Electrical superconducting ceramic fiber devices

• US 4,990,490 A
• Filed: 06/03/1988
• Issued: 02/05/1991
• Est. Priority Date: 06/03/1988
• Status: Expired due to Fees

• Current Assignee: ISCO International Inc.
• Original Assignee: CPS Superconductor Corp. (CPS Technologies Corp.)
• Inventors: Halloran, John W., Pathare, Viren M.
• Primary Examiner(s): Ramsey, Kenneth J.
• Application Number:
  US07/202,964
• Time in Patent Office: 977 Days
• Field of Search: 29/599, 228/179, 228/243, 228/190, 264/61, 264/62, 264/63, 264/174, 264/60, 427/62, 419/36, 419/37, 505/1, 505/705, 505/887, 505/927, 174/125.1, 428/389, 428/614, 428/632, 428/930, 106/1.18, 106/1.19
• US Class Current: 505/431
• CPC Class Codes: H10N 60/0801 Manufacture or treatment of filaments or composite wires
• CPC Class Codes: H10N 60/203 comprising high-Tc ceramic materials
• CPC Class Codes: Y10S 505/887 Conductor structure
• CPC Class Codes: Y10S 505/927 Metallurgically bonding superconductive members
• CPC Class Codes: Y10T 29/49014 Superconductor

Abstract

A coating composition for ceramic fibers is provided which includes metal particles and a vehicle. The coating can be applied to a green ceramic or a sintered ceramic, and is co-sintered or sintered therewith. Such coatings are useful for coating high temperature superconducting ceramic fibers and can be co-sintered therewith. The coated superconducting fibers, in which case the coating is porous to allow for annealing to adjust the oxygen stoichiometry, can then be sandwiched between metal cladding layers to provide a multifilamentary electrical conductor including superconducting active components. The coating is useful for such conductors because it compatibilizes the ceramic fiber with metal components, such as a solder, as well as protecting the ceramic from possibly degrading reactions. The compositions are also generally advantageous in compatibilizing ceramic fibers with a metal matrix.

Claims

1. A process for producing an electrical conductor, comprising the steps of:

(i) providing at least one sintered superconducting ceramic fiber having a metallization coating sintered thereon;

(ii) providing at least one composite sheet having a cladding metal outer layer and a conductive adherent inner layer;

(III) manipulating at least one composite sheet to provide generally opposing inner layers of the adherent;

(iv) feeding at least one eramic fiber between the opposing layers; and

(v) sandwiching the fed fiber(s) between the opposing layers to form an electrical conductor.

2. The process as defined by claim 1, wherein said step (i) comprises the steps of:

(a) providing a green superconducting ceramic fiber;

(b) coating the green fiber with a metallization coating;

(c) sintering the green fiber to provide a ceramic fiber having metallization thereon; and

(d) annealing the sintered fiber in an oxygen-containing environment to adjust the stoichiometry and provide a superconducting ceramic fiber.

3. The process as defined by claim 1, wherein the ceramic is selected from the group consisting of LM₂ Cu₃ O_7-x, (L_1-x M_x)₂ CuO₄, Mpb_1-x Bi_x O₃, La₂ CuO₄, Bi₂ M₃ Cu₂ O₈, M₂ YCu₃ O₇, Tl₂ M₄ Cu₃ O₁₀, and mixtures thereof, wherein 0<

x<

0.1, L is an element having an atomic number of 57 to 71 or mixtures thereof, and M is Ba, Sr, Ca, or mixtures thereof.

4. The process as defined by claim 1, wherein the metallization includes a metal selected from the group consisting of silver, gold, platinum, palladium, and mixtures and alloys thereof sinterable at the sintering temperatures of the ceramic.

5. The process as defined by claim 1, wherein the conductive adherent is a solder of a braze metal alloy.

6. The process as defined by claim 1, wherein the cladding is selected from the group consisting of copper, aluminum, silver, gold, alloys of each, and mixtures of each.