Polyurethane sealants made using high molecular weight polyols prepared with double metal cyanide catalysts

• US 4,985,491 A
• Filed: 10/05/1989
• Issued: 01/15/1991
• Est. Priority Date: 10/05/1989
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: OLIN Corporation
• Inventors: Reisch, John W.
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US07/417,356
• Time in Patent Office: 467 Days
• Field of Search: 524/875, 528/59, 528/60, 528/61, 528/64, 528/65
• US Class Current: 524/875
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/307 Atmospheric humidity
• CPC Class Codes: C08G 18/4812 Mixtures of polyetherdiols with polyetherpolyols having at least three hydroxy groups
• CPC Class Codes: C08G 18/4829 Polyethers containing at least three hydroxy groups C08G18/4833 - C08G18/5096 take precedence
• CPC Class Codes: C08G 18/4866 having a low unsaturation value
• CPC Class Codes: C08G 2190/00 Compositions for sealing or packing joints
• CPC Class Codes: C08G 65/2663 Metal cyanide catalysts, i.e. DMC's

Abstract

This invention relates to a method of fabricating a polyurethane sealant composition employing a polyether triol having a molecular weight of between about 5,000 and about 30,000 and having a level of end group unsaturation of no greater than 0.04 milliequivalents per gram of triol, wherein the triol is fabricated in the presence of a double metal cyanide catalyst. The triol is reacted, alone or in admixture with a diol, with a polyisocyanate to produce an isocyanate-terminated prepolymer. The prepolymer is then chain-extended to produce the desired sealant.

Claims

1. A polyurethane sealant composition made by reacting an isocyanate-terminated prepolymer with a chain extender, said isocyanate-terminated prepolymer being the reaction product of a polyisocyanate and a polyether triol having a molecular weight of between about 5,000 and about 30,000, said triol having an end group unsaturation level of no greater than 0.04 milliequivalents per gram of triol.

4. The composition of claim 1 which additionally contains at least one compounding ingredient.

5. The composition of claim 4 wherein said compounding ingredient is selected from the group consisting of plasticizers, uv stabilizers, adhesion promoters, fillers and pigments.

6. The composition of claim 4 wherein said compounding ingredient is employed in an amount of between 0 and about 75 weight percent based upon the total weight of the composition.

2. A polyurethane sealant composition comprising a chain-extended reaction product of at least one polyisocyanate with a polyol mixture containing a polyether diol having a molecular weight of between about 500 and about 15,000 and a polyether triol having a molecular weight of between about 5,000 and about 30,000, said triol and diol having end group unsaturation levels of no greater than 0.04 milliequivalents per gram of polyol, thereby producing an isocyanate-terminated prepolymer, said prepolymer being reacted with a chain-extender to produce said chain-extended reaction product.

7. The composition of claim 2 which additionally contains at least one compounding ingredient.

8. The composition of claim 7 wherein said compounding ingredient is selected from the group consisting of plasticizers, uv stabilizers, adhesion promoters, fillers and pigments.

9. The composition of claim 7 wherein said compounding ingredient is employed in an amount of between 0 and about 75 weight percent based upon the total weight of the composition.

3. A method of fabricating a polyurethane sealant composition which comprises the steps of:

(a) fabricating a polyether triol having a molecular weight of between about 5,000 and about 30,000 and having a level of end group unsaturation of no greater than 0.04 milliequivalents per gram of triol, said triol being fabricated in the presence of a double metal cyanide catalyst,

(b) fabricating a polyether diol having a molecular weight between 500 and 15,000, with the proviso that if said diol has a molecular weight of greater than 3,000, then the diol is fabricated using a double metal cyanide catalyst and the diol has an end group unsaturation level of no greater than 0.04 milliequivalents per gram of diol,

(c) mixing said triol with said diol to provide a polyol mixture,

(d) reacting said polyol mixture with a polyisocyanate to produce an isocyanate-terminated prepolymer, and

(e) reacting said isocyanate-terminated prepolymer with a chain extender or allowing said prepolymer to react with moisture in order to produce a chain-extended polyurethane sealant.

10. The composition of claim 3 wherein said sealant composition additionally contains at least one compounding ingredient.

11. The composition of claim 10 wherein said compounding ingredient is selected from the group consisting of plasticizers, uv stabilizers, adhesion promoters, fillers and pigments.

12. The composition of claim 10 wherein said compounding ingredient is employed in an amount of between 0 and about 75 weight percent based upon the total weight of the composition.