Oxygen sensor

• US 4,990,235 A
• Filed: 02/09/1990
• Issued: 02/05/1991
• Est. Priority Date: 02/23/1989
• Status: Expired due to Term

• Current Assignee: Toyota Jidosha Kabushiki Kaisha (Toyota Motor Corporation)
• Original Assignee: Toyota Jidosha Kabushiki Kabushiki Kaisha
• Inventors: Chujo, Yoshiki
• Primary Examiner(s): Tung, T.
• Application Number:
  US07/477,734
• Time in Patent Office: 361 Days
• Field of Search: 204/153.18, 204/421-429
• US Class Current: 204/424
• CPC Class Codes: G01N 27/4065 Circuit arrangements specially adapted therefor
• CPC Class Codes: G01N 27/4072 characterized by the diffusion barrier

Abstract

An oxygen sensor having a body formed of a solid electrolyte material on which electrodes are provided, and a diffusion chamber formed on one side of the body. The diffusion chamber is connected to the space in which the gas to be detected exists, i.e., the interior of the intake or exhaust pipe of an internal combustion engine. A plate is mounted on the body in which a pin-hole is formed for controlling the speed of diffusion of oxygen ions so that the concentration of oxygen ions in the diffusion chamber is equal to that in the detection space. A pore of pores is provided in a plate member forming the diffusion chamber, to enable a rapid equalization of the pressures of the detection space and diffusion chamber while maintaining a control of the diffusion of oxygen ions via the pin-hole.

Claims

1. An oxygen sensor for detecting oxygen density of an oxygen-containing gas in a region of pulsating pressure, said oxygen sensor comprising:

a body formed of a solid electrolyte material that is capable of conducting oxygen ions;

a wall enclosing a portion of the surface of the solid electrolyte body, the wall and the solid electrolyte body forming a hollow structure, the interior of which forms a diffusion chamber; and

a plurality of electrodes mounted on the structure, the electrodes being adapted to be connected to a voltage source to provide a sensor cell and a pumping cell, wherein

the structure, when placed in said region of pulsating pressure, is permeable to gas molecules only through at least one pin-hole opening formed in the structure and through a porous portion of the structure not including the pin-hole opening,

the total flow area of the at least one pin-hole opening is selected to be small enough to control the rate of diffusion of oxygen molecules from the region of pulsating pressure into the diffusion chamber, and the flow area of each pin-hole opening is selected to be large enough to control the diffusion rate primarily by causing multiple collisions between the gas molecules passing through the pin-hole rather than primarily by multiple collisions between the gas molecules and the inner surface of the pin-hole opening, and

the size of each pore in the porous portion is much smaller than the size of the pin-hole and the total pore area of all the pores in the porous portion is substantially smaller than the flow area of the pin-hole opening but is sufficient to permit pulsative changes in the pulsating pressure region to be transmitted to the diffusion chamber.

2. An oxygen sensor according to claim 1 wherein the porous portion of the structure comprises a plate member formed of a porous material having a predetermined air permeability per unit area.

3. An oxygen sensor according to claim 2 wherein the pin-hole opening is formed in the porous plate member.

4. An oxygen sensor according to claim 2 wherein the total pore area of all the pores in the porous plate member is on the order of 0.01% of the total flow area of the at least one pin-hole opening.

5. An oxygen sensor according to claim 4 wherein the diameter of each pin-hole opening is between about 0.1 mm and about 0.8 mm.

6. An oxygen sensor according to claim 1 wherein said plurality of electrodes comprises two pairs of electrodes, one of the pairs of electrodes serving as the sensor cell and the other of the pairs serving as the pumping cell.

7. An oxygen sensor according to claim 6 wherein both pairs of the electrodes are mounted on the solid electrolyte body.

8. An oxygen sensor according to claim 6 wherein the one pair of electrodes is mounted on the solid electrolyte body and the other pair of electrodes is mounted on the wall.

9. An oxygen sensor according to claim 1 wherein said plurality of electrodes comprises a single pair of electrodes mounted on the solid electrolyte body and serving as both the sensor cell and the pumping cell.