Method for treating polyetherimide substrates and articles obtained therefrom

• US 4,999,251 A
• Filed: 04/03/1989
• Issued: 03/12/1991
• Est. Priority Date: 04/03/1989
• Status: Expired due to Fees

• Current Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Original Assignee: General Electric Company
• Inventors: Dumas, William V., Foust, Donald F.
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): DANG, VI
• Application Number:
  US07/331,715
• Time in Patent Office: 708 Days
• Field of Search: 427/304, 427/306, 428/458, 428/35.8, 525/420
• US Class Current: 428/458
• CPC Class Codes: C23C 18/24 using acid aqueous solutions
• CPC Class Codes: H05K 3/381 by special treatment of the substrate
• CPC Class Codes: Y10T 428/1355 Elemental metal containing [e.g., substrate, foil, film, coating, etc.]
• CPC Class Codes: Y10T 428/31681 Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]

Abstract

The method is provided for treating the surface of a polyetherimide substrate to improve its adhesion characteristics for electrolessly deposited metal, such as copper. There is employed a series of surface treatments including the initial immersion of the polyetherimide substrate in sulfuric acid, contact with aqueous base, such as potassium hydroxide, followed by oxidation with an alkali metal permanganate such as potassium permanganate, and surface treatment with a reducing agent, such as a hydroxylamine salt. Polyetherimide metal composites are also provided.

Claims

1. A method for modifying the surface of a polyethermide substrate to improve its adhesion characteristics for electrolessly deposited metal without the use of an adhesion promoter which consists essentially of

(A) treating the polyetherimide surface with a degreasing agent,

(B) modifying the degreased polyetherimide surface with concentrated sulfuric acid.

(C) treating the modified polyetherimide surface with an aqueous base to provide a pH of 14 or above,

(D) oxidizing the resulting polyetherimide surface of (C) with alkali metal permanganate resulting in the production of a manganese oxide residue, and

(E) effecting the removal of the manganese oxide residue from the polyetherimide surface by treating the polyetherimide surface with a reducing agent.

2. A method in accordance with claim 1, where the polyetherimide is reinforced with glass fiber.

3. A method in accordance with claim 1, where the reducing agent is hydroxylamine hydrochloride.

4. A method in accordance with claim 1, where the alkali metal permanganate is potassium permanganate.

5. A method in accordance with claim 1, where the degreasing agent is 1,1-2-trichlorotrifluoroethane.

6. Metallized polyetherimide composite comprising a polyetherimide substrate having electrolessly deposited metal patterned thereon, where the polyetherimide substrate has been treated in accordance with claim 1.

7. A polyetherimide substrate having a thickness of 0.5 to 25 mils treated in accordance with the method of claim 1.

8. A composite in accordance with claim 6 having metal electrolytically deposited on the surface of the electrolessly deposited metal.

9. A composite in accordance with claim 6 having electrolytically deposited copper on electrolessly deposited copper.

10. A circuit board in accordance with claim 6.

11. A coffee pot in accordance with claim 6 have electrolessly deposited metal on its base.