Method of preparing silicon compositions

• US 4,987,169 A
• Filed: 04/21/1989
• Issued: 01/22/1991
• Est. Priority Date: 04/22/1988
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Mori, Shigeru, Sakuta, Koji, Kuwata, Satoshi
• Primary Examiner(s): Marquis, Melvyn I.
• Application Number:
  US07/341,744
• Time in Patent Office: 641 Days
• Field of Search: 524/267, 524/731
• US Class Current: 524/267
• CPC Class Codes: A61K 47/34 Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polyesters, polyamino acids, polysiloxanes, polyphosphazines, copolymers of polyalkylene glycol or poloxamers A61K47/10 takes precedence
• CPC Class Codes: A61K 8/891 saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
• CPC Class Codes: A61Q 19/00 Preparations for care of the skin
• CPC Class Codes: C08G 77/12 containing silicon bound to hydrogen C08G77/045 takes precedence
• CPC Class Codes: C08G 77/20 containing silicon bound to unsaturated aliphatic groups C08G77/045 takes precedence
• CPC Class Codes: C08G 77/70 Siloxanes defined by use of the MDTQ nomenclature
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/04 Polysiloxanes
• CPC Class Codes: C10M 119/30 containing atoms of elements not provided for in groups C10M119/02 - C10M119/28
• CPC Class Codes: C10M 2229/006 used as thickening agents
• CPC Class Codes: C10N 2040/50 Medical uses
• CPC Class Codes: C10N 2050/10 Semi-solids; greasy

Abstract

A method of preparing a uniform silicone composition, comprising treating under the application of a shearing force a polymeric product obtained by addition polymerization of (A) an organhydrogenpolysiloxane containing in its molecule from 1.5 to 5 silicon-bonded hydrogen atoms on average, said silicon-bonded hydrogen atoms being in an amount of from 1 to 20 mol %, based on the total of the silicon-bonded hydrogen atoms and silicon-bonded organic groups in the molecule; and (B) an organopolysiloxane containing in its molecule from 1.5 to 5 silicon-bonded aliphatic unsaturated groups on average; in the presence of from 10 to 1,000 parts by weight of low-viscosity silicone oil having a viscosity of not more than 100 cSt at 25° C. based on 100 parts by weight of the total amount of said (A) and (B).

Claims

1. A method of preparing a uniform silicone composition, comprising treating under the application of a shearing force a polymeric product obtained by addition polymerization of (A) on organohydrogenpolysiloxane containing in its molecule from 1.5 to 5 silicon-bonded hydrogen atoms on average, said silicon-bonded hydrogen atoms being in an amount of from 1 to 20 mol %, based on the total of the silicon-bonded hydrogen atoms and silicon-bonded organic groups in the molecule;

and (B) an organopolysiloxane containing in its molecule from 1.5 to 5 silicon-bonded aliphatic unsaturated groups on average;

in the presence of from 10 to 1,000 parts by weight of low-viscosity silicone oil having a viscosity of not more than 100 cSt at 25°

C. based on 100 parts by weight of the total amount of said (A) and (B).

2. The method according to claim 1, wherein said polymeric product is treated under said application of shearing force, together with from 10 to 1,000 parts by weight of the same low-viscosity silicone oil as the above (C), and said silicone composition is obtained in the form of paste.

3. The method according to claim 1, wherein said addition polymerization is carried out with stirring, in the presence of from 10 to 200 parts by weight of said component (C) low-viscosity silicone oil, and said silicone composition is obtained in the form of powder.

4. The method according to claim 1, wherein said organohydrogenpolysiloxane (A) has the formula.

5. The method according to claim 1, wherein said organopolysiloxane (B) has the formula:

space="preserve" listing-type="equation">[(CH.sub.2 ═

CH)(CH.sub.3).sub.2 SiO.sub.0.5 ].sub.e [(CH.sub.3).sub.3 SiO.sub.0.5 ].sub.f

space="preserve" listing-type="equation">[(CH.sub.3).sub.2 SiO].sub.g [(CH.sub.2 ═

CH)CH.sub.3 SiO].sub.h

wherein, e and f are each an integer of from 0 to 2, provided that e+f=2, g is an integer from 0 to 500 and h is an integer of from 0 to 50.

6. The method according to claim 1, wherein said low-viscosity silicone oil has a viscosity of not more than 50 cSt at 25°

C.

7. The method according to claim 1, wherein said low-viscosity silicone oil has a viscosity of not more than 10 cSt at 25°

C.

8. The method according to claim 1, wherein said organohydrogenpolysiloxane (A) is in the form of a mixture of compounds.

9. The method according to claim 1, wherein said organopolysiloxane (B) is in the form of a mixture of compounds.

10. The method according to claim 1, wherein a molar ratio of silicon-bonded hydrogen atoms of (A) to the silicon-bonded aliphatic unsaturated groups of (B) is from 1/3 to 3/1.

11. The method according to claim 1, wherein said low-viscosity silicone oil is a siloxane having a low degree of polymerization selected from the group of methylpolysiloxane, dimethylpolysiloxane, methylphenylpolysiloxane, ethylpolysiloxane, ethylmethylpolysiloxane, ethylphenylpolysiloxane, octamethylcyclotetrasiloxane and decamethylcyclopentasiloxane and mixtures thereof.

12. The method according to claim 1, which further comprises effecting said reaction in the presence of a platinum compound or a rhodium compound, as a catalyst, in a solvent.

13. The method according to claim 1, wherein said compound (A) is selected from the group consisting of trimethylsilyl-terminated dimethylmethylhydrogenpolysiloxane, dimethylhydrogensilyl-terminated dimethylpolysiloxane and trimethylsilyl-terminated dimethylmethylhydrogenpolysiloxane.

14. The method according to claim 1, wherein said compound (B) is selected from the group consisting of dimethylvinylsilyl-terminated dimethylpolysiloxane and trimethylsilyl-terminated dimethylmethylvinylpolysiloxane.

15. The method according to claim 1, wherein said low-viscosity silicone oil is selected from the group consisting of phenyltris(trimethylsiloxy) silane and octamethyltrisiloxane.

16. The method according to claim 1, wherein said catalyst is chloroplatinate.