Method for manufacturing an article comprising a refractory dielectric body

• US 5,000,771 A
• Filed: 12/29/1989
• Issued: 03/19/1991
• Est. Priority Date: 12/29/1989
• Status: Expired due to Term

• Current Assignee: Fitel USA Corporation
• Original Assignee: AT&T, Inc.
• Inventors: Partus, Fred P., Fleming, James W. Jr.
• Primary Examiner(s): LINDSAY JR, ROBERT
• Application Number:
  US07/458,921
• Time in Patent Office: 445 Days
• Field of Search: 65/2, 65/3.11, 65/23, 65/61, 65/31, 156/643, 156/663
• US Class Current: 65/391
• CPC Class Codes: C03B 37/01205 starting from tubes, rods, fibres or filaments C03B37/014 takes precedence
• CPC Class Codes: C03B 37/01237 to modify the diameter by heat-polishing, e.g. fire-polishing
• CPC Class Codes: C03B 37/01257 Heating devices therefor
• CPC Class Codes: C03B 37/01446 Thermal after-treatment of preforms, e.g. dehydrating, consolidating, sintering C03B37/01853 takes precedence
• CPC Class Codes: C03B 37/0148 Means for heating preforms during or immediately prior to deposition C03B37/0142, C03B37/01876 take precedence

Abstract

To attain high strength optical glass fibers, the glass preforms, from which the fibers are drawn, must generally be free of surface imperfections such as bubbles, and air lines. It has been discovered that these imperfections can be removed quickly and cleanly by contacting the preform surface with a substantial portion of the electrically conducting plasma region (the plasma fireball) extending from a plasma torch. Significantly, the surface material is substantially removed by vaporization, due to the extremely high plasma temperature (>9000° C. at the plasma center) of the isothermal plasma torch. Though the temperatures in the tail of the plasma fireball are substantially less than at the plasma center, the temperatures are generally still several thousand degrees centigrade. These tail temperatures typically are sufficiently high to cause vaporization of most refractory dielectrics making the inventive method applicable to the fabrication of a wide variety of articles comprising refractory dielectric bodies.

Advantageously, selective etching, according to one aspect of the inventive method, is used to remove fiber preform eccentricity and to fabricate optical fiber preforms with non-circular cross-sections for such applications as fiber sensors. Selective etching can result by controlling the plasma fireball location, the rotation of the silica preform, and/or the travel of the fireball across the preform. Significantly, the fireball location is controlled, among other ways, by injecting into the torch an additional gas that has a high ionization threshold or by inserting a probe along the axis of the torch. In either case, a substantial portion of the plasma fireball is advantageously "pushed" outside the torch for ease of contact with the silica preform surface, or any other refractory dielectric being processed.

Claims

1. Method for manufacturing an article comprising a refractory dielectric material, the method comprising:

(a) providing a refractory dielectric body;

(b) removing a portion of material from the refractory dielectric body; and

(c) completing manufacturing the article;

Characterized in that

(d) step (b) comprises exposing the refractory dielectric body to a substantially localized heat source so that at least a substantial part of the portion of material is removed by vaporization, the heat source comprising a plasma fireball generated by a plasma torch, the plasma fireball being the electrically conducting portion of a plasma into which plasma sustaining electromagnetic energy is coupled by the plasma torch.

2. Method of claim 1, wherein the heat source comprises contact with the plasma fireball generated by the plasma torch, the plasma generated from a first gas, associated with the first gas being an ionization threshold, and associated with the plasma torch being an axis.

3. Method of claim 2, wherein the refractory dielectric body is an optical fiber preform comprising a silica glass.

4. Method of claim 2, wherein the first gas comprises oxygen.

5. Method of claim 2, comprising introducing a second gas into the plasma torch, where the second gas has a ionization threshold that is higher than that of the first gas.

6. Method of claim 2, comprising positioning a substantial portion of the plasma fireball outside the plasma torch, the portion being in the range 0.01% to 50% of the fireball volume.

7. Method of claim 5, wherein the second gas is nitrogen.

8. Method of claim 2, wherein the plasma torch comprises an electrically insulated probe means extending into the plasma torch substantially along the plasma torch axis.

9. Method of claim 2, comprising moving the plasma fireball along the refractory dielectric body at a speed in the range 0.01-100 cm/sec.

10. Method of claim 2, comprising rotating the refractory dielectric body, at least during some interval while removing a portion of material from the refractory dielectric body, at varying rates in the range from 0.0 rpm to about 200 rpm.

11. Method of claim 3, wherein the article is an optical fiber.

12. Method of claim 3, wherein the preform further comprises a synthetic silica substrate.

13. Method of claim 2, wherein the article is an optical fiber sensor.