Cryogenic distillation with unbalanced heat pump

• US 4,987,744 A
• Filed: 01/26/1990
• Issued: 01/29/1991
• Est. Priority Date: 01/26/1990
• Status: Expired due to Fees

• Current Assignee: Praxair Technology Incorporated (Linde Plc)
• Original Assignee: Union Carbide Industrial Gases Technology Corporation
• Inventors: Handley, James R., Pahade, Ravindra F.
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US07/470,715
• Time in Patent Office: 368 Days
• Field of Search: 62/9, 62/11, 62/24, 62/40
• US Class Current: 62/623
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/40 Features relating to the provision of boil-up in the bottom of a column
• CPC Class Codes: F25J 2200/50 using multiple (re-)boiler-condensers at different heights of the column
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2215/04 Recovery of liquid products
• CPC Class Codes: F25J 2220/82 Separating low boiling, i.e. more volatile components, e.g. He, H2, CO, Air gases, CH4
• CPC Class Codes: F25J 2270/02 Internal refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/12 External refrigeration with liquid vaporising loop
• CPC Class Codes: F25J 2270/60 Closed external refrigeration cycle with single component refrigerant [SCR], e.g. C1-, C2- or C3-hydrocarbons
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0266 separation of carbon dioxide production of carbon dioxide in general C01B32/00
• CPC Class Codes: F25J 3/04278 using external refrigeration units, e.g. closed mechanical or regenerative refrigeration units
• CPC Class Codes: F25J 3/044 using a single pressure main column system only F25J3/0446, F25J3/04624, F25J3/04636 take precedence
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

A cryogenic distillation system wherein a first heat exchange fluid transfers heat in part from a process stream to the bottom of a column, and in part from a process stream to a second heat exchange fluid and out of the system, thus generating net refrigeration.

Claims

1. A method for separating a multicomponent feed by cryogenic distillation comprising:

(A) providing feed having lighter and heavier components into a distillation column;

(B) separating the feed by cryogenic distillation in the column into a top vapor enriched in lighter components(s) and into a bottom liquid enriched in heavier component(s);

(C) heating a first heat exchange fluid by indirect heat exchange with a cooling process stream;

(D) warming the bottom liquid by indirect heat exchange with a first portion of the heated first heat exchange fluid;

(E) warming a second heat exchange fluid having a vapor pressure less than that of the first heat exchange fluid by indirect heat exchange with a second portion of the heated first heat exchange fluid;

(F) passing the cooled first and second portions resulting from steps (D) and (E) in indirect heat exchange with said process stream to carry out the heat exchange of step (C); and

(G) cooling the second heat exchange fluid and passing the resulting cooled second heat exchange fluid in indirect heat exchange with the said second portion to carry out the heat exchange of step (E).

2. The method of claim 1 wherein the said cooling process stream is top vapor.

3. The method of claim 2 wherein the cooling top vapor is partially condensed, resulting liquid is passed down the column as reflux, and resulting vapor is removed.

4. The method of claim 1 wherein the said cooling process stream is feed.

5. The method of claim 4 wherein a feed stream is divided in vapor and liquid streams and the resulting vapor feed serves as the cooling process stream.

6. The method of claim 4 wherein the cooling feed is partially condensed.

7. The method of claim 1 wherein the warming bottom liquid is partially vaporized, resulting vapor is passed up the column as boilup, and resulting liquid is removed.

8. The method of claim 1 wherein the feed comprises methane as a lighter component and carbon dioxide as a heavier component.

9. The method of claim 1 wherein the first heat exchange fluid comprises ethane and the second heat exchange fluid comprises propane.

10. The method of claim 1 wherein the first portion comprises from 25 to 90 percent, and the second portion comprises from 10 to 75 percent, of the heated first heat exchange fluid.

11. The method of claim 1 wherein the second heat exchange fluid in cooled by heat exchange with air.

12. The method of claim 1 wherein the second heat exchange fluid is cooled by heat exchange with water.

13. The method of claim 1 wherein the cooled first and second portions are combined and are passed together in indirect heat exchange with the cooling process stream.

14. The method of claim 1 wherein the second heat exchange fluid is compressed prior to the cooling of step (G) and expanded prior to the warming of step (E).

15. The method of claim 1 wherein in step (C) the first heat exchange fluid is vaporized by the heat exchange with the process stream.

16. The method of claim 1 wherein in step (D) the first portion of the first heat exchange fluid is condensed by the heat exchange with the bottom liquid.

17. The method of claim 1 wherein in step (E) the second portion of the first heat exchange fluid is condensed by the heat exchange with the second heat exchange fluid.

18. The method of claim 1 wherein after step (C) but prior to steps (D) and (E) the first heat exchange fluid is compressed.

19. The method of claim 18 wherein the first heat exchange fluid is cooled after the compression.

20. The method of claim 1 wherein the second heat exchange fluid is condensed by the cooling of step (G).

21. The method of claim 1 wherein the feed is taken from an oil or gas reservoir.