Process for manufacturing a gas generating material

• US 4,994,212 A
• Filed: 05/24/1990
• Issued: 02/19/1991
• Est. Priority Date: 05/24/1990
• Status: Expired due to Term

• Current Assignee: TRW Vehicle Safety Systems Incorporated (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Original Assignee: TRW Vehicle Safety Systems Incorporated (Zeppelin - Stiftung der Stadt Friedrichshafen)
• Inventors: Knowlden, Leo S., Goetz, George W., Kumkoski, James M., Vos, Thomas H.
• Primary Examiner(s): Nelson, Peter A.
• Assistant Examiner(s): CARROLL, CHRISMAN DION
• Application Number:
  US07/528,144
• Time in Patent Office: 271 Days
• Field of Search: 149/35, 149/109.6, 264/3.1, 264/3.3, 264/3.4
• US Class Current: 264/3.3
• CPC Class Codes: C06B 21/0033 Shaping the mixture
• CPC Class Codes: C06B 35/00 Compositions containing a metal azide
• CPC Class Codes: C06D 5/06 by reaction of two or more solids

Abstract

A process for manufacturing a gas generating material includes preparing a wet mixture of a metal azide and a metal oxide without prior mixing of the metal azide and metal oxide in dry form. The metal azide content of the gas generating material is controlled and the possibility of forming hazardous hydrazoic acid fumes is minimized by maintaining the temperature of the wet mixture of gas generating material between 20° C. and 30° C. The possibility of forming hydrazoic acid fumes is further reduced by maintaining the pH of the wet mixture of gas generating materials at or above 10.5. Excess liquid is removed from the wet mixture of gas generating materials so that the wet mixture has a moisture content of approximately 9%. The excess liquid from the wet mixture is recycled and used the formation of additional gas generating material. The wet mixture of gas generating materials, having a moisture content of approximately 9%, is formed through small openings to form extrudate of gas generating material.

Claims

1. A process for manufacturing a gas generating material comprising the steps of:

preparing a wet mixture of a metal azide and a metal oxide without prior mixing of the metal azide and metal oxide in dry form;

processing the wet mixture to form granules of gas generating material;

drying the granules of gas generating material; and

maintaining the mixture in a wet state throughout said processing prior to said step of drying the granules.

2. A process as set forth in claim 1 wherein said step of preparing a wet mixture of a metal azide and a metal oxide includes mixing a metal azide powder and a metal oxide powder in a liquid.

3. A process as set forth in claim 1 wherein said step of preparing a wet mixture of a metal azide and a metal oxide includes mixing a metal oxide powder in a liquid containing a metal azide.

4. A process as set forth in claim 1 wherein said step of processing said wet mixture to form granules of gas generating material includes removing liquid from the wet mixture, said step of preparing a wet mixture of a metal azide and a metal oxide including mixing the metal azide and the metal oxide with the liquid removed from the wet mixture.

5. A process as set forth in claim 4 wherein said step of mixing the metal azide and the metal oxide with the liquid removed from the wet mixture includes adding the metal azide to the wet mixture and, thereafter, adding the metal oxide to the liquid removed from the wet mixture.

6. A process as set forth in claim 1 further including the step of sensing the pH of the wet mixture of a metal azide and a metal oxide and increasing the base content of the wet mixture if the sensed pH is below a predetermined number.

7. A process as set forth in claim 1 further including the step of sensing the temperature of the wet mixture of a metal azide and a metal oxide and cooling the wet mixture if the temperature of the wet mixture exceeds a predetermined temperature.

8. A process as set forth in claim 1 further including the steps of maintaining the mixture at a pH of at least 10.5 and at a temperature of 20°

C. to 30°

C. during said step of processing the wet mixture.

9. A process as set forth in claim 1 wherein said step of processing the wet mixture includes repeatedly grinding the wet mixture and, thereafter, removing liquid from the wet mixture.

