Palladium based powder-metal alloys and method for making same

• US 5,000,779 A
• Filed: 05/18/1988
• Issued: 03/19/1991
• Est. Priority Date: 05/18/1988
• Status: Expired due to Fees

• Current Assignee: Leach & Garner Company 49 Pearl Street Attleboro MA
• Original Assignee: Leach & Garner Co. (Berkshire Hathaway Incorporated)
• Inventors: German, Randall M., Faroog, Shaji, Bourguignon, Laura L., Agarwal, Dwarika P.
• Primary Examiner(s): Lechert, Jr., Stephen J.
• Assistant Examiner(s): Bhat, N.
• Application Number:
  US07/195,721
• Time in Patent Office: 1,035 Days
• Field of Search: 419/12, 419/23, 75/244, 75/247, 420/502, 420/464, 420/503, 420/497, 420/505
• US Class Current: 75/244
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/1035 Liquid phase sintering
• CPC Class Codes: B22F 9/082 atomising using a fluid using centrifugal force B22F9/10
• CPC Class Codes: C22C 1/0466 Alloys based on noble metals
• CPC Class Codes: C22C 32/00 Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ

Abstract

The subject of this invention is the development of new alloys along with new processing approaches for the utilization of the alloys. A particular class of alloys comprises at least one noble metal selected from the group comprising gold, palladium, silver and copper and an amount of between about 0.20 weight percent and about 0.80 weight percent of at least one metalloid selected from the group of metalloids consisting of boron, phosphorous, silicon and lithium. Rapid solidification technology in powder fabrication and the addition of metalloids have been combined to produce a new class of palladium based alloys. The metalloid additions greatly increase the hardness, enhance the fine grain structure and aid sintering densification. Net-shape forming is a benefit derived from the characteristics of the new alloys.

Claims

1. An alloy composition of matter comprising:

at least one noble metal selected from the group consisting of gold, palladium, silver and copper; and

an amount of between about 0.20 weight percent and about 0.80 weight percent of at least one metalloid selected from the group of metalloids consisting of boron, phosphorous, silicon and lithium.

5. The noble metal alloy as recited in claim 1, 2, 3 or 4 wherein said alloy is in the form of a substantially spherical particle a plurality of said particles being a metal powder.

6. The noble metal alloy as recited in claim 5 wherein said metal powder is produced by gas atomization and said particle size is less than about 100 micrometers wherein said particles are comprised of grains having a grain size less than about 10 micrometers.

2. A noble metal alloy comprising:

an amount of between about 5.0 weight percent and about 60.0 weight percent palladium;

an amount of between about 5.0 weight percent and about 60.0 weight percent silver;

an amount of between about 5.0 weight percent and about 60.0 weight percent copper;

an amount of between about 0.05 weight percent and about 0.80 weight percent boron; and

an amount of between about 0.05 weight percent and about 0.80 weight percent phosphorous.

3. A noble metal alloy comprising:

not less than 20.0 weight percent palladium;

not less than 20.0 weight percent silver;

not less than 20.0 weight percent copper;

not less than 0.20 weight percent boron; and

not less than 0.20 weight percent phosphorous.

4. A noble metal alloy comprising:

between about 30.0 and about 40.0 weight percent palladium;

between about 30.0 and about 40.0 weight percent silver;

between about 30.0 and about 40.0 weight percent copper;

between about 0.25 and about 0.50 weight percent boron; and

between about 0.25 and about 0.50 weight percent phosphorous.