Composite particle dispersions

• US 4,997,864 A
• Filed: 01/24/1989
• Issued: 03/05/1991
• Est. Priority Date: 01/29/1988
• Status: Expired due to Fees

• Current Assignee: Imperial Chemical Industries PLC (Nouryon BV)
• Original Assignee: Imperial Chemical Industries PLC (Nouryon BV)
• Inventors: Waters, Julian A.
• Primary Examiner(s): Schofer, Joseph L.
• Assistant Examiner(s): WEBER, THOMAS
• Application Number:
  US07/301,052
• Time in Patent Office: 770 Days
• Field of Search: 523/319, 523/333, 523/334, 427/221
• US Class Current: 523/319
• CPC Class Codes: C08J 3/005 Processes for mixing polymers
• CPC Class Codes: C08J 3/212 and solid additives

Abstract

A process for the preparation of composite particle dispersons is disclosed. The composite particles have a core particle 1 surrounded by a second material 2. Normally a core shell particle will be formed and the second material which forms the shell will be a polymer material.

The composite particles are formed by mixing a dispersion of polymer particles with pre-formed core material particles. The polymer particles are stabilized relative to one another, and the core material particles are destabilized in the dispersion so that they are able to make contact with the surfaces of the polymer particles. The process takes place at a temperature above the operative glass transition temperature of the polymer, and in the process the polymer spreads over the surface of the core particle so that the core particle is encapsulated.

The process will proceed, and composite particles will be formed, when the interfacial energies of the three interfaces (core/polymer: core/liquid: polymer/liquid) and the relative volumes of the core particles and polymer particles are related to one another in accordance with an equation which is set out in the specification.

Claims

1. A process for preparing a dispersion of composite particles, which process comprises mixing first particles with a liquid dispersion of polymer particles, the polymer particles being ionically and/or sterically colloidally stable against particle-particle flocculation and agglomeration, wherein the mixing takes place at a temperature above the operative glass transition temperature of the polymer particles and under a condition where ##EQU31## where γ

_1-3 is the interfacial energy of the first particle surface/liquid interface

γ

_1-2 is the interfacial energy of the first particle surface/polymer particle interface

γ

_2-3 is the interfacial energy of the polymer particle surface/liquid interface

v_p and v_c represent the relative volumes of, respectively, the average polymer particle and the average first particle with v_p +v_c =1

and where the first particles are able to make contact with the surfaces of the polymer particles so that when contact occurs between first particles and polymer particles, composite particles are produced as a dispersion in the liquid phase, the composite particles having ionic and/or stearic colloidal stability against particle-particle flocculation and agglomeration.

2. A process as claimed in claim 1, wherein the value of ##EQU32## is greater than 0.5.

3. A process as claimed in claim 1, wherein the surface of the polymer particles remains more hydrophilic/lyophilic than the surface of the first particles during the process.

4. A process as claimed in claim 1, wherein the polymer particles are dispersed in a non-aqueous liquid medium and wherein the first particles have a lyophobic surface in the liquid medium and the polymer particles have a surface composition which includes oligomer or polymer or polymer components soluble in the liquid phase sufficient to give these particles a lyophilic surface.

5. A process as claimed in claim 1, wherein the first particles are dispersed in a liquid medium prior to being mixed with the polymer particle dispersion.

6. A process as claimed in claim 5, wherein the liquid medium of the first particle dispersion is miscible with the liquid medium of the polymer particle dispersion.

7. A process as claimed in claim 5, wherein the first particles include a surfactant in order to maintain the particles stable in their liquid medium.

8. A process as claimed in claim 1, wherein the polymer particles are dispersed in an aqueous medium.

9. A process as claimed in claim 8, wherein the first particles have a hydrophobic surface and the polymer particles have a surface composition which includes oligomer or polymer or polymer components soluble in the liquid phase sufficient to give the polymer particles a hydrophilic surface.

10. A process as claimed in claim 1, wherein the first particles are pigment particles.

11. A process as claimed in claim 1, wherein the first particles are filler or extender particles.

12. A process as claimed in claim 1, wherein the first particles are polymer particles.

13. A process as claimed in claim 12, wherein the polymer particles are made by an emulsion polymerisation process.

14. A process as claimed in claim 1, wherein the polymer particles include an organic liquid residing at least partly inside the polymer particles.

15. A process as claimed in claim 1, wherein the liquid dispersion of polymer particles is a naturally occurring, naturally stabilised latex.

16. A process as claimed in claim 1, wherein the first particles are added slowly to the dispersion of polymer particles.

17. A process as claimed in claim 1, wherein a further component is added to the mixture of the first particles and the polymer particles in dispersion, the further component being effective to alter the stability of one or the other or both of the particle types in the dispersion or to vary one or more of the interfacial energies.

18. A process as claimed in claim 1, wherein the first particles are in a liquid dispersion, which dispersion is unstable to dilution with another liquid, and the polymer particles are in dispersion in said another liquid.

19. A process as claimed in claim 17, wherein the first particles are initially ionically stabilised in the mixture and the polymer particles are at least partly sterically stabilised, and wherein a compound of opposite charge to the first particle stabilisation is added to the mixture to destabilise the first particles.

20. A process as claimed in claim 17, wherein the first particles are initially ionically stabilised in the mixture and the polymer particles are at least partly sterically stabilised, and wherein an electrolyte compound is added to the mixture to destabilise the charged first particles.

21. A process as claimed in claim 19, wherein the compound of opposite charge is selected to increase the hydrophobic nature of the first particles.

22. A process as claimed in claim 21, wherein the compound of opposite charge is a surfactant.

23. A process as claimed in claim 21, wherein the compound of opposite charge is a polymer.

24. A process as claimed in claim 17, wherein the further component is a polymer which includes the same polymeric components as are present in the polymer particles.

25. A process as claimed in claim 1, wherein the ratio of polymer particles to first particles is approximately 1:

1.

26. A process as claimed in claim 1, wherein there are more first particles than polymer particles.

27. A process as claimed in claim 1, wherein the polymer particles are larger than the first particles.

28. A process for preparing a dispersion of composite particles in a liquid phase, the composite particles being stable against flocculation and aggregation, which process comprises mixing first particles, which particles are not stable against flocculation and aggregation in the process, with a liquid dispersion of polymer particles where the polymer particles are stable against flocculation and aggregation;

wherein the mixing takes place at a temperature above the operative glass transition temperature of the polymer particles and where

space="preserve" listing-type="equation">θ

.sub.p <

90°

and ##EQU33## where v_p and v_c represent the relative volumes of, respectively, the average polymer particle and the average average first particle, with v_p +v_c =1 and where p is the contact angle made by the material of the polymer particles in an environment of the liquid phase at a surface which has the surface composition of the first particles.