01/1991
• Est. Priority Date: 12/20/1988
• Status: Expired due to Fees

• Current Assignee: Dynamit Nobel AG
• Original Assignee: Dynamit Nobel AG
• Inventors: Bender, Richard
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/453,944
• Time in Patent Office: 378 Days
• Field of Search: 149/35, 149/61
• US Class Current: 149/35
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

The present invention concerns propellant compositions for the generation of nontoxic gases which are utilized, for example, in airbag generators. These compositions contain, as a gas-yielding component, at least one alkali azide. According to the invention, the compositions are stabilized against the effects of moisture and carbon dioxide by the addition of talc and/or magnesium oxide. These additives are included in amounts of from 3 to 10% by weight. The additive acts so that the propellant compositions do not release hydrazoic acid even under the action of moisture and/or carbon dioxide.

Claims

1. A propellant composition for generating nontoxic propellant gases wherein hydrazoic acid is not released, which comprises an alkali azide, an inorganic oxidizing agent, and as the stabilizer for preventing release of hydrazoic acid upon exposure of the composition to humid and carbon dioxide-containing atmosphere, magnesium oxide and/or talc in amounts of between 3 and 10% by weight, based on the weight of the total composition;

said talc having a MgO content of between 26% and 31.6% by weight.

2. A propellant composition according to claim 1, wherein said composition contains a mixture of the magnesium oxide and talc in which the ratio of talc:

magnesium oxide ranges from 10;

1 to 1.3;

1.

3. A propellant composition according to claim 1, wherein said composition contains, besides an alkali azide and an inorganic oxidizing agent, additional finely dispersed silicon dioxide or another compound leading to the formation of vitreous melts.

4. A propellant composition according to claim 2, wherein said composition contains, besides an alkali azide and an inorganic oxidizing agent, additional finely dispersed silicon dioxide or another compound leading to the formation of vitreous melts.

5. A propellant composition according to claim 4, wherein the composition contains 50 to 60% by weight of an alkali azide, 10 to 30% by weight of an oxidizing agent and up to 20% by weight of the compound leading to the formation of vitreous melts.

6. A propellant composition according to claim 5, wherein the alkali azide is sodium azide;

the oxidizing agent is potassium nitrate; and

the compound leading to the formation of vitreous melts is pyrogenic silicic acid.

7. A propellant composition according to claim 1, wherein the talc is a mineral represented by the formula:

3MgO·

4SiO₂ ·

H₂ O wherein portions of the MgO can be replaced with calcium oxide, Al₂ O₃ and Fe₂ O₃ ;

the proportions of Al₂ O₃ can be up to 4% by weight, the proportions of calcium oxide can be up to 6% by weight, and the proportions of Fe₂ O₃ can be up to 2% by weight.

8. A propellant composition according to claim 3, wherein the composition contains 50 to 60% by weight of an alkali azide, 10 to 30% by weight of an oxidizing agent and up to 20% by weight of the compound leading to the formation of vitreous melts.

9. A propellant composition according to claim 8, wherein the alkaline azide is sodium azide;

the oxidizing agent is potassium nitrate; and

the compound leading to the formation of vitreous melts is pyrogenic silicic acid.

10. A propellant composition according to claim 1, wherein the composition contains as a stabilizer, magnesium oxide and/or talc in amounts of from 5 to 8% by weight.

11. A propellant composition according to claim 1, wherein the stabilizer consists of a mixture of magnesium oxide and talc.

12. A propellant according to claim 11, wherein the talc is a mineral represented by the formula:

3MgO·

4SiO₂ ·

H₂ O, wherein portions of the MgO can be replaced with calcium oxide, Al₂ O₃ and Fe₂ O₃ ;

the proportions of Al₂ O₃ can be up to 4% by weight, the proportions of calcium oxide can be up to 6% by weight, and the proportions of Fe₂ O₃ can be up to 2% by weight.

13. A propellant composition according to claim 12, wherein said composition contains the mixture of magnesium oxide and talc in a ratio of talc:

magnesium oxide ranging from 10;

1 to 1.3;

1.

14. A propellant composition according to claim 1, wherein the stabilizer consists of magnesium oxide.

15. A propellant composition according to claim 1, wherein the stabilizer consists of talc.

16. A propellant composition according to claim 14, wherein the talc is a mineral represented by the formula:

3MgO·

4SiO₂ ·

H₂ O wherein portions of the MgO can be replaced with calcium oxide, Al₂ O₃ and Fe₂ O₃ ;

the proportions of Al₂ O₃ can be up to 4% by weight, the proportions of calcium oxide can be up to 6% by weight, and the proportions of Fe₂ O₃ can be up to 2% by weight.