Fluorosilicone rubber composition

• US 4,988,758 A
• Filed: 07/21/1988
• Issued: 01/29/1991
• Est. Priority Date: 01/20/1986
• Status: Expired due to Term

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Fujiki, Hironao, Fukuda, Takeshi, Fukushima, Motoo, Itoh, Kunio
• Primary Examiner(s): Jacobs, Lewis T.
• Application Number:
  US07/222,212
• Time in Patent Office: 922 Days
• Field of Search: 528/24, 528/15, 524/588, 524/866, 524/492
• US Class Current: 524/492
• CPC Class Codes: C08G 77/24 halogen-containing groups
• CPC Class Codes: C08K 5/14 Peroxides
• CPC Class Codes: C08L 83/00 Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
• CPC Class Codes: C08L 83/08 containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen

Abstract

The fluorine-substituted organopolysiloxane as the principal ingredient of the inventive silicone rubber composition has vinyl groups to serve as the cross-linking points at the molecular chain terminals while at least the penultimate siloxane unit or the silicon atom adjacent to the terminal silicon atom has no fluorine-substituted hydrocarbon group bonded to the silicon atom. Being freed from the steric hindrance due to the bulky fluorine-substituted hydrocarbon group bonded to the adjacent silicon atom, the vinyl group bonded to the terminal silicon atom can pertain to the cross-linking reaction much easier than otherwise so that the silicone rubber composition of the invention containing an organic peroxide or a combination of an organohydrogenpolysiloxane and a platinum catalyst as a curing agent can be rapidly cured to give a cured silicone rubber article having excellent resistance against oils and organic solvents as well as mechanical properties.

Claims

1. A curable fluorine-substituted organopolysiloxane composition which comprises, in mixture

(A) a polyorganosiloxane having a viscosity of at least 400 centipoise at 25°

C. and a molecular structure represented by the general formula

space="preserve" listing-type="equation">.sup.1 --O--(--SiR.sub.2 --O--).sub.n --(--SiRR.sub.f --O--).sub.m --X.sup.2,

or

space="preserve" listing-type="equation">[X.sup.1 --O--(--SiR.sub.2 i--O--).sub.n --(--SiRR.sub.f --O--).sub.m --].sub.p SiR.sub.4-p,

in which R is a monovalent hydrocarbon group selected from the class consisting of methyl, vinyl and phenyl groups, R_f is a fluorinated alkyl group having 3 to 10 carbon atoms, n is zero or a positive integer, m is a positive integer with the proviso that n;

(m+n) is in the range from 0.005 to 1, p is 2, 3 or 4, X¹ is a vinyl dimethyl siloxy-substituted silyl group represented by the general formula

space="preserve" listing-type="equation">Vi-SiMe.sub.2 --(--O--SiMe.sub.2 --).sub.r --,

in which Vi is a vinyl group, Me is a methyl group and r is a positive integer in the range from 1 to 30, and X² is a hydrogen atom or X¹ ; and

(B) an organic peroxide curing agent in an amount sufficient to cure the component (A).

2. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 which further comprises (C) a finely divided silica filler having a specific surface area of at least 50 m² /g in an amount up to 100 parts by weight per 100 parts by weight of the component (A).

3. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the amount of the organic peroxide as the curing agent is in the range from 0.1 to 10 parts by weight per 100 parts by weight of the component (A).

4. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the group denoted by the symbol R_f is a 3,3,3-trifluoropropyl group.

5. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the group denoted by the symbol R_f is a 2-(perfluorobutyl)ethyl group.

6. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein the group denoted by the symbol R_f is a 2-(perfluorooctyl)ethyl group.

7. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein X² is X¹.

8. The curable fluorine-substituted organopolysiloxane composition as claimed in claim 1 wherein X² is a hydrogen atom.