Porous hollow fiber

• US 4,992,332 A
• Filed: 04/27/1989
• Issued: 02/12/1991
• Est. Priority Date: 02/04/1986
• Status: Expired due to Fees

• Current Assignee: UBE Industries Limited (UBE Corporation)
• Original Assignee: UBE Industries Limited (UBE Corporation)
• Inventors: Yamanaka, Mitsuo, Kamei, Eiichi, Shimomura, Yasushi
• Primary Examiner(s): KENDELL, LORRAINE
• Application Number:
  US07/346,278
• Time in Patent Office: 656 Days
• Field of Search: 428/376, 428/398, 428/375, 428/400, 210/500.23
• US Class Current: 428/398
• CPC Class Codes: B01D 67/0088 Physical treatment with compounds, e.g. swelling, coating or impregnation
• CPC Class Codes: B01D 69/08 Hollow fibre membranes manufacture of hollow fibres D01D5/24, D01F1/08
• CPC Class Codes: Y10T 428/2933 Coated or with bond, impregnation or core
• CPC Class Codes: Y10T 428/2935 Discontinuous or tubular or cellular core
• CPC Class Codes: Y10T 428/2975 Tubular or cellular
• CPC Class Codes: Y10T 428/2978 Surface characteristic

Abstract

The improvement in a porous hollow fiber having a large number of micropores in its surrounding wall, in which walls of said pores are coated with an essentially water-insoluble alkylcellulose derivative such as ethylcellulose, carboxymethylethylcellulose, hydroxypropylmethylcellulose acetate succinate or hydroxypropylmethylcellulose phthalate, or poly(2-hydroxyethyl methacrylate).

Claims

1. In a porous hollow polypropylene fiber having a large number of micropores in its surrounding wall, the improvment in which walls of said pores are coated with an essentially water-insoluble polymer selected from the group consisting of, carboxymethylethylcellulose, hydroxypropylmethylcellulose acetate succinate and hydropropylmethylcellulose phthalate and.

2. The porous hollow fiber as claimed in claim 1, wherein outer and inner surfaces of the surrounding wall are further coated with said polymer.

3. The porous hollow fiber as claimed in claim 1, wherein at least one of outer and inner surfaces of the surrounding wall is coated with a non-porous layer of said polymer.

4. The porous hollow fiber as claimed in claim 1, wherein said micropores in the surrounding wall are filled up with said polymer.

5. The porous hollow fiber as claimed in claim 1, wherein said polymer is hydroxypropylmethylcellulose acetate succinate having substituents comprising 12-28 mol.% of methoxyl group, 4-23 mol.% of hydroxypropoxyl group, 2-16 mol.% of acetyl group and 4-28 mol.% of succinoyl group.

6. The porous hollow fiber as claimed in claim 1, wherein said polymer is carboxymethylethylcellulose containing 8.9-14.9 wt.% of carboxymethyl group and 32.5-43.0 wt.% of ethoxyl group.

7. The porous hollow fiber as claimed in claim 1, wherein said polymer is hydroxypropylmethylcelulose phthalate having substituents comprising 18-24 mol.% of methoxyl group, 5-10 mol.% of hydroxypropoxyl group, and 21-35 mol.% of carboxybenzoyl group.