Process for purifying crude glycerol

• US 4,990,695 A
• Filed: 08/09/1989
• Issued: 02/05/1991
• Est. Priority Date: 08/09/1988
• Status: Expired due to Fees

• Current Assignee: Unichema Chemie BV
• Original Assignee: Unilever Patent Holdings BV (Unilever PLC)
• Inventors: Rampi, Aldo, Gamba, Pietro, Buenemann, Thomas, Oudejans, Johannes C.
• Primary Examiner(s): Evans, J. E.
• Application Number:
  US07/391,280
• Time in Patent Office: 545 Days
• Field of Search: 568/869
• US Class Current: 568/869
• CPC Class Codes: C07C 29/76 by physical treatment
• CPC Class Codes: C07C 31/225 Glycerol

Abstract

The invention provides a process for purifying crude glycerol such as splitters crude, soaplye crude and methanolysis crude which comprises a microfiltration step over a filter material on a ceramic support preferably comprising alumina. Preferably the filter material comprises zirconia and/or alumina. Preferably the process further comprises the step of distillation and/or treatment with ion exchange resins. Also the process may involve a combination of microfiltration and ultrafiltration.

Claims

1. A process for purifying crude glycerol in aqueous solution, comprising the steps of obtaining the crude glycerol from oils and fats by saponification, hydrolysis or methanolysis, and microfiltrating over a filter material having a pore size in the range of from 1×

10^-6 to 1×

10^-8 m on a ceramic support.

2. A process according to claim 1, wherein the ceramic support material comprises alumina.

3. A process according to claim 1, wherein the filter material comprises ceramic material.

5. A process according to claim 1, wherein the process further comprises the step of treatment with ion exchange resins and/or distillation.

7. A process according to claim 1, wherein the crude glycerol starting material is an aqueous solution and contains 8 to 80% (w.w.) of glycerol and has been obtained by saponifying, hydrolysis or methanolysis of oils or fats.

8. A process according to claim 7, wherein the crude glycerol starting material is an aqueous solution containing 20 to 55% of glycerol.

9. A process according to claim 1, wherein prior to any filtration the pH of the crude glycerol starting material is adjusted to a value between 9 and 12 at a temperature between 60°

-100°

C.

10. A process according to claim 1 characterized in that the microfiltration is conducted over a filter material having a pore diameter between 5.10^-8 m and 20.10^-8 m.

4. A process for purifying crude glycerol in aqueous solution, comprising the steps of obtaining the crude glycerol from oils and fats by saponification, hydrolysis or methanolysis, and microfiltrating and ultrafiltrating in combination over a filter material having a pore size less than 1×

10^-8 m on a ceramic support.

6. A process according to claim 4, wherein the ultrafiltration step is conducted over a filter material which comprises an organic polymeric material.