Selective gas detecting apparatus

• US 4,996,431 A
• Filed: 02/10/1989
• Issued: 02/26/1991
• Est. Priority Date: 02/10/1989
• Status: Expired due to Fees

• Current Assignee: Gas Research Institute (GTI Energy)
• Original Assignee: Gas Research Institute (GTI Energy)
• Inventors: Bonne, Ulrich, Matthys, Robert J.
• Primary Examiner(s): FIELDS, CAROLYN
• Application Number:
  US07/308,468
• Time in Patent Office: 746 Days
• Field of Search: 250/343, 250/339, 250/345, 250/338.5
• US Class Current: 250/343
• CPC Class Codes: G01J 1/1626 Arrangements with two photodetectors, the signals of which are compared
• CPC Class Codes: G01J 2001/161 Ratio method, i.e. Im/Ir
• CPC Class Codes: G01J 2001/4242 Modulated light, e.g. for synchronizing source and detector circuit
• CPC Class Codes: G01N 2021/3166 using separate detectors and filters
• CPC Class Codes: G01N 21/314 with comparison of measurements at specific and non-specific wavelengths dual wavelength spectrometry G01J3/427
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis

Abstract

A selective gas detecting apparatus for determining the concentration and type of hydrocarbon gas in a gas sample based upon absorption of infrared radiation by the gas sample, the apparatus having two infrared radiation absorption channels with the wavelengths for measurement selected so that one channel at 3.2 microns provides an output signal corresponding to approximately the sum of all hydrocarbons in the gas sample which signal is displayed as an indication of concentration of hydrocarbon gas in the gas sample, and the other channel at 3.4 microns, after essentially being ratioed to the 3.2 micron channel output provides an output signal representative of the type or average type of hydrocarbon in the gas sample, and the ratio of the signal in the two channels is displayed as an indication of the type of hydrocarbon in the gas sample.

Claims

1. A selective gas detecting apparatus for determining a concentration and type or average type of hydrocarbon gas in a gas sample based upon absorption of infrared radiation by the gas sample, comprising:

means for passing infrared radiation through the gas sample, infrared radiation detecting means for detecting infrared radiation passed through the gas sample and producing in a first signal channel a first measurement signal indicative of a first wavelength absorbed by the gas sample, and producing in a second signal channel a second measurement signal indicative of a second wavelength absorbed by the gas sample, processing circuit means including first circuit means responsive to said first measurement signal for providing a first output signal corresponding to a first total concentration of hydrocarbons in the gas sample, second circuit means responsive to said second measurement signal for providing a second output signal corresponding to a second total concentration of hydrocarbons in the gas sample, ratio determining means responsive to said first and second output signals for providing a ratio signal corresponding to the ratio of said first and second output signals, said ratio signal being indicative of the type or average type of hydrocarbon gas, and display means responsive to said first output signal and said ratio signal for providing an indication of the concentration and type or average type of hydrocarbon gas in the gas sample, respectively.

2. A gas detecting apparatus according to claim 1, wherein said first wavelength is 3.2±

0.1 microns and said second wavelength is 3.4±

0.1 microns.

3. A gas detecting apparatus according to claim 2, wherein said infrared radiation detecting means produces a reference measurement signal indicative of a third wavelength absorbed by the gas sample, said reference measurement signal being applied to said first and second circuit means for generating said first and second output signals.

4. A gas detecting apparatus according to claim 3, wherein said third wavelength is 2.9±

0.1 microns.

5. A gas detecting apparatus according to claim 2, wherein said third wavelength is 3.9±

0.1 microns.

6. A gas detecting apparatus according to claim 3, wherein said processing circuit means further comprises offset means for adjusting said ratio signal to be a preselected value when said ratio signal indicates that the type of hydrocarbon is methane.

7. A gas detecting apparatus according to claim 6, wherein said offset means includes means for producing an offset signal and circuit means for subtracting said offset signal from said ratio signal at the output of said ratio determining means.

8. A gas detecting apparatus according to claim 3, wherein said display means comprises first and second analog meters and first and second function circuit means, said first function circuit means being interposed between said ratio determining means and said first meter and responsive to said ratio signal for providing a signal corresponding to the logarithm of said ratio signal for driving said first meter, and said second function circuit means being interposed between said first circuit means and said second meter and responsive to said second output signal for providing a signal corresponding to the logarithm of said second output signal for driving said second meter.

9. A gas detecting apparatus according to claim 3, further comprising alarm means responsive to said ratio signal for providing an indication whenever a measured concentration of ethane is below a preselected level.

10. A gas detecting apparatus according to claim 4, wherein said infrared radiation detecting means comprises first, second and third infrared detectors responsive to infrared radiation at 3.4 microns, 3.2 microns, and 2.9 microns, respectively, first combining circuit means for combining signal outputs of said first and third detectors to produce said first measurement signal, and second combining circuit means for combining signal outputs of said second and third detectors for producing said second measurement signal.

11. A gas detecting apparatus according to claim 3, wherein said first and second circuit means each comprise a low pass filter circuit and said ratio determining means comprises a function circuit providing a signal output corresponding to a quotient of said first and second output signals.

12. A gas detecting apparatus according to claim 11, wherein said display means comprises first and second analog meters and first and second function circuit means, said first function circuit means being interposed between said ratio determining means and said first meter and responsive to said ratio signal for providing a signal corresponding to a logarithm of said ratio signal for driving said first meter, and said second function circuit means being interposed between said first circuit means and said second meter and responsive to said second output signal for providing a signal corresponding to the logarithm of said second output signal for driving said second meter.

13. A gas detecting apparatus according to claim 12, wherein said first meter has a scale divided into low, intermediate and high reading portions to indicate that the type of hydrocarbon is swamp gas, or natural gas, propane or gasoline vapors, respectively.

14. A selective gas detecting apparatus for determining the concentration and type or average type of hydrocarbon gas in a gas sample based upon absorption of infrared radiation by the gas sample comprising:

means for passing infrared radiation through the gas sample, infrared detecting means for detecting infrared radiation passed through the gas sample including a first infrared detector producing a first detection signal indicative of a first wavelength absorbed by the gas sample, a second infrared detector producing a second detection signal indicative of a second wavelength absorbed by the gas sample, and a reference infrared detector producing a reference signal indicative of a third wavelength absorbed by the gas sample, first signal combining circuit means for combining said reference signal with said first detection signal to produce a first measurement signal indicative of said first wavelength absorbed by the gas sample, second signal combining circuit means for combining said reference signal with said second detection to produce a second measurement signal indicative of said second wavelength absorbed by the gas sample, processing circuit means including first circuit means responsive to said first measurement signal for providing a first output signal corresponding to a first total concentration of hydrocarbons in the gas sample, second circuit means responsive to said second measurement signal for providing a second output signal corresponding to a second total concentration of hydrocarbons in the gas sample, ratio determining means responsive to said first and second output signals for providing a ratio signal corresponding to the ratio of said first and second output signals, said ratio signal being indicative of the type or average type of hydrocarbon gas, and display means responsive to said second output signal and said ratio signal for providing an indication of the concentration and type or average type of hydrocarbon gas in the gas sample, respectively.

15. A gas detecting apparatus according to claim 14, wherein said first wavelength is 3.2 microns, said second wavelength is 3.4 microns and said third wavelength is 3.9 microns.

16. A gas detecting apparatus according to claim 15, wherein said first wavelength is 3.2 microns, said second wavelength is 3.4 microns and said third wavelength is 2.9 microns.

17. A gas detecting apparatus according to claim 16, wherein said processing circuit means further comprises offset means for adjusting said ratio signal to be a preselected value when said ratio signal indicates that the type of hydrocarbon is methane.

18. A gas detecting apparatus according to claim 17, wherein said offset means includes means for producing an offset signal and circuit means for subtracting said offset signal from said ratio signal at the output of said ratio determining means.

19. A gas detecting apparatus according to claim 16, further comprising alarm means responsive to said ratio signal for providing an indication whenever the measured concentration of ethane is below a preselected level.

20. A method of determining a concentration and type or average type of hydrocarbon gas in a gas sample comprising:

passing infrared radiation through the gas sample, detecting infrared radiation passed through the gas sample, producing in a first signal channel a first measurement signal indicative of a first wavelength absorbed by the gas sample and corresponding to a first total concentration of hydrocarbons in the gas sample, producing in a second signal channel a second measurement signal indicative of a second wavelength absorbed by the gas sample and corresponding to a second total concentration of hydrocarbons in the gas sample, obtaining a ratio of the first and second measurement signals to produce a ratio signal indicative of the type or average of hydrocarbon gas and applying the second measurement signal and the ratio signal to first and second analog meters to provide an indication of the concentration and type or average of hydrocarbon gas, respectively, in the gas sample.