10. A process as set forth in claim 1 wherein said wet mixture comprises 45% to 55% by weight of solids.

11. A process for manufacturing a gas generating material comprising the steps of:

preparing a first wet mixture of ingredients of the gas generating material in a first supply tank;

grinding the first wet mixture at a grinding location spaced from the first supply tank;

thereafter, directing the first wet mixture into a second supply tank;

adding additional ingredients to the first wet mixture in the second supply tank and preparing a second wet mixture in the second supply tank;

directing the second wet mixture from the second supply tank to a liquid removal station;

removing liquid from the second wet mixture at the liquid removal station to provide the second mixture with a desired moisture content; and

forming the second mixture with the desired moisture content into particles.

12. A process as set forth in claim 11 wherein said step of preparing a first wet mixture includes preparing a wet mixture of a metal azide and a metal oxide without prior mixing of the metal azide and metal oxide in dry form.

13. A process as set forth in claim 11 further including the steps of sensing the pH of the first wet mixture and adding a material to the first wet mixture to increase the pH of the first wet mixture in response to sensing that the first wet mixture has a pH below a predetermined number, sensing the pH of the second wet mixture and adding a material to the second wet mixture to increase the pH of the second wet mixture in response to sensing that the second wet mixture has a pH below a predetermined number.

14. A process as set forth in claim 11 further including the steps of cooling the first wet mixture during preparing and grinding of the first wet mixture.

15. A process as set forth in claim 11 wherein said step of removing liquid from the second wet mixture at the liquid removal station to provide the second mixture with a desired moisture content includes the step of reducing the moisture content of the second mixture to between 7% and 11% by weight.

16. A process as set forth in claim 11 further including the step of conducting liquid removed from the second wet mixture at the liquid removal station to the first supply tank to recycle the liquid.

17. A process as set forth in claim 11 wherein said step of forming said second mixture with the desired moisture content into particles includes forcing the second mixture through a plurality of openings.

18. A process as set forth in claim 11 further including the step of maintaining the first wet mixture at a temperature of 20°

C. to 30°

C. during said steps of preparing the first wet mixture and grinding the first wet mixture.

19. A process for manufacturing a gas generating material comprising the steps of:

preparing a wet mixture of a metal azide and an oxidizer without prior mixing of the metal azide and oxidizer in dry form;

processing the wet mixture to form granules of gas generating material;

drying the granules of gas generating materials after processing the mixture to form granules; and

maintaining the mixture at a temperature of 20°

C. to 30°

C. during said preparing and processing steps.

20. A process as defined in claim 19 wherein said oxidizer comprises a metal oxide.

21. A process as set forth in claim 20 further including the step of maintaining the mixture at a pH of at least 10.5 during said step of processing the wet mixture.

22. A process as set forth in claim 20 wherein said step of processing the wet mixture includes removing liquid from the wet mixture, said process further including the step of using the liquid to form additional wet mixture.

23. A process as set forth in claim 20 wherein said step of preparing the wet mixture includes grinding a wet mixture of a metal azide and metal oxide and adding an extrusion aid and strengthening fibers t the mixture after performing said grinding step.

24. A process as set forth in claim 20 wherein said step of preparing a wet mixture of a metal azide and a metal oxide without prior mixing of the metal azide and metal oxide in dry form includes preparing a solution of the metal azide and an oxidizing agent in a first tank, said step of maintaining the mixture at a temperature of 20°

C. to 30°

C. during said preparing and processing steps including heating the solution in the first tank, said step of preparing a wet mixture of a metal azide and a metal oxide without prior mixing of the metal azide and metal oxide in dry form further includes directing the solution from the first tank to a second tank and adding metal oxide powder and metal azide powder to the solution in the second tank, said step of maintaining the mixture at a temperature of 20°

C. to 30°

C. during said preparing and processing steps further includes cooling the wet mixture in the second tank.

25. A process as set forth in claim 24 wherein said step of processing the wet mixture to form granules includes removing liquid from the wet mixture, said method further including recycling the removed liquid by mixing it with the solution of a metal azide and an oxidizing agent prior to performing said step of adding metal oxide powder and metal azide powder to the wet mixture in the second tank.

26. A process as set forth in claim 19 wherein said step of preparing a wet mixture of a metal azide and a metal oxide includes grinding the wet mixture of the metal azide and metal oxide, said step of maintaining the mixture at a temperature of 20°

C. to 30°

C. includes cooling the mixture while performing said grinding step, said step of processing the wet mixture to form granules includes extruding the wet mixture through a plurality of openings after performing said step of grinding the wet mixture, said step of maintaining the mixture at a temperature of 20°

C. to 30°

C. including cooling the mixture while performing said extruding step.

27. A process as set forth in claim 19 wherein said wet mixture comprises 45% to 55% by weight of solids.

28. A process for manufacturing a gas generating material comprising the steps of:

preparing a wet mixture of a metal azide and an oxidizer;

sensing the pH of the mixture;

adding a base material to the mixture to maintain the pH of the mixture greater than about 10.5; and

processing the mixture to form particles of gas generating material.

29. A process as set forth in claim 28 wherein said oxidizer comprises a metal oxide.

30. A process as set forth in claim 29 wherein said step of adding a base material to the mixture to maintain the pH of the mixture greater than 10.5 includes adding a source of hydroxide ions to the mixture.

31. A process as set forth in claim 29 further including adding additional ingredients to the wet mixture, said step of sensing the pH of the mixture including sensing the pH of the mixture prior to adding the additional ingredients to the mixture and sensing the pH of the mixture after adding the additional ingredients to the mixture, said step of adding a base material to the mixture to maintain the pH of the mixture greater than about 10.5 including adding base material to the mixture before the additional ingredients are added to the mixture and after adding the additional ingredients to the mixture.

32. A process as set forth in claim 29 further including the step of maintaining the temperature of the mixture at a temperature of from 20°

C. to 30°

C. during said step of preparing a wet mixture.

33. A process as set forth in claim 29 wherein said step of preparing a wet mixture of a metal azide and a metal oxide includes preparing the wet mixture without prior mixing of the metal azide and metal oxide in dry form.

34. A process for manufacturing a gas generating material comprising the steps of:

preparing a wet mixture of a metal azide and an oxidizer;

processing the mixture to form particles of gas generating material including removing liquid from the mixture to provide the mixture with a desired moisture content; and

recycling the removed liquid by utilizing the removed liquid during said step of preparing a wet mixture.

35. A process as set forth in claim 34 wherein said step of removing liquid from the mixture to provide the mixture with a desired moisture content includes reducing the moisture content of the mixture to approximately 9%.

36. A process as set forth in claim 34 wherein said step of recycling the removed liquid includes adding oxidizer to the removed liquid during performance of said step of preparing a wet mixture.

37. A process as set forth in claim 34 wherein said step of recycling the removed liquid includes adding an oxidizing agent to the removed liquid.

38. A process as set forth in claim 34 wherein said step of preparing a wet mixture of a metal azide and an oxidizer is performed without prior mixing of the metal azide and oxidizer in dry form.

39. A process as set forth in claim 34 wherein said step of processing the mixture comprises forcing the mixture through a plurality of openings after performing said step of removing liquid from the mixture.

40. A process as set forth in claim 34 wherein said step of preparing a wet mixture of a metal azide and an oxidizer includes repeatedly grinding the we mixture.

41. A process as set forth in claim 34 wherein said step of preparing a wet mixture of a metal azide and an oxidizer includes maintaining the temperature of the wet mixture at 20°

C. to 30°

C.

42. A process as set forth in claim 41 wherein said step of preparing a wet mixture of a metal azide and an oxidizer includes sensing the pH of the mixture and maintaining the pH of the mixture above 10.5.

43. A process as set forth in claim 34 wherein said wet mixture comprises 45% to 55% by weight of solids.