Method for making a composite

• US 4,988,480 A
• Filed: 08/23/1990
• Issued: 01/29/1991
• Est. Priority Date: 12/20/1988
• Status: Expired due to Fees

• Current Assignee: Institut Strukturnoi Makrokinetiki Akademii NAUK SSSR
• Original Assignee: Institut Strukturnoi Makrokinetiki Akademii NAUK SSSR
• Inventors: Ratnikov, Viktor I., Epishin, Konstantin L., Kvanin, Vadim L., Pitjulin, Alexandr N., Borovinskaya, Inna P., Merzhanov, Alexandr G.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Application Number:
  US07/566,358
• Time in Patent Office: 159 Days
• Field of Search: 419/11, 419/12, 419/13, 419/17, 419/19, 419/25, 419/28, 419/45, 419/54, 419/55
• US Class Current: 419/11
• CPC Class Codes: C04B 35/645 Pressure sintering
• CPC Class Codes: C04B 35/651 Thermite type sintering, e.g. combustion sintering
• CPC Class Codes: C22C 1/058 by reaction sintering (i.e. gasless reaction starting from a mixture of solid metal compounds)

Abstract

The proposed invention is used for the manufacture from the obtained composite of cutting tools, hard alloy tooling, dies and other products. A method according to the invention involves preparing a mixture, compacting it, placing the mixture into a synthesis zone, igniting the mixture, with subsequent reaction of components of the mixture under combustion conditions. Then cure is carried out during a period ranging from about 0.1 seconds to about 0.5 hours, and the hot combustion products are compacted under pressure at an average pressure rise rate ranging from about 10 to about 2000 kgf/cm².s, with subsequent cure of the compacted product under isobaric conditions to complete homogenization of the composite, with subsequent cooling thereof to obtain an end composite.

Claims

1. A method for making a composite, comprising blending a mixture containing at least one metallic element of groups III-VI, VIII of the periodic table of the chemical elements and at least one compound of at least one of the elements of said groups taken individually or in combination, at least one nonmetallic element of groups III-VI of the periodic table of the chemical elements and at least one compound of at least one of the elements of said groups taken individually or in combination, and a binder component, compacting the mixture, placing the mixture into a synthesis zone, igniting the mixture with subsequent reaction of the components of the mixture under combustion conditions, and compacting the hot combustion products to obtain an end composite, characterized in that after ignition the mixture is cured till compaction of hot products during a period ranging from about 0.1 seconds to about 0.5 hours, and compacting the hot combustion products is carried out under pressure at an average rate of pressure rise ranging from about 10 to about 2000 kgf/cm² ·

s, with subsequent cure of the compacted product under isobaric conditions to complete homogenization of the composite and subsequent cooling.

2. A method as claimed in claim 1, characterized in that the composite is heat treated after homogenization and before cooling.

3. A method as claimed in claim 1, characterized in that the composite is heat treated after cooling.

4. A method as claimed in claims 2 or 3, characterized in that cooling of said composite is carried out at an average rate ranging from about 10 to about 5000 deg./h.

5. A method as claimed in claim 1, characterized in that at least at the moment of ignition of mixture and during the initial stage of cure before compaction of the combustion products a pressure ranging from about 10 to about 1000 kgf/cm² is built up.

6. A method as claimed in claim 5, characterized in that said pressure is maintained during the entire cure period before compaction of said combustion products.

7. A method as claimed in claim 1, characterized in that the mixture is heated using an external energy supply to a temperature ranging from about 100°

to about 1200°

C. before ignition of said mixture.

8. A method as claimed in claim 1, characterized in that the mixture is placed into a heat insulating porous envelope after the compaction of the mixture.

9. A method as claimed in claim 8, characterized in that the heat insulating envelope has an open porosity, the volume of the open porosity being about 60% and less of the volume of the heat insulating envelope.

10. A method as claimed in claim 1 or 9, characterized in that the synthesis zone is evacuated to a residual pressure of about 10^-1 mmHg and below before said ignition of said mixture.

11. A method as claimed in claim 1, characterized in that compaction of said mixture is carried out to a relative density ranging from about 20% to about 90%.

12. A method as claimed in claim 11, characterized in that the mixture is molded during compaction of the mixture.

13. A method as claimed in claim 1, characterized in that the cure before compaction of the hot combustion products, the compaction of the hot combustion products and the cure of the compacted product under isobaric conditions are carried out in an ultrasonic field.

14. A method as claimed in claim 1, characterized in that the ignition of the mixture is carried out by means of ultrasonic oscillations.

15. A method as claimed in claim 1, characterized in that a perforated layer of a heat resistant material is placed on the surface of the mixture in the synthesis zone and an ignition composition having a combustion rate which is at least equal to that of the mixture is placed on this layer, the ignition of the mixture being carried out by means of the ignition composition.

16. A method as claimed in claim 1, characterized in that gas removal passages are formed in the mixture before the ignition, the volume of the passages being about 60% and less of the volume of the mixture.

17. A method as claimed in claim 1, characterized in that the metallic element is in the form of wastes of a metal of groups III-VI, VIII of the periodic table of the chemical elements and/or an alloy thereof.

18. A method as claimed in claim 1, characterized in that the nonmetallic element is in the form of a production waste of a nonmetallic element of groups III-VI of the periodic table of the chemical elements.

19. A method as claimed in claim 1, characterized in that the binder component is in the form of a production waste of a binder component.