Supercritical fluid-aided treatment of porous materials

• US 4,992,308 A
• Filed: 09/16/1988
• Issued: 02/12/1991
• Est. Priority Date: 09/16/1988
• Status: Expired

• Current Assignee: University of South Florida (State University System of Florida)
• Original Assignee: University of South Florida (State University System of Florida)
• Inventors: Sunol, Aydin K.
• Primary Examiner(s): SILVERMAN, STANLEY S
• Application Number:
  US07/245,858
• Time in Patent Office: 879 Days
• Field of Search: 427/297, 427/394, 427/395, 427/396, 427/397, 427/308, 427/317, 427/324, 427/328, 162/72
• US Class Current: 427/297
• CPC Class Codes: B05D 1/18 performed by dipping
• CPC Class Codes: B05D 2203/20 Wood or similar material
• CPC Class Codes: B05D 2401/90 at least one component of the composition being in supercritical state or close to supercritical state
• CPC Class Codes: B05D 7/06 to wood
• CPC Class Codes: B27K 3/15 Impregnating involving polymerisation including use of polymer-containing impregnating agents macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02
• CPC Class Codes: B27K 5/007 using pressure B27K3/08 takes precedence
• CPC Class Codes: C08L 33/12 Homopolymers or copolymers of methyl methacrylate
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: Y02P 20/54 using solvents, e.g. supercritical solvents or ionic liquids

Abstract

Method and process using a supercritical fluid, with or without the aid of entrainers (1) to solubilize a monomer, monomer mixture or polymer which may or may not include additives and entrainers, (2) to carry the supercritical solvent mixture thereby created into the wood matrix, (3) to remove extractives from the wood, (4) to precipitate the monomer or polymer within the wood, and (5) to polymerize the monomer in situ in the wood.

Claims

1. A process of making a porous material having enhanced properties, which comprises:

contacting porous material with a first supercritical solvent under conditions sufficient to extract extractives from said material;

separating supercritical solvent containing extractives from the porous material having less extractives;

contacting the porous material having less extractives with a second supercritical solvent containing a polymerizable monomer under conditions sufficient to impregnate the monomer into the porous material having less extractives;

precipitating the polymerizable monomer within the porous material having less extractives; and

polymerizing said precipitated polymerizable monomer in situ within the porous material having less extractives, thereby making a porous material having enhanced properties.

2. A process that enhances the chemical and mechanical properties of wood, which comprises:

preparing a predetermined quantity of a monomer in fluid form and containing said monomer in a vessel;

introducing a supercritical fluid into said vessel so that it flows through said monomer and dissolves said monomer, thereby forming a supercritical solvent; and

subjecting an article of wood to said supercritical solvent for a predetermined period of time at a predetermined pressure and at a predetermined temperature; and

recovering from the vessel wood having enhanced chemical and mechanical properties.

3. A process for treating wood to improve its physical qualities, which comprises:

immersing the wood for a predetermined time in a supercritical solvent containing monomer;

enlarging the pores of the wood by subjecting it to an entrainer dissolved in the supercritical fluid;

promoting polymerization of the monomer by dissolving a catalyst in said supercritical solvent;

inhibiting premature polymerization by including a polymerization inhibitor in the supercritical solvent; and

facilitating the transporting of monomers from bulk into the cell walls of the wood by dissolving an additional solvent in said supercritical solvent;

subjecting the immersed wood to conditions sufficient to polymerize the monomer within the cells of the wood, and separating the wood containing polymer from the supercritical fluid, thereby making a wood having improved physical properties.

4. A process for making paper which comprises impregnating wood with an alkaline medium or acid medium in the presence of a first fluid maintained under supercritical conditions, digesting the medium impregnated wood in the presence of a second fluid maintained under supercritical conditions including conditions sufficient to extract extractives and lignin from the wood and to separate the wood into essentially discrete fibers, separating supercritical fluid and extractives and lignin from the digested wood, and treating the separated digested wood under conditions including contacting the digested wood with a third supercritical fluid containing monomer, precipitating the monomer within the wood, and polymerizing the monomer in situ in the digested wood, and thereafter under conditions sufficient to convert the digested wood to paper.

5. A process for making a wood composite which comprises

contacting wood with a fluid medium maintained in its supercritical state having a solute of polymerizable monomer;

polymerizing the solute in situ under the supercritical state conditions;

removing the fluid medium from the wood by separating the solute from the fluid medium by precipitating the solute from its supercritical state to a liquid or solid state into the wood material;

thereby making a wood composite.

6. Process according to claim 5 whereby polymerizing the solute and separating the solute are simultaneous steps under isobaric conditions.

7. A process for making a wood composite which comprises;

contacting wood with a fluid medium maintained in its supercritical state having a solute of polymerizable monomer;

separating the solute from the fluid medium by precipitating the solute from its supercritical state to a liquid or solid state into the wood matrix; and

,

polymerizing the solute in situ;

thereby making a wood composite.