Heat reflecting glass plate with multilayer coating

• US 4,985,312 A
• Filed: 12/01/1989
• Issued: 01/15/1991
• Est. Priority Date: 12/13/1988
• Status: Expired due to Fees

• Current Assignee: Central Glass Company Limited
• Original Assignee: Central Glass Company Limited
• Inventors: Nakamura, Masato, Furuya, Koichi, Nakashima, Hiroshi, Takeuchi, Nobuyuki, Iida, Yasunobu
• Primary Examiner(s): Dean, W.
• Assistant Examiner(s): WYSZOMIERSKI, GEORGE P
• Application Number:
  US07/444,717
• Time in Patent Office: 410 Days
• Field of Search: 428/623, 428/627, 428/630, 428/632, 428/658, 428/673, 428/674
• US Class Current: 428/627
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3626 one layer at least containing a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3649 made of metals other than silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 2217/948 Layers comprising indium tin oxide [ITO]
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
• CPC Class Codes: Y10T 428/12576 Boride, carbide or nitride component
• CPC Class Codes: Y10T 428/12597 Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12792 Zn-base component
• CPC Class Codes: Y10T 428/12896 Ag-base component

Abstract

The invention provides a heat reflecting glass plate with a multilayer coating on a transparent glass plate. The multilayer coating comprises a film of indium-tin oxide (ITO) of Al=N deposited on the glass surface, a heat reflective film of Ag or Cu deposited on the ITO or AlN film to a thickness of 40-200 Å, a metal Zn film deposited on the Ag or Cu film to a thickness of 20-200 Å and an ITO or AlN film as the outermost layer. The multilayer coating may further comprise at least one set of the Ag or Cu film, metal Zn film and ITO or AlN film such that each Ag or Cu film overlies an ITO or AlN film and is overlaid with a metal Zn film and that the outermost layer is an ITO or AlN film. The multilayer coating is excellent in the fundamental characteristics as a heat reflecting and transparent coating and also in moisture resistance.

Claims

1. A heat reflecting glass plate, comprising a transparent glass plate and a multilayer coating formed on one side of the glass plate, the multilayer coating comprising:

a base layer which is a film of a protective material selected from the group consisting of indium-tin oxide and AlN deposited on the glass plate surface;

a first heat reflective layer which is a film of a metal selected from the group consisting of Ag and Cu deposited on said base layer and has a thickness in the range from 40 to 200 Å

;

a first barrier layer which is a metal Zn film deposited on said first heat reflective layer and has a thickness in the range from 20 to 200 Å

;

a first protective layer which is a film of said protective material deposited on said first barrier layer;

a second heat reflective layer which is a film of said metal selected from the group consisting of Ag and Cu deposited on said first protective layer and has a thickness in the range from 40 to 200 Å

;

a second barrier layer which is a metal Zn film deposited on said second heat reflective layer and has a thickness in the range from 20 to 200 Å

; and

a second protective layer which is a film of said protective material deposited on said second barrier layer.

2. A heat reflecting glass plate according to claim 1, wherein the thickness of each of said first and second heat reflective layers is in the range from 50 to 150 Å

.

3. A heat reflecting glass plate according to claim 1, wherein the thickness of each of said first and second barrier layers is in the range from 50 to 100 Å

.

4. A heat reflecting glass plate according to claim 1, wherein said transparent glass plate is an inorganic glass plate.

5. A heat reflecting glass plate according to claim 1, wherein said transparent glass plate is an organic glass plate.

6. A heat reflecting glass plate, comprising a transparent glass plate and a multilayer coating formed on one side of the glass plate, the multilayer coating comprising:

a base layer which is a film of a protective material selected from the group consisting of indium-tin oxide and AlN deposited on the glass plate surface;

a heat reflective layer which is a film of a metal selected from the group consisting of Ag and Cu deposited on said base layer and has a thickness in the range from 40 to 200 Å

;

a barrier layer which is a metal Zn film deposited on said heat reflective layer and has a thickness in the range from 20 to 200 Å

; and

a protective layer which is a film of said protective material,

wherein said heat reflective layer is smaller in surface area than the other layers such that only in a peripheral region of the glass plate said barrier layer makes direct contact with said base layer.

7. A heat reflecting glass plate, comprising a transparent glass plate and a four-layer coating formed on one side of the glass plate, the four-layer coating comprising:

a base layer which is an AlN film deposited on the glass plate surface;

a heat reflective layer which is a film of a metal selected from the group consisting of Ag and Cu deposited on said base layer and has a thickness in the range form 40 to 200 Å

;

a barrier layer which is a metal Zn film deposited on said heat reflective layer and has a thickness in the range from 20 to 200 Å

; and

a protective layer which is an AlN film deposited on said barrier layer.

8. The heat reflecting glass plate of claim 7, wherein the thickness of said heat reflective layer is in the range from 50 to 150 Å

.

9. The heat reflecting glass plate of claim 7, wherein the thickness of said barrier layer is in the range from 50 to 100 Å

.

10. The heat reflecting plate of claim 7, wherein said transparent glass plate is an inorganic glass plate.

11. The heat reflecting plate of claim 7, wherein said transparent glass plate is an organic glass plate.