Placement process for oil field chemicals

• US 4,986,353 A
• Filed: 09/14/1988
• Issued: 01/22/1991
• Est. Priority Date: 09/14/1988
• Status: Expired due to Fees

• Current Assignee: Conoco Incorporated (ConocoPhillips), E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: Conoco Incorporated (ConocoPhillips), E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Whitfill, Donald L., Clark, Charles R., Bellis, Harold E., McBride, Edward F., Cords, D. Philip
• Primary Examiner(s): Stoll, Robert L.
• Assistant Examiner(s): Geist, Gary L.
• Application Number:
  US07/244,433
• Time in Patent Office: 860 Days
• Field of Search: 252/8.551, 252/8.552, 252/8.553, 252/8.555, 252/315.4, 166/279, 166/310, 166/371, 166/902
• US Class Current: 166/279
• CPC Class Codes: C09K 8/516 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/536 characterised by their form or by the form of their components, e.g. encapsulated material
• CPC Class Codes: C09K 8/92 characterised by their form or by the form of their components, e.g. encapsulated material C09K8/70 takes precedence
• CPC Class Codes: Y10S 166/902 for inhibiting corrosion or coating
• CPC Class Codes: Y10S 507/902 Controlled release agent
• CPC Class Codes: Y10S 507/922 Fracture fluid

Abstract

Oil field chemicals are incorporated in polymeric particles of the condensation product of hydroxyacetic acid or the co-condensation product of hydroxyacetic acid and other compounds containing hydroxy-, carboxylic acid-, or hydroxycarboxylic acid moieties. The particles are introduced into an oil well bore and/or subterranean oil formation where the polymeric particles dissolve over a period of time and release the oil field chemicals.

Claims

1. The process for the continuous release of an oil field chemical within a subterranean hydrocarbon bearing formation or wellbore penetrating such formation comprising:

(a) placing said oil field chemical in a solid polymeric matrix comprising the condensation product of hydroxyacetic acid monomer or hydroxyacetic acid co-condensed with up to 15 percent by weight of other hydroxy-, carboxylic acid-, or hydroxycarbonyl acid-containing moieties, said condensation product having a number average molecular weight of from about 200 to about 4000;

(b) dispersing particles of such solid polymeric matrix containing such chemical in a wellbore fluid which is a non-solvent for such polymeric particles and contained chemical; and

(c) introducing said wellbore fluid containing said particles into a wellbore or subterranean formation through a wellbore;

then

(d) allowing water and temperature to degrade said particulate condensation products to form water soluble and oil soluble components; and

thereby

(e) continuously releasing said chemical from said degraded particulate condensation products.

2. The process as described in claim 1 wherein the chemical in the solid particulate matrix is at least one chemical selected from the group consisting of scale inhibitors, corrosion inhibitors, surfactants, bacteriacides, paraffin dispersants, pourpoint modifiers, cement additives, fracture fluid cross linkers, emulsion breaking chemicals, chemical tracers, radioactive tracers, and asphaltene treatment chemicals.

3. The process as described in claim 1 wherein the chemical is placed in the solid particulate matrix by combining the chemical with condensation product in the molten state and thereafter allowing the condensation product to cyrstallize.

4. The process as described in claim 2 wherein the chemical is placed in a polymeric matrix comprising the condensation product of hydroxyacetic acid with at least one co-condensing compound selected from the group consisting of citric acid, lactic acid, trimethylol-ethane, 2,2-(bishydrozy-methyl) propanoic acid and adipic acid.

5. The process as described in claim 4 wherein the treatment chemical is present in the solid particulate matrix at concentrations of from about 5% to about 80% by weight of the particulate matrix.

6. The process as described in claim 5 wherein the solid particulate matrix particles range in average diameter from about 1 micron to about 900 microns.

7. The process as described in claim 1 wherein the solid particulate matrix has a number average molecular weight of from about 200 to about 650.