Materials and methods for photocatalyzing oxidation of organic compounds on water

• US 4,997,576 A
• Filed: 09/25/1989
• Issued: 03/05/1991
• Est. Priority Date: 09/25/1989
• Status: Expired due to Fees

• Current Assignee: Board of Regents of the University of Texas System (University of Texas System)
• Original Assignee: Board of Regents of the University of Texas System (University of Texas System)
• Inventors: Heller, Adam, Brock, James R.
• Primary Examiner(s): NOT, DEFINED
• Assistant Examiner(s): Shideler, Krisanne
• Application Number:
  US07/412,317
• Time in Patent Office: 526 Days
• Field of Search: 210/748, 210/749, 210/763, 210/758, 210/922, 210/925
• US Class Current: 210/748.09
• CPC Class Codes: B01J 35/30 characterised by their physical properties
• CPC Class Codes: C02F 1/288 using composite sorbents, e.g. coated, impregnated, multi-layered
• CPC Class Codes: C02F 1/30 by irradiation
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/681 by addition of solid materials for removing an oily layer on water
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 2101/32 Hydrocarbons, e.g. oil
• CPC Class Codes: C02F 2305/10 Photocatalysts
• CPC Class Codes: Y10S 210/925 using chemical agent

Abstract

A bead having an exterior surface which is at least partially coated with a material that under illumination and in the presence of air is capable of accelerating the oxidation of organic compounds floating on water. The coated bead is water floatable and has an equivalent diameter of less than about 2 mm, preferably on the order of 10-30 microns. These coated beads can be used to accelerate under illumination oxidation of a floating oil film (e.g. from an oil spill) by dispersing the coated beads in the film and allowing them to be exposed to solar illumination and oxygen.

Claims

1. A method for treating an oil film floating on a body of water, comprising the steps of:

dispersing a plurality of water floatable particles on such an oil film, the particles comprising a material that under illumination and in the presence of air is capable of accelerating the oxidation of organic compounds in the oil film; and

allowing the particles to be exposed to solar illumination and ambient air such that the particles accelerate the oxidation of organic compounds in the oil film.

2. The method of claim 1, wherein the particle material comprises an inorganic material.

3. The method of claim 1, wherein the particle material comprises an n-type semiconductor having a band gap of at least about 2 eV.

4. The method of claim 1, wherein the particle material comprises a photoconductive material.

5. The method of claim 1, wherein the particle material comprises titanium dioxide, zinc oxide, zinc sulfide, or iron oxide.

6. The method of claim 1, wherein the particle material comprises rutile or anatase.

7. A method for treating an oil film floating on a body of water, comprising the steps of:

dispersing a plurality of beads on such an oil film, the beads being at least partically coated with a material that under illumination and in the presence of air is capable of accelerating the oxidation of organic compounds in the oil film, each coated bead being water floatable and having an equivalent diameter of less than about 2 mm; and

allowing the coated beads to be exposed to solar illumination and ambient air such that the coating material accelerates the oxidation of organic compounds in the oil film.

8. The method of claim 7, wherein each coated bead has a density less than the density of sea water.

9. The method of claim 7, wherein each coated bead has a density less than the density of water.

10. The method of claim 7, wherein each coated bead has a density less than 0.9 g/cm³ at 20°

C.

11. The method of claim 7, wherein each coated bead has a density less than 0.7 g/cm³ at 20°

C.

12. The method of claim 7, wherein the coated beads float at or near the surface of the oil film.

13. The method of claim 7, wherein each coated bead is substantially hydrophobic.

14. The method of claim 7, wherein each bead is additionally coated with a substantially hydrophobic material.

15. The method of claim 7, wherein each bead has an index of refraction of at least about 1.5.

16. The method of claim 7, wherein each bead has an index of refraction of at least about 1.6.

17. The method of claim 7, wherein the coating material on each bead has an index of refraction of at least about 2.0.

18. The method of claim 7, wherein the index of refraction of the coating material is higher than that of each bead.

19. The method of claim 7, wherein the coating material on each bead comprises an n-type semiconductor having a band gap of at least about 2 eV.

20. The method of claim 7, wherein the coating material on each bead comprises a photoconductive material.

21. The method of claim 7, wherein the coating material on each bead comprises titanium dioxide.

22. The method of claim 7, wherein the coating material on each bead comprises zinc oxide, zinc sulfide, or iron oxide.

23. The method of claim 7, wherein the beads comprise a glass material.

24. The method of claim 7, wherein the beads comprise a ceramic material.

25. The method of claim 23 or 24, wherein the beads are hollow.

26. The method of claim 7, wherein each bead comprises a plastic material coated with an intermediate layer comprising a material which will not accelerate the oxidation of the plastic material by air or itself be oxidized by the outer coating material.

27. The method of claim 7, wherein the plastic material comprises polyethylene or polypropylene.

28. The method of claim 26 or 27, wherein the intermediate layer material comprises silicon dioxide or aluminum oxide.

29. The method of claim 7, wherein each coated bead has an equivalent diameter of less than about 200 microns.

30. The method of claim 7, wherein each coated bead has an equivalent diameter of less than about 100 microns.

31. The method of claim 7, wherein each coated bead has an equivalent diameter of between about 10 and 30 microns.

32. The method of claim 7, wherein each coated bead has an equivalent diameter of at least 30 nm.

33. The method of claim 7, wherein each coated bead has an equivalent diameter less than the average thickness of the oil film.

34. The method of claim 7, wherein light is trapped by the beads and internally reflected to the coating material.

35. The method of claim 7, wherein the coating material comprises rutile or anatase.