Removal of undesirable material from water-soluble polysaccharide ethers

• US 4,988,807 A
• Filed: 04/09/1990
• Issued: 01/29/1991
• Est. Priority Date: 01/23/1989
• Status: Expired due to Fees

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Kling, Susan, Christensen, Stephen B., Schulz, Gary J.
• Primary Examiner(s): CINTINS, IVARS C
• Application Number:
  US07/506,724
• Time in Patent Office: 295 Days
• Field of Search: 210/683, 210/686, 210/692, 210/917, 536/85, 536/91, 536/95, 536/96, 536/99, 536/100, 536/127
• US Class Current: 536/127
• CPC Class Codes: A61K 9/2866 Cellulose; Cellulose derivatives, e.g. hydroxypropyl methylcellulose
• CPC Class Codes: C08B 11/20 Post-etherification treatments of chemical or physical type, e.g. mixed etherification in two steps, including purification
• CPC Class Codes: C08B 37/0003 General processes for their isolation or fractionation, e.g. purification or extraction from biomass
• CPC Class Codes: Y10S 210/917 Color

Abstract

A method of removing undesirable material from water-soluble polysaccharide ethers, such as water-soluble cellulose ethers, via contact of an aqueous solution of the water-soluble polysaccharide ether with an anion exchange resin. Anion exchange resins that are useful in the invention are derived from epoxy resin polymers, acrylic based copolymers or a copolymer of styrene-divinylbenzene. The method significantly reduces the amount of colored bodies in the polysaccharide ether.

Claims

1. A method of removing color bodies from a water-soluble polysaccharide ether containing such color bodies comprising:

(a) contacting an aqueous solution which comprises a water-soluble polysaccharide ether containing color bodies, with an anion exchange resin in an amount and at conditions effective to associate the color bodies with the resin; and

(b) separating the resin from the polysaccharide ether so as to result in the polysaccharide ether having a reduced concentration of color bodies;

wherein the water-soluble polysaccharide ether is in the aqueous solution in a concentration greater than about 1 weight percent.

2. The method of claim 1 wherein the anion exchange resin is derived from the group consisting of an epoxy resin polymer, an acrylic based copolymer, and a copolymer composition of styrene-divinylbenzene.

3. The method in claim 2 wherein the epoxy resin polymer is an epoxy-amine copolymer.

4. The method in claim 2 wherein the acrylic based copolymer is an acrylic-divinylbenzene copolymer.

5. The method in claim 1 wherein the anion exchange resin is a weak-base resin.

6. The method in claim 1 wherein the anion exchange resin is a strong-base resin.

7. The method in claim 1 wherein the anion exchange resin is a macroporous resin.

8. The method in claim 1 wherein the anion exchange resin is a gel-type resin.

9. The method in claim 1 wherein the resin is a mixed bed of resins comprising a strong-base styrene-divinylbenzene gel-type resin and a strong-acid cation exchange styrene-divinylbenzene resin.

10. The method in claim 1 wherein the resin is an absorptive, porous, post-crosslinked resin.

11. The method in claim 1 wherein the water-soluble polysaccharide ether is derived from a natural gum.

12. The method in claim 11 wherein the natural gum is selected from the group consisting of arabic, xanthan and guar.

13. The method in claim 1 wherein the water-soluble polysaccharide ether is derived from a dextran.

14. The method in claim 1 wherein the water-soluble polysaccharide ether is derived from a starch.

15. The method of claim 1 wherein the water-soluble polysaccharide ether is a water-soluble cellulose ether.

16. The method of claim 15 wherein the water-soluble cellulose ether is selected from the group consisting of alkylcellulose, hydroxyalkyl alkylcellulose, methylcellulose, hydroxypropyl methylcellulose, hydroxyethyl methylcellulose, ethyl methylcellulose, hydroxyethyl hydroxypropyl methylcellulose, hydroxyethylcellulose, and hydroxypropylcellulose.

17. The method of claim 1 wherein the polysaccharide ether is present in the aqueous solution in a concentration greater than about 5 weight percent.