Process for formation of base

• US 4,981,965 A
• Filed: 09/09/1988
• Issued: 01/01/1991
• Est. Priority Date: 09/09/1987
• Status: Expired due to Term

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fuji Photo Film Co Limited (Fujifilm Holdings Corporation)
• Inventors: Nakamura, Taku, Tsukahara, Jiro, Yabuki, Yoshiharu
• Primary Examiner(s): Raymond, Richard L.
• Application Number:
  US07/242,406
• Time in Patent Office: 844 Days
• Field of Search: 564/236, 544/402, 544/196, 546/306, 548/316
• US Class Current: 544/196
• CPC Class Codes: G03C 1/615 Substances generating bases

Abstract

A base precursor in the form of a salt of an organic base with a carboxylic acid is disclosed. The organic base is a diacidic to tetraacidic base which is composed of two to four guanidine moieties and at least one linking group for the guanidine moities. The organic base is such a hydrophilic compound that the number of carbon atoms contained in the organic base is not more than six times the number of the guanidine moieties. The linking group is a residue of a hydrocarbon or a heterocyclic ring. The guanidine moiety corresponds to an atomic group formed by removing one or two hydrogen atoms from a compound having the following formula (I): ##STR1## where each of R¹, R², R³, R⁴ and R⁵ independently is hydrogen, an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, an aralkyl group, an aryl group or a heterocyclic group, each of which may have one or more substituent groups, and any two of R¹, R², R³, R⁴ and R⁵ may be combined together to form a five-membered or six-membered nitrogen-containing heterocyclic ring. A process for formation of an organic base from the base precursor and a light-sensitive material containing the base precursor are also disclosed.

Claims

1. A process for formation of a base comprising the step of heating a base precursor in the form of a salt of an organic base with a carboxylic acid which has such a property that the carboxyl group of the acid undergoes decarboxylation at a temperature of 50°

to 200°

C., wherein the organic base is a diacidic to tetraacidic base having the following formula (II);

space="preserve" listing-type="equation">R.sup.6 (--B).sub.n (II)

wherein R⁶ is an n-valent residue of a hydrocarbon or a heterocyclic ring, the number of the carbon atoms contained in the organic base is not more than six times the number of the guanidine moieties, "n" is an integer of 2 to 4, and "B" is a monovalent group corresponding to an atomic group formed by removing one hydrogen atom from a compound having the following formula (I);

##STR28## wherein each of R¹, R², R³, R⁴ and R⁵ independently is a monovalent group selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, an alkynyl group, a cycloalkyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups, and any two of R¹, R², R³, R⁴ and R⁵ may be combined together to form a five-membered or six-membered nitrogen-containing heterocyclic ring.

2. The process as claimed in claim 1, wherein the base precursor is heated at a temperature of 80°

to 250°

C.

3. The process as claimed in claim 1, wherein the base precursor is heated the presence of a polymer.

4. The process as claimed in claim 1, wherein each of R¹ to R⁵ in the formula (I) is hydrogen or an alkyl group.

5. The process as claimed in claim 1, wherein the compound having the formula (I) is guanidine.

6. The process as claimed in claim 1, wherein the number of carbon atoms contained in the organic base is not more than five times the number of the guanidine moieties.

7. The process as claimed in claim 1, wherein the organic base has a symmetrical chemical structure.

8. The process as claimed in claim 1, wherein the number of the guanidine moieties is 2.

9. The process as claimed in claim 1, wherein R⁶ in the formula (II) is an alkylene group or an arylene group, which may have one or more substituent groups.

10. The process as claimed in claim 1, wherein the carboxylic acid has an aryl group or an arylene group.

11. The process as claimed in claim 1, wherein the carboxylic acid has the following formula (III-I):

##STR29## wherein each of R³¹ and R³² independently is a monovalent group selected from the group consisting of hydrogen, an alkyl group, an alkenyl group, a cycloalkyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups, "k" is 1 or 2;

provided that when "k" is 1, Y is a monovalent group selected from the group consisting of an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group and a heterocyclic group, each of which may have one or more substituent groups, and when "k" is 2, "Y" is a divalent group selected from the group consisting of an alkylene group, an arylene group and a heterocyclic group, each of which may have one or more substituent groups.

12. The process as claimed in claim 1, wherein the salt of the organic base with the carboxylic acid has a melting point of 50°

to 200°

C.