Solid imaging method utilizing compositions comprising thermally coalescible materials

• US 5,006,364 A
• Filed: 08/24/1989
• Issued: 04/09/1991
• Est. Priority Date: 08/24/1989
• Status: Expired due to Term

• Current Assignee: DSM IP Assets BV (DSM-Firmenich AG)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Fan, Roxy N.
• Primary Examiner(s): Pianalto, Bernard
• Application Number:
  US07/398,194
• Time in Patent Office: 593 Days
• Field of Search: 427/44, 427/53.1, 427/264, 427/265, 427/375, 427/54.1, 427/385.5, 427/407.1, 427/55
• US Class Current: 427/510
• CPC Class Codes: B29C 35/0805 using electromagnetic radiation
• CPC Class Codes: B29C 64/135 the energy source being concentrated, e.g. scanning lasers or focused light sources
• CPC Class Codes: G03F 7/0037 Production of three-dimensional images
• CPC Class Codes: Y10S 430/148 Light sensitive titanium compound containing

Abstract

A solid imaging method utilizing photoformable compositions comprising thermally coalescible materials for producing multilayer models and prototypes having improved structural properties and resolution.

Claims

1. A method for accurately fabricating an integral three dimensional object from a multiplicity of contiguous layers of a thermally coalescible photoformable liquid composition comprising the steps of:

(a) forming a layer of a thermally coalescible photoformable liquid on a substrate;

(b) imagewise exposing areas of at least a portion of the layer to actinic radiation;

(c) introducing a new layer of liquid onto the layer previously exposed imagewise to actinic radiation according to step (b);

(d) imagewise exposing areas of at least a portion of the new liquid layer to actinic radiation, with the requirement that the photoformable composition comprises a thermally coalescible polymeric cohesive material, a photohardenable monomer, and a photoinitiator, wherein after the exposure to the acthnic radiation, the photoformed areas of the composition remain thermally coalescible;

(e) successively repeating steps (c) and (d) until all layers of the three dimensional object have been photoformed and connected through joining surfaces; and

(f) in sequence

(i) removing the unexposed portion of the photoformable composition from the exposed portion of the three dimensional object, and

(ii) thermally coalescing the three dimensional object in order to promote cohesion both within the contiguous layers and at the joining surfaces between the contiguous layers, thus producing a single coalesced three dimensional object.

2. A method as defined in claim 1, wherein at least one of the layers has also an infraposed surface.

3. A method as defined in claim 2, wherein the photohardenable monomer comprises an ethylenically unsaturated monomer.

4. A method as defined in claim 3, wherein the ethylenically unsaturated monomer is selected from the group consisting of unsaturated bisphenol A oligomers, unsaturated urethane oligomers, and mixtures thereof.

5. A method as defined in claim 2, wherein the removing step (f)(i) is performed with a poor non-coalescing solvent.

6. A method as defined in claim 2, wherein the actinic radiation comprises a laser beam.

7. A method as defined in claim 2, wherein the thermally coalescible material comprises a plastisol containing a polymer and a thermal plasticizer.

8. A method as defined in claim 7, wherein the polymer is selected from the group consisting of polyvinyl halide, polyvinyl halide acetate, polyvinylidene halide, polyvinylidene halide acetate, polyphenylene oxide, polyvinyl acetal, and mixtures thereof.

9. A method as defined in claim 8, wherein the halide is selected from the group consisting of chloride, fluoride, and mixtures thereof.

10. A method as defined in claim 9, wherein the ethylenically unsaturated monomer is selected from the group consisting of unsaturated bisphenol A oligomers, unsaturated urethane oligomers, and mixtures thereof.

11. A method as defined in claim 9, wherein the actinic radiation comprises a laser beam.

12. A method as defined in claim 7, wherein the thermal plasticizer is non-polymerizable.

13. A method as defined in claim 7, wherein the photoformable liquid composition further comprises reinforcement fibers.

14. A method as defined in claim 7, wherein the unsaturated monomer constitutes part of the polymer.

15. A method as defined in claim 14, wherein the photoinitiator constitutes part of the polymer.

16. A method as defined in claim 7, wherein the polymer is selected from the group consisting of acrylic polymers, methacrylic polymers, and mixtures thereof.

17. A method as defined in claim 1, further comprising the steps of:

repeating the steps used in the method of claim 1 in order to fabricate at least one additional single integral three-dimensional object, each single object thus fabricated having at least one first preselected matching surface intended to match a second matching surface, the second surface being part of at least one other single object;

applying a coating of thermally coalescible composition on at least one of the first and second matching surfaces;

bringing the first matching surfaces in contact with the second matching surfaces; and

thermally coalescing the coating of the thermally coalescible composition within the first and second matching surfaces in order to form a strong bond between the first and second surfaces, thus completing the fabrication of an integral complex object.

18. A method as defined in claim 1, further comprising the steps of:

repeating the steps used in the method of claim 1, except step (f)(ii) in order to fabricate at least one uncoalesced single integral three dimensional object, each uncoalesced single object thus fabricated having at least one third matching surface intended to match a fourth matching surface, the fourth matching surface being part of at least one other single object;

bringing the third matching surfaces in contact with the fourth matching surfaces; and

thermally coalescing the uncoalesced single object in order to form a strong bond between the first and second surfaces, thus completing the fabrication of an integral complex object.