Method of forming a ceramic product

• US 4,987,104 A
• Filed: 11/01/1988
• Issued: 01/22/1991
• Est. Priority Date: 03/14/1986
• Status: Expired due to Fees

• Current Assignee: Commonwealth Scientific & Industrial Research Organisation (Commonwealth Of Australia As Represented By Department Of Industry, Innovation, Climate Change, Science, Research And Tertiary Education)
• Original Assignee: Commonwealth Scientific & Industrial Research Organisation (Commonwealth Of Australia As Represented By Department Of Industry, Innovation, Climate Change, Science, Research And Tertiary Education)
• Inventors: Trigg, Mark B.
• Primary Examiner(s): Dixon, Jr., William R.
• Assistant Examiner(s): Gallo, Chris
• Application Number:
  US07/272,804
• Time in Patent Office: 812 Days
• Field of Search: 501/92, 501/97, 501/95, 501/98, 106/65
• US Class Current: 501/92
• CPC Class Codes: C04B 35/584 based on silicon nitride
• CPC Class Codes: C04B 35/593 obtained by pressure sintering
• CPC Class Codes: C04B 35/597 based on silicon oxynitride, e.g. SIALONS
• CPC Class Codes: C04B 35/80 Fibres, filaments, whiskers, platelets, or the like

Abstract

A method of forming a dense ceramic product comprised of silicon nitride and silicon oxynitride or aluminum substituted derivative of either in which silica is subjected to a controlled partial carbothermal reduction process in the presence of nitrogen to produce residual silica and silicon nitride, fabricating the resulting material into the desired shape and heating in a nitrogen atmopshere at a temperature of from 1400° C. to 2000° C. with or without pressure to form the product. The silica may conveniently be derived from pyrolysed rice hulls. The product may also comprise silicon carbide, which may be derived from the carbothermal reduction, and a glassy phase.

Claims

1. A method of forming a ceramic product by converting silica to silicon nitride in a carbothermal reduction process in the presence of nitrogen, fabricating the silicon nitride into the desired shape of the ceramic product and sintering the fabricated silicon nitride, characterised in that the carbothermal reduction process is partially completed so as to produce a mixture comprising residual silica and silicon nitride which is fabricated into the desired shape and is heated in a densification step in a nitrogen atmosphere at a temperature of from 1400°

C. to 2000°

C. to produce a ceramic product comprised of silicon nitride and silicon oxynitride.

2. A method according to claim 1 wherein the carbothermal reduction process also produces silicon carbide and up to about 40% silicon carbide is present in the ceramic product.

3. A method according to claim 1 wherein following the carbothermal reduction process the particulate material is heated to remove residual carbon.

4. A method according to claim 1 wherein at least part of the silicon nitride and/or silicon oxynitride is present in the form of one or more aluminium substituted derivatives.

5. A method according to claim 4 wherein aluminium is added before or after the carbothermal reduction process.

6. A method according to claim 4 wherein aluminium is present in the silica source material.

7. A method according to claim 6 wherein the silica source material comprises rice hulls which are pyrolysed prior to the carbothermal reduction process.

8. A method according to claim 1 wherein the densification step is performed in the presence of a sintering aid selected from the metal, oxide, nitrate, carbonate or nitride form of one or more of the following group of elements:

lithium, beryllium, magnesium, calcium, scandium, yttrium, cerium, titanium, zirconium, hafnium and members of the rare earth group.

9. A method according to claim 1 wherein the densification step is performed using external pressure.

10. A method according to claim 1 wherein whiskers are formed during the carbothermal reduction.