Antiwear, antioxidant and friction reducing additive for lubricating oils

• US 4,990,271 A
• Filed: 09/07/1989
• Issued: 02/05/1991
• Est. Priority Date: 09/07/1989
• Status: Expired due to Fees

• Current Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Original Assignee: Exxon Research and Engineering Company (Exxon Mobil Corporation)
• Inventors: Francis, James N.
• Primary Examiner(s): Howard, Jacqueline V.
• Application Number:
  US07/404,142
• Time in Patent Office: 516 Days
• Field of Search: 252/49.7, 252/46.4, 252/46.3
• US Class Current: 508/445
• CPC Class Codes: C07F 11/005 compounds without a metal-carbon linkage
• CPC Class Codes: C10M 135/14 having a carbon-to-sulfur double bond
• CPC Class Codes: C10M 159/18 Complexes with metals
• CPC Class Codes: C10M 2219/062 having carbon-to-sulfur double bonds
• CPC Class Codes: C10M 2223/045 Metal containing thio derivatives
• CPC Class Codes: C10N 2010/04 Groups 2 or 12
• CPC Class Codes: C10N 2010/12 Groups 6 or 16
• CPC Class Codes: C10N 2040/25 Internal-combustion engines
• CPC Class Codes: C10N 2040/251 Alcohol-fuelled engines
• CPC Class Codes: C10N 2040/255 Gasoline engines
• CPC Class Codes: C10N 2040/28 Rotary engines

Abstract

A lubricating oil composition is provided which comprises a major amount of an oil of lubricating viscosity and a minor amount of an additive formed by contacting molybdenum hexacarboxyl with dixanthogens of the formula (ROCS₂)₂ wherein the R is an organo group having a sufficient number of carbon atoms to render the additive formed soluble in the oil. In general, R is the same or different alkyl, aralkyl, and alkoxylalkyl groups having from about 2 to about 20 carbon atoms and preferably R is an alkyl group having from about 4 to about 12 carbon atoms.

Claims

1. A lubricating oil composition comprising:

an oil of lubricating viscosity and an additive formed by contacting molybdenum hexacarbonyl with a dixanthogen of the formula (ROCS₂)₂ for a time sufficient to form the additive, wherein R is an organo group having a sufficient number of carbon atoms to render the additive soluble in the oil.

2. The composition of claim 1 wherein R is selected from alkyl, aralkyl and alkoxylalkyl groups having from about 2 to about 20 carbon atoms.

3. The composition of claim 2 wherein R is an alkyl group of from about 4 to 12 carbon atoms.

4. The composition of claim 1 wherein the contacting is conducted at temperatures of from ambient temperatures to about 140°

C.

5. The composition of claim 4 wherein the contacting is conducted at temperatures of about 80°

C. to about 120°

for about 2 hours to about 10 hours.

6. The composition of claim 5 wherein the mole ratio of dixanthogen to molybdenum hexacarbonyl is in the range of from about 1.5:

1 to about 2;

1.

7. The composition of claim 6 wherein the additive is present in an amount ranging from about 0.01 to about 2.0 weight percent based on the weight of the oil.

8. The composition of claim 7 wherein the amount is in the range of from 0.1 to 1.0 weight percent.

9. A lubricating composition comprising:

an oil of lubricating viscosity; and

an additive having the formula Mo₄ S₄ (S₂ C--OR)₆ wherein R is selected from organo groups having sufficient number of carbon atoms to render the additive soluble in oil.

10. The lubricating composition of claim 9 wherein R is selected from alkyl, aralkyl and alkoxylalkyl groups having from about 2 to about 20 carbon atoms.

11. The lubricating composition of claim 10 wherein the amount of the additive is in the range of from about 0.01 to about 2.0 weight percent based on the weight of oil.

12. A lubricating oil composition comprising:

a major amount of an oil selected from natural and synthetic oils having lubricating viscosities; and

, from about 0.01 to about 2.0 weight percent of an additive formed by reacting a dixanthogen and Mo(CO)₆ in the mole ratio of from about 1.5;

1 to about 2;

1 at temperatures of from about 80°

C. to about 120°

C. for from about 2 hours to about 10 hours, the dixanthogen having the formula (ROCS₂)₂ wherein R is selected from alkyl, aralkyl and alkoxylalkyl groups having from about 2 to about 20 carbon atoms.

13. The composition of claim 12 wherein R is an alkyl group of from about 4 to 12 carbon atoms.

14. An additive concentrate for blending with lubricating oils to provide lubricating composition having improved wear, friction, and oxidation properties comprising:

a hydrocarbon diluent and from about 1 to about 90 weight percent of a compound formed by reacting a dixanthogen and Mo(CO)₆ in the mole ratio of from about 1.5;

1 to about 2;

1 at temperatures of from about ambient temperature to about 140°

C. for from about 2 hours to about 10 hours, the dixanthogen having the formula (ROCS₂)₂ wherein R is selected from alkyl, aralkyl and alkoxylalkyl groups having from about 2 to about 20 carbon atoms.

15. The concentrate of claim 14 wherein the hydrocarbon diluent is selected from hydrocarbons in which the additive is soluble.

16. The concentrate of claim 15 wherein the compound formed by reacting a dixanthogen and Mo(CO)₆ is present in from about 30 to about 60 weight percent.

17. A method of preparing a lubricating oil additive comprising:

contacting a dixanthogen and Mo(CO)₆ in the mole ratio of from about 1.5;

1 to about 2;

1 at temperatures of from about ambient temperature to about 140°

C. for from about 2 hours to about 10 hours, the dixanthogen having the formula (ROCS₂)₂ wherein R is selected from alkyl, aralkyl and alkoxylalkyl groups having from about 2 to about 20 carbon atoms.

18. The method of claim 17 wherein the temperature ranges from about 80°

C. to about 120°

C.

19. The method of claim 18 wherein the contacting is conducted in the presence of an aromatic hydrocarbon.

20. The method of claim 19 wherein the hydrocarbon is toluene